https://oldena.lpnu.ua/handle/ntb/55800| Title: | Preparation and Characterization of Molecular Imprinted Polymer for the Selective Recognition of Serotonin |
| Other Titles: | Одержання та характеристика полімерів з “молекулярними відтисками” для селективного розпізнавання серотоніну |
| Authors: | Hepokur, Ceylan Nursevin Öztop, H. Saraydin, Dursun |
| Affiliation: | Sivas Cumhuriyet University |
| Bibliographic description (Ukraine): | Hepokur C. Preparation and Characterization of Molecular Imprinted Polymer for the Selective Recognition of Serotonin / Ceylan Hepokur, H. Nursevin Öztop, Dursun Saraydin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 195–204. |
| Bibliographic description (International): | Hepokur C. Preparation and Characterization of Molecular Imprinted Polymer for the Selective Recognition of Serotonin / Ceylan Hepokur, H. Nursevin Öztop, Dursun Saraydin // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 195–204. |
| Is part of: | Chemistry & Chemical Technology, 2 (14), 2020 |
| Issue: | 2 |
| Volume: | 14 |
| Issue Date: | 24-Jan-2020 |
| Publisher: | Видавництво Львівської політехніки Lviv Politechnic Publishing House |
| Place of the edition/event: | Львів Lviv |
| DOI: | doi.org/10.23939/chcht14.02.195 |
| Keywords: | акриламід метакрилова кислота метакриламід молекулярно-імпринтовані полімери серотонін acrylamide methacrylic acid methacrylamide molecularly imprinted polymers serotonin |
| Number of pages: | 10 |
| Page range: | 195-204 |
| Start page: | 195 |
| End page: | 204 |
| Abstract: | Одержано полімери «з молекулярними відтисками» (молекулярно імпринтовані полімери, MIП) для
високоселективного розпізнавання серотоніну. Як мономери для
одержання МІП використано акриламід, метакрилову кислоту та
метакриламид. Проведено полімеризацію функціональних
мономерів з диметакрилатом етиленгліколю, діакрилатом 1,4-
бутандіолу і триметилпропантриакрилатом з серотоніном.
Видалення серотоніну з MIП проводили за допомогою суміші
метанол/оцтова кислота (4:1). Синтезовано неімпринтовані
полімери (НІП) без серотоніну. Одержані полімери досліджено за
допомогою методів Фур‘є-спектроскопії, диференційно скануючої
калориметрії, термогравіметричного аналізу та скануючої
електронної мікроскопії. Встановлено вплив температури, pH і
концентрації на адсорбцію серотоніну. Визначено значення
селективності таможливість повторного використання. Molecularly imprinted polymers (MIPs) were prepared for highly selective recognition of serotonin. Acrylamide, methacrylic acid and methacrylamide were selected as the monomers for the production of MIPs. Functional monomers were polymerized with ethylene glycol dimethacrylate, 1,4-butanediol diacrylate, and trimethylpropane triacrylate with serotonin (MIP-EGDMA, MIP-BUT and MIP-TMT). Serotonin was removed from MIP by the mixture of methanol/acetic acid (4:1). Nonimprinted polymers (NIPs) were synthesized without serotonin (NIP-EGDMA, NIP-BUT and NIP-TMT). For the characterization of synthesized polymers FTIR, DSC, TGA, and SEM analysis were investigated. The parameters that affect the adsorption of serotonin on polymers such as temperature, pH and concentration were evaluated. The selectivity and reusability studies were also investigated. |
| URI: | https://ena.lpnu.ua/handle/ntb/55800 |
| Copyright owner: | © Національний університет “Львівська політехніка”, 2020 © Hepokur C., Oztop N., Saraydin D., 2020 |
| URL for reference material: | https://doi.org/10.1016/j.apsusc.2018.07.142 https://doi.org/10.1002/cbdv.200490069 https://doi.org/10.3390/ijms9122333 https://doi.org/10.1016/j.aca.2016.02.046 https://doi.org/10.3390/i7050155 https://doi.org/10.1016/j.bios.2017.08.022 https://doi.org/10.1016/j.aca.2005.01.052 https://doi.org/10.3176/proc.2018.2.04 https://doi.org/10.1016/j.elecom.2017.07.007 https://doi.org/10.1016/j.bios.2005.05.015 https://doi.org/10.1002/pola.20186 https://doi.org/10.1016/S0378-4347(99)00057-2 https://doi.org/10.1016/j.aca.2007.01.016 https://doi.org/10.1016/j.snb.2012.05.040 https://doi.org/10.1016/j.aca.2010.04.019 https://doi.org/10.1016/j.chroma.2006.09.065 https://doi.org/10.1002/macp.1987.021880408 https://doi.org/10.1016/j.talanta.2008.05.033 https://doi.org/10.1016/S0006-3495(96)79393-1 https://doi.org/10.1016/S1386-1425(02)00308-6 https://doi.org/10.1021/jp109337a https://doi.org/10.1016/S0142-9612(99)00048-4 https://doi.org/10.1002/pen.23950 https://doi.org/10.1016/j.talanta.2011.09.043 https://doi.org/10.1039/jr9600003973 https://doi.org/10.1007/s12221-017-7215-7 |
| References (Ukraine): | [1] Yola M., Atar N.: Appl. Surf. Sci., 2018, 458, 648. https://doi.org/10.1016/j.apsusc.2018.07.142 [2] Mathews C., van Holde K.: Biochemistry: The Benjamin/Cummings Publ. Co., Redwood City, California 1990. [3] Sengupta B., Chaudhuri S., Banerjee A., Sengupta P.: Chem. Biodivers., 2004, 1, 868. https://doi.org/10.1002/cbdv.200490069 [4] Suedee R., Seechammanturakit V., Suksuwan A., Canyuk B.: Int. J. Mol. Sci., 2008, 9, 2333. https://doi.org/10.3390/ijms9122333 [5] Patra S., Roy E., Madhuri R., Sharma P.: Anal. Chim. Acta, 2016, 918, 77. https://doi.org/10.1016/j.aca.2016.02.046 [6] Yan H., Row H.: Int. J. Mol. Sci., 2006, 7, 155. https://doi.org/10.3390/i7050155 [7]JeCho S., Noh H., Won M. et al.: Biosens. Bioelectron., 2018, 99, 471. https://doi.org/10.1016/j.bios.2017.08.022 [8] Hawkins D., Stevenson D., Reddy S.: Anal. Chim. Acta, 2005, 542, 61. https://doi.org/10.1016/j.aca.2005.01.052 [9] Ayankojo A., Reut J., Öpik A. et al.: Proceed. Estonian Acad. Sci., 2018, 67, 138. https://doi.org/10.3176/proc.2018.2.04 [10] Gálvez A., Mayorga-MatinezC., ParoloC. et al.: Electrochem. Commun., 2017, 82, 6. https://doi.org/10.1016/j.elecom.2017.07.007 [11] O’Mahony J., Molinelli A., Nolan K. et al.: Biosens. Bioelectron., 2005, 21, 1383. https://doi.org/10.1016/j.bios.2005.05.015 [12] VazquezM., Spivak D.:J. Polym. Sci., 2004, 42, 3668. https://doi.org/10.1002/pola.20186 [13] Takeuchi T., Haginaka J.:J. Chromatogr. B, 1999, 728, 1. https://doi.org/10.1016/S0378-4347(99)00057-2 [14] Tooth B., Pap T., Horvath V., Horvai G.: Anal. Chim. Acta, 2007, 591, 17. https://doi.org/10.1016/j.aca.2007.01.016 [15] Peeters M., Troost F., Van Grinsven B., et al.: Sensor. Actuat. BChem., 2012, 172, 602. https://doi.org/10.1016/j.snb.2012.05.040 [16] Turiel E., Esteban A.: Anal. Chim. Acta, 2010, 668, 87. https://doi.org/10.1016/j.aca.2010.04.019 [17] Urban J., Jandera P., Schoenmakers P.:J. Chromatogr. A, 2007, 1150, 279. https://doi.org/10.1016/j.chroma.2006.09.065 [18] Wulff G., Poll H.:Macromol. Chem. Phys., 1997, 188, 741. https://doi.org/10.1002/macp.1987.021880408 [19] Okutucu B.,Telefoncu A.: Talanta, 2008, 76, 1153. https://doi.org/10.1016/j.talanta.2008.05.033 [20] Chattopathyay A., Rukmini R., Mukherjee S.: Biophys. J., 1996, 71, 1952. https://doi.org/10.1016/S0006-3495(96)79393-1 [21] Ewing G.: Instrumental Methods of Chemical Analysis, 4.edn. McGraw-Hill,Tokyo 1975. [22] Bayari S., Ide S.: Spectrochim. Acta A, 2003, 59, 1255. https://doi.org/10.1016/S1386-1425(02)00308-6 [23] Lagutschenkov A., LangerJ., Berden G. et al.:J. Phys. Chem. A, 2010, 114, 13268. https://doi.org/10.1021/jp109337a [24] PenicheC., Argüelles-Monal W., Davidenko N. et al.: Biomater., 1999, 20, 1869. https://doi.org/10.1016/S0142-9612(99)00048-4 [25] Işikver Y., Saraydin D.: Polym. Eng. Sci., 2015, 55, 843. https://doi.org/10.1002/pen.23950 [26]Barati A., Kazemi E., Dadfarnia S., Shabani A.:JIEC, 2017, 46, 212. [27] Okutucu B.,Önal S.: Talanta, 2011, 87, 74. https://doi.org/10.1016/j.talanta.2011.09.043 [28] Rudnick G., Kirk K., Fishkes H., Schuldiner S.:J. Biolog. Chem., 1989, 264, 14865. [29] Giles C., Macewan T., Nakhwa S., Smith D.:Journal of Chemical Society, 1960, 3973. https://doi.org/10.1039/jr9600003973 [30] Işikver Y.: Fibers and Polymers, 2017, 18, 2070. https://doi.org/10.1007/s12221-017-7215-7 [31] Saraydin D., Karadağ E.: Tr. J. Chem., 1996, 20, 234. |
| References (International): | [1] Yola M., Atar N., Appl. Surf. Sci., 2018, 458, 648. https://doi.org/10.1016/j.apsusc.2018.07.142 [2] Mathews C., van Holde K., Biochemistry: The Benjamin/Cummings Publ. Co., Redwood City, California 1990. [3] Sengupta B., Chaudhuri S., Banerjee A., Sengupta P., Chem. Biodivers., 2004, 1, 868. https://doi.org/10.1002/cbdv.200490069 [4] Suedee R., Seechammanturakit V., Suksuwan A., Canyuk B., Int. J. Mol. Sci., 2008, 9, 2333. https://doi.org/10.3390/ijms9122333 [5] Patra S., Roy E., Madhuri R., Sharma P., Anal. Chim. Acta, 2016, 918, 77. https://doi.org/10.1016/j.aca.2016.02.046 [6] Yan H., Row H., Int. J. Mol. Sci., 2006, 7, 155. https://doi.org/10.3390/i7050155 [7]JeCho S., Noh H., Won M. et al., Biosens. Bioelectron., 2018, 99, 471. https://doi.org/10.1016/j.bios.2017.08.022 [8] Hawkins D., Stevenson D., Reddy S., Anal. Chim. Acta, 2005, 542, 61. https://doi.org/10.1016/j.aca.2005.01.052 [9] Ayankojo A., Reut J., Öpik A. et al., Proceed. Estonian Acad. Sci., 2018, 67, 138. https://doi.org/10.3176/proc.2018.2.04 [10] Gálvez A., Mayorga-MatinezC., ParoloC. et al., Electrochem. Commun., 2017, 82, 6. https://doi.org/10.1016/j.elecom.2017.07.007 [11] O’Mahony J., Molinelli A., Nolan K. et al., Biosens. Bioelectron., 2005, 21, 1383. https://doi.org/10.1016/j.bios.2005.05.015 [12] VazquezM., Spivak D.:J. Polym. Sci., 2004, 42, 3668. https://doi.org/10.1002/pola.20186 [13] Takeuchi T., Haginaka J.:J. Chromatogr. B, 1999, 728, 1. https://doi.org/10.1016/S0378-4347(99)00057-2 [14] Tooth B., Pap T., Horvath V., Horvai G., Anal. Chim. Acta, 2007, 591, 17. https://doi.org/10.1016/j.aca.2007.01.016 [15] Peeters M., Troost F., Van Grinsven B., et al., Sensor. Actuat. BChem., 2012, 172, 602. https://doi.org/10.1016/j.snb.2012.05.040 [16] Turiel E., Esteban A., Anal. Chim. Acta, 2010, 668, 87. https://doi.org/10.1016/j.aca.2010.04.019 [17] Urban J., Jandera P., Schoenmakers P.:J. Chromatogr. A, 2007, 1150, 279. https://doi.org/10.1016/j.chroma.2006.09.065 [18] Wulff G., Poll H.:Macromol. Chem. Phys., 1997, 188, 741. https://doi.org/10.1002/macp.1987.021880408 [19] Okutucu B.,Telefoncu A., Talanta, 2008, 76, 1153. https://doi.org/10.1016/j.talanta.2008.05.033 [20] Chattopathyay A., Rukmini R., Mukherjee S., Biophys. J., 1996, 71, 1952. https://doi.org/10.1016/S0006-3495(96)79393-1 [21] Ewing G., Instrumental Methods of Chemical Analysis, 4.edn. McGraw-Hill,Tokyo 1975. [22] Bayari S., Ide S., Spectrochim. Acta A, 2003, 59, 1255. https://doi.org/10.1016/S1386-1425(02)00308-6 [23] Lagutschenkov A., LangerJ., Berden G. et al.:J. Phys. Chem. A, 2010, 114, 13268. https://doi.org/10.1021/jp109337a [24] PenicheC., Argüelles-Monal W., Davidenko N. et al., Biomater., 1999, 20, 1869. https://doi.org/10.1016/S0142-9612(99)00048-4 [25] Işikver Y., Saraydin D., Polym. Eng. Sci., 2015, 55, 843. https://doi.org/10.1002/pen.23950 [26]Barati A., Kazemi E., Dadfarnia S., Shabani A.:JIEC, 2017, 46, 212. [27] Okutucu B.,Önal S., Talanta, 2011, 87, 74. https://doi.org/10.1016/j.talanta.2011.09.043 [28] Rudnick G., Kirk K., Fishkes H., Schuldiner S.:J. Biolog. Chem., 1989, 264, 14865. [29] Giles C., Macewan T., Nakhwa S., Smith D.:Journal of Chemical Society, 1960, 3973. https://doi.org/10.1039/jr9600003973 [30] Işikver Y., Fibers and Polymers, 2017, 18, 2070. https://doi.org/10.1007/s12221-017-7215-7 [31] Saraydin D., Karadağ E., Tr. J. Chem., 1996, 20, 234. |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 2 |
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| 2020v14n2_Hepokur_C-Preparation_and_Characterization_195-204.pdf | 1.13 MB | Adobe PDF | View/Open | |
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