| DC Field | Value | Language |
|---|
| dc.contributor.author | Stasevych, Maryna | |
| dc.contributor.author | Zvarych, Viktor | |
| dc.contributor.author | Khomyak, Semen | |
| dc.contributor.author | Lunin, Volodymyr | |
| dc.contributor.author | Kopak, Nazarii | |
| dc.contributor.author | Novikov, Volodymyr | |
| dc.contributor.author | Vovk, Mykhailo | |
| dc.date.accessioned | 2019-06-20T11:19:51Z | - |
| dc.date.available | 2019-06-20T11:19:51Z | - |
| dc.date.created | 2018-01-20 | |
| dc.date.issued | 2018-01-20 | |
| dc.identifier.citation | Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione / Maryna Stasevych, Viktor Zvarych, Semen Khomyak, Volodymyr Lunin, Nazarii Kopak, Volodymyr Novikov, Mykhailo Vovk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 300–304. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/45186 | - |
| dc.description.abstract | Досліджено протон-ініційоване перетво-
рення дитіокарбаматних похідних 9,10-антрацендіону за умов
кислотно-каталізованої циклодегідратації при дії суміші
H2SO4-АсОН та подальшому обробленні перхлоратною
кислотою. На основі даних спектральних методів (1Н, 13С
ЯМР, ІЧ-, УФ-спектроскопії) встановлено, що реакція зупи-
няється на стадії протонування атома Сульфуру тіокар-
бонільної групи з утворенням перхлоратних солей. УФ спектри
одержаних перхлоратів характеризуються гіпсохромним
зсувом з чітко вираженим максимумом поглинання. | |
| dc.description.abstract | Proton-initiated conversion of dithiocarbamate
derivatives of the 9,10-anthracenedione under conditions
of acid-catalyzed cyclodehydration using the action of a
mixture of H2SO4-AcOH and further treatment with
perchloric acid was investigated. Based on the data of the
spectral methods (1H, 13C NMR, IR, UV spectroscopy), it
is established that the reaction stops at the stage of
protonation of the sulfur atom of the thiocarbonyl group
with the formation of perchlorates. The UV spectra of the
obtained perchlorates are characterized by a hypochromic
shift with a clearly pronounced absorption maximum. | |
| dc.format.extent | 300-304 | |
| dc.language.iso | en | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry & Chemical Technology, 3 (12), 2018 | |
| dc.relation.uri | https://doi.org/10.1002/med.21391 | |
| dc.relation.uri | https://doi.org/10.1016/j.tetlet.2012.09.011 | |
| dc.relation.uri | https://doi.org/10.1080/17415993.2012.718349 | |
| dc.relation.uri | https://doi.org/10.1007/s00706-016-1839-y | |
| dc.relation.uri | https://doi.org/10.1134/S1070363216120227 | |
| dc.relation.uri | https://doi.org/10.1080/1062936X.2017.1323796 | |
| dc.relation.uri | https://doi.org/10.3762/bjoc.8.226 | |
| dc.relation.uri | https://doi.org/10.1135/cccc19721533 | |
| dc.relation.uri | https://doi.org/10.5560/ZNB.2012-0232 | |
| dc.relation.uri | https://doi.org/10.1139/v70-368 | |
| dc.relation.uri | https://doi.org/10.3891/acta.chem.scand.19-1113 | |
| dc.subject | 9 10-антрацендіон | |
| dc.subject | дитіокарбамати | |
| dc.subject | кислотно-каталізована циклодегідратація | |
| dc.subject | перхлорати | |
| dc.subject | спектральні дослідження | |
| dc.subject | 9 10-anthracenedione | |
| dc.subject | dithiocarbamates | |
| dc.subject | acidcatalyzed cyclodehydration | |
| dc.subject | perchlorates | |
| dc.subject | spectroscopic studies | |
| dc.title | Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione | |
| dc.title.alternative | Протон-ініційоване перетворення дитіокарбаматів 9,10-антрацендіону | |
| dc.type | Article | |
| dc.rights.holder | © Національний університет „Львівська політехніка“, 2018 | |
| dc.rights.holder | ©Stasevych M., Zvarych V., Khomyak S., Lunin V., Kopak N., Novikov V., Vovk M., 2018 | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.affiliation | Institute of Organic Chemistry of National Academy of Sciences of Ukraine | |
| dc.format.pages | 5 | |
| dc.identifier.citationen | Proton-initiated conversion of dithiocarbamates of 9,10-anthracenedione / Maryna Stasevych, Viktor Zvarych, Semen Khomyak, Volodymyr Lunin, Nazarii Kopak, Volodymyr Novikov, Mykhailo Vovk // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 300–304. | |
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| dc.relation.referencesen | [1] GorelikM., Khimiya Antrakhinonov i ikh Proizvodnykh. Khimiya, Moskva 1983. | |
| dc.relation.referencesen | [2]Malik E., Müller C.:Med. Res. Rev., 2016, 36, 705.https://doi.org/10.1002/med.21391 | |
| dc.relation.referencesen | [3] Baqi Y., Müller C., Tetrahedron Lett., 2012, 53, 6739.https://doi.org/10.1016/j.tetlet.2012.09.011 | |
| dc.relation.referencesen | [4] Aly A., Brown A., Bedai T., Ishak E., J. Sulfur Chem., 2012, 33,605. https://doi.org/10.1080/17415993.2012.718349 | |
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| dc.relation.referencesen | [13] Axhausen J., Ruhl G., Kornath A., Z. Naturforsch., 2012, 67b,1235. https://doi.org/10.5560/ZNB.2012-0232 | |
| dc.relation.referencesen | [14] Vandebeek R., Joris S., Aspila K., Chakraba C., J. Can. Chem.,1970, 48, 2204. https://doi.org/10.1139/v70-368 | |
| dc.relation.referencesen | [15] ShankaranarayanaM., Patel C., Acta Chem. Scand., 1965, 19,1113. https://doi.org/10.3891/acta.chem.scand.19-1113 | |
| dc.citation.journalTitle | Chemistry & Chemical Technology | |
| dc.citation.volume | 12 | |
| dc.citation.issue | 3 | |
| dc.citation.spage | 300 | |
| dc.citation.epage | 304 | |
| dc.coverage.placename | Lviv | |
| Appears in Collections: | Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3
|
