https://oldena.lpnu.ua/handle/ntb/45186| Title: | Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione |
| Other Titles: | Протон-ініційоване перетворення дитіокарбаматів 9,10-антрацендіону |
| Authors: | Stasevych, Maryna Zvarych, Viktor Khomyak, Semen Lunin, Volodymyr Kopak, Nazarii Novikov, Volodymyr Vovk, Mykhailo |
| Affiliation: | Lviv Polytechnic National University Institute of Organic Chemistry of National Academy of Sciences of Ukraine |
| Bibliographic description (Ukraine): | Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione / Maryna Stasevych, Viktor Zvarych, Semen Khomyak, Volodymyr Lunin, Nazarii Kopak, Volodymyr Novikov, Mykhailo Vovk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 300–304. |
| Bibliographic description (International): | Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione / Maryna Stasevych, Viktor Zvarych, Semen Khomyak, Volodymyr Lunin, Nazarii Kopak, Volodymyr Novikov, Mykhailo Vovk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 300–304. |
| Is part of: | Chemistry & Chemical Technology, 3 (12), 2018 |
| Journal/Collection: | Chemistry & Chemical Technology |
| Issue: | 3 |
| Volume: | 12 |
| Issue Date: | 20-Jan-2018 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | 9 10-антрацендіон дитіокарбамати кислотно-каталізована циклодегідратація перхлорати спектральні дослідження 9 10-anthracenedione dithiocarbamates acidcatalyzed cyclodehydration perchlorates spectroscopic studies |
| Number of pages: | 5 |
| Page range: | 300-304 |
| Start page: | 300 |
| End page: | 304 |
| Abstract: | Досліджено протон-ініційоване перетво-
рення дитіокарбаматних похідних 9,10-антрацендіону за умов
кислотно-каталізованої циклодегідратації при дії суміші
H2SO4-АсОН та подальшому обробленні перхлоратною
кислотою. На основі даних спектральних методів (1Н, 13С
ЯМР, ІЧ-, УФ-спектроскопії) встановлено, що реакція зупи-
няється на стадії протонування атома Сульфуру тіокар-
бонільної групи з утворенням перхлоратних солей. УФ спектри
одержаних перхлоратів характеризуються гіпсохромним
зсувом з чітко вираженим максимумом поглинання. Proton-initiated conversion of dithiocarbamate derivatives of the 9,10-anthracenedione under conditions of acid-catalyzed cyclodehydration using the action of a mixture of H2SO4-AcOH and further treatment with perchloric acid was investigated. Based on the data of the spectral methods (1H, 13C NMR, IR, UV spectroscopy), it is established that the reaction stops at the stage of protonation of the sulfur atom of the thiocarbonyl group with the formation of perchlorates. The UV spectra of the obtained perchlorates are characterized by a hypochromic shift with a clearly pronounced absorption maximum. |
| URI: | https://ena.lpnu.ua/handle/ntb/45186 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2018 ©Stasevych M., Zvarych V., Khomyak S., Lunin V., Kopak N., Novikov V., Vovk M., 2018 |
| URL for reference material: | https://doi.org/10.1002/med.21391 https://doi.org/10.1016/j.tetlet.2012.09.011 https://doi.org/10.1080/17415993.2012.718349 https://doi.org/10.1007/s00706-016-1839-y https://doi.org/10.1134/S1070363216120227 https://doi.org/10.1080/1062936X.2017.1323796 https://doi.org/10.3762/bjoc.8.226 https://doi.org/10.1135/cccc19721533 https://doi.org/10.5560/ZNB.2012-0232 https://doi.org/10.1139/v70-368 https://doi.org/10.3891/acta.chem.scand.19-1113 |
| References (Ukraine): | [1] GorelikM.: Khimiya Antrakhinonov i ikh Proizvodnykh. Khimiya, Moskva 1983. [2]Malik E., Müller C.:Med. Res. Rev., 2016, 36, 705.https://doi.org/10.1002/med.21391 [3] Baqi Y., Müller C.: Tetrahedron Lett., 2012, 53, 6739.https://doi.org/10.1016/j.tetlet.2012.09.011 [4] Aly A., Brown A., Bedai T., Ishak E.: J. Sulfur Chem., 2012, 33,605. https://doi.org/10.1080/17415993.2012.718349 [5] Zvarych V., Stasevych M., Lunin V. et al.:Monatsh. Chem.,2016, 147, 2093. https://doi.org/10.1007/s00706-016-1839-y [6] Zvarych V., Stasevych M., Lunin V. et al.: Rus. J. Gen. Chem.,2016, 86, 2699. https://doi.org/10.1134/S1070363216120227 [7] Halenova T., Nikolaeva I., Stasevych M. et al.: Res. J. Pharm. Biol. Chem. Sci., 2017, 8, 1626. [8] StasevychM., Zvarych V., Lunin V. et al.: SAR QSAR Environ. Res., 2017, 28, 355. https://doi.org/10.1080/1062936X.2017.1323796 [9] Bahrin L., Jones P., Hopf H.: Beilstein J. Org. Chem., 2012, 8,1999. https://doi.org/10.3762/bjoc.8.226 [10] Lungu N., Bahrin L., Asaftei I. et al.: Rev. Chim. (Bucharest),2014, 65, 181. [11] Kratochvil N., NeprasM.: Collect. Czechoslovak Chem. Comm. 1972, 37, 1533. https://doi.org/10.1135/cccc19721533 [12] Bahrin L., Luca A., Birsa L.: Rev. Chim. (Bucharest), 2014, 65, 199. [13] Axhausen J., Ruhl G., Kornath A.: Z. Naturforsch., 2012, 67b,1235. https://doi.org/10.5560/ZNB.2012-0232 [14] Vandebeek R., Joris S., Aspila K., Chakraba C.: J. Can. Chem.,1970, 48, 2204. https://doi.org/10.1139/v70-368 [15] ShankaranarayanaM., Patel C.: Acta Chem. Scand., 1965, 19,1113. https://doi.org/10.3891/acta.chem.scand.19-1113 |
| References (International): | [1] GorelikM., Khimiya Antrakhinonov i ikh Proizvodnykh. Khimiya, Moskva 1983. [2]Malik E., Müller C.:Med. Res. Rev., 2016, 36, 705.https://doi.org/10.1002/med.21391 [3] Baqi Y., Müller C., Tetrahedron Lett., 2012, 53, 6739.https://doi.org/10.1016/j.tetlet.2012.09.011 [4] Aly A., Brown A., Bedai T., Ishak E., J. Sulfur Chem., 2012, 33,605. https://doi.org/10.1080/17415993.2012.718349 [5] Zvarych V., Stasevych M., Lunin V. et al.:Monatsh. Chem.,2016, 147, 2093. https://doi.org/10.1007/s00706-016-1839-y [6] Zvarych V., Stasevych M., Lunin V. et al., Rus. J. Gen. Chem.,2016, 86, 2699. https://doi.org/10.1134/S1070363216120227 [7] Halenova T., Nikolaeva I., Stasevych M. et al., Res. J. Pharm. Biol. Chem. Sci., 2017, 8, 1626. [8] StasevychM., Zvarych V., Lunin V. et al., SAR QSAR Environ. Res., 2017, 28, 355. https://doi.org/10.1080/1062936X.2017.1323796 [9] Bahrin L., Jones P., Hopf H., Beilstein J. Org. Chem., 2012, 8,1999. https://doi.org/10.3762/bjoc.8.226 [10] Lungu N., Bahrin L., Asaftei I. et al., Rev. Chim. (Bucharest),2014, 65, 181. [11] Kratochvil N., NeprasM., Collect. Czechoslovak Chem. Comm. 1972, 37, 1533. https://doi.org/10.1135/cccc19721533 [12] Bahrin L., Luca A., Birsa L., Rev. Chim. (Bucharest), 2014, 65, 199. [13] Axhausen J., Ruhl G., Kornath A., Z. Naturforsch., 2012, 67b,1235. https://doi.org/10.5560/ZNB.2012-0232 [14] Vandebeek R., Joris S., Aspila K., Chakraba C., J. Can. Chem.,1970, 48, 2204. https://doi.org/10.1139/v70-368 [15] ShankaranarayanaM., Patel C., Acta Chem. Scand., 1965, 19,1113. https://doi.org/10.3891/acta.chem.scand.19-1113 |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3 |
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| 2018v12n3_Stasevych_M-Proton_initiated_conversion_300-304.pdf | 289.96 kB | Adobe PDF | View/Open | |
| 2018v12n3_Stasevych_M-Proton_initiated_conversion_300-304__COVER.png | 544.12 kB | image/png | View/Open |
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