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Please use this identifier to cite or link to this item: https://oldena.lpnu.ua/handle/ntb/46461
Title: Synthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite
Other Titles: Синтез та характеристика суміші Al,Cu-зшитого і промотованого міддю бентоніту
Authors: Ravari, Maryam Hamidi
Sarrafi, Amir
Tahmooresi, Majid
Affiliation: Shahid Bahonar University of Kerman
International Center of High Technology & Environmental Science
Bibliographic description (Ukraine): Ravari M. H. Synthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite / Maryam Hamidi Ravari, Amir Sarrafi, Majid Tahmooresi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 2. — P. 231–235.
Bibliographic description (International): Ravari M. H. Synthesis and Characterization of Mixed Al,Cu-Pillared and Copper Doped Al-Pillared Bentonite / Maryam Hamidi Ravari, Amir Sarrafi, Majid Tahmooresi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 2. — P. 231–235.
Is part of: Chemistry & Chemical Technology, 2 (13), 2019
Issue: 2
Issue Date: 28-Feb-2019
Publisher: Видавництво Львівської політехніки
Lviv Politechnic Publishing House
Place of the edition/event: Львів
Lviv
Keywords: алюміній
бентоніт
мідь
зшиті глини
aluminum
bentonite
copper
pillared clays
Number of pages: 5
Page range: 231-235
Start page: 231
End page: 235
Abstract: З використанням зразка бентоніту одер- жано суміші глин, зшитих алюмінієм та міддю (Al, Cu-PILCs) з різним відсотком Cu та імпрегнованих алюмінієм (Cu@Al- PILC). Характеристику зразків проведено за допомогою рентгенівської дифракції, адсорбції-десорбції N2 та Фур‘є- спектроскопії. Визначено, що площа поверхні за БЕТ, загальна площа та об‘єм мікропор Al-PILC зменшуються в Cu@Al- PILC, проте збільшуються у випадку змішаних металів і досягають максимуму для Al, Cu-PILCs. Встановлено, що найвищий вміст міді є в Cu@Al-PILC, тому його каталітичні властивості покращуються. Фур‘є-спектроскопією підтверд- жено введення міді в структуру Al, Cu-PILCs.
In this paper, mixed aluminum and copper pillared clays (Al,Cu-PILCs) with different percentage of Cu and copper impregnated aluminum pillared clay (Cu@Al-PILC) were prepared using a bentonite sample. The samples were characterized by X-ray diffraction, N2 adsorption-desorption and Fourier transformed infrared spectroscopy. The results showed bentonite had a main reflection of montmorillonite that characterized by basal spacing, increased by pillaring. The specific BET surface area, total surface area and micropore volume of Al-PILC decreased in Cu@Al-PILC but increased in the case of mixed metal pillars and the maximum of these parameters related to Al,Cu15-PILC. Maximum weight percentage of copper was in Cu@Al-PILC therefore it contained higher percent of copper and its catalytic properties increased. FTIR result of samples confirmed the successful intercalation of Cu.
URI: https://ena.lpnu.ua/handle/ntb/46461
Copyright owner: © Національний університет „Львівська політехніка“, 2019
© Hamidi RavariM., Sarrafi A., Tahmooresi M., 2019
URL for reference material: https://doi.org/10.1016/j.apcata.2011.11.023
https://doi.org/10.1016/j.cattod.2007.12.112
https://doi.org/10.1016/S1002-0721(10)60393-6
https://doi.org/10.1016/S0169-1317(01)00069-2
https://doi.org/10.1016/j.cej.2009.05.004
https://doi.org/10.1016/S0920-5861(01)00320-0
https://doi.org/10.1080/01614940.2014.904182
https://doi.org/10.1016/j.clay.2010.07.004
https://doi.org/10.1016/j.molstruc.2015.10.072
https://doi.org/10.1016/j.clay.2010.04.012
https://doi.org/10.1016/j.crci.2015.08.004
https://doi.org/10.1016/j.cattod.2007.03.041
https://doi.org/10.1016/S0926-3373(98)00083-6
https://doi.org/10.1016/j.micromeso.2007.05.011
https://doi.org/10.1016/j.ccr.2012.03.010
https://doi.org/10.1007/978-1-4020-2303-3_9
https://doi.org/10.1016/0021-9517(65)90307-6
https://doi.org/10.1016/j.jiec.2012.11.018
https://doi.org/10.4236/jsemat.2013.34037
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9. Chae H., Nam I., Ham S., Hong S.: Catal. Today, 2001, 68, 31. https://doi.org/10.1016/S0920-5861(01)00320-0
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22. Lippens B., Deboer J.: J. Catal., 1995, 4, 319. https://doi.org/10.1016/0021-9517(65)90307-6
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References (International): 1. Bergaya F., Theng B., Lagaly G., Handbook of Clay Science. Elsevier 2006.
2. Ayodele O., Lim J., Hameed B., Appl. Catal. A-Gen., 2012, 413, 301. https://doi.org/10.1016/j.apcata.2011.11.023
3. Britto J., Oliveira S., Rabelo D., Rangel M., Catal. Today, 2008, 133, 582. https://doi.org/10.1016/j.cattod.2007.12.112
4. Zuo S., Zhou R., Qi Ch., J. Rare Earths, 2011, 29, 52. https://doi.org/10.1016/S1002-0721(10)60393-6
5. Kloprogge J., Evans R., Hickey L., Frost L., Appl. Clay Sci., 2002, 20, 157. https://doi.org/10.1016/S0169-1317(01)00069-2
6. Mishra T., TransitionMetal Oxide-Pillared Clay Catalyst: Synthesis to Application [in:] Gil A. et al. (Eds.): Pillared Clays and Related Catalysts. Springer Science+BusinessMedia 2010.
7. Mojovic Z., Bankovic P., Milutinovic-Nikolis A. et al., Chem. Eng. J., 2009, 154, 149. https://doi.org/10.1016/j.cej.2009.05.004
8. Pires J., PintoM., Pillared Interlayered Clays as Adsorbents of Gases and [in:] Gil A. et al. (Eds.): Pillared Clays and Related Catalysts. Springer Science+BusinessMedia 2010.
9. Chae H., Nam I., Ham S., Hong S., Catal. Today, 2001, 68, 31. https://doi.org/10.1016/S0920-5861(01)00320-0
10. Alejandro Galeano L., Angel VicenteM., Gil A., Catal. Rev., 2014, 56, 239. https://doi.org/10.1080/01614940.2014.904182
11. Turgut Basoglu F., Balci S., Appl. Clay Sci., 2010, 50, 73. https://doi.org/10.1016/j.clay.2010.07.004
12. Turgut Basoglu F., Balci S., J. Mol. Struct., 2016, 1106, 382. https://doi.org/10.1016/j.molstruc.2015.10.072
13. Bankovic P., Mojovic Z., Milutinovic-Nikolis A. et al., Appl. Clay Sci., 2010, 49, 84. https://doi.org/10.1016/j.clay.2010.04.012
14. Hadjltaief H., ZinaM., GalvesM., Costa P., Comptes Rendus Chimie, 2015, 18, 1161. https://doi.org/10.1016/j.crci.2015.08.004
15. Abeysinghe S., Keggin-type aluminum nanoclusters: synthesis, structural characterization and environmental implications. MS thesis, University of Iowa, 2012.
16. Giordano G., Perathoner S., Centi G. et al., Catal. Today, 2007, 124, 240. https://doi.org/10.1016/j.cattod.2007.03.041
17. Yang R., Tharappiwattananon N., Long R., Appl. Catal. BEnviron., 1998, 19, 289. https://doi.org/10.1016/S0926-3373(98)00083-6
18. Caudo S., Genovese Ch., Perathoner S., Centi G.:Micropor. Mesopor. Mater., 2008, 107, 46. https://doi.org/10.1016/j.micromeso.2007.05.011
19. Windle C., Perutz R., Adv. Chem. Rev., 2012, 256, 2562. https://doi.org/10.1016/j.ccr.2012.03.010
20. Lowell S., Shields J., ThomasM., ThommesM.:Micropore Analysis. [in:] Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density. Particle Technology Series, vol 16. Springer, Dordrecht 2004, 129-156. https://doi.org/10.1007/978-1-4020-2303-3_9
21. Jasinska I., Particle size pore structure of nanomaterial. PhD thesis, West Pomeranian University of Technology 2011.
22. Lippens B., Deboer J., J. Catal., 1995, 4, 319. https://doi.org/10.1016/0021-9517(65)90307-6
23. Ayodele O., Hameed B., J. Ind. Eng. Chem., 2013, 19, 966. https://doi.org/10.1016/j.jiec.2012.11.018
24. Djomgoue P., NjopwouoD., J. Surf. Eng. Mat. Adv. Technol., 2013, 3, 275. https://doi.org/10.4236/jsemat.2013.34037
25. Tomul F., Balci S., J. Sci., 2007, 21, 21.
26. Regnier P., Lasaga A.C., Berner R. et al., Am. Mineralogist, 1994, 79, 809.
27. HariharanM., Varghese N., Benny Cherian A. et al., Int. J. Sci. Res. Publ., 2014, 4(10), 1.
Content type: Article
Appears in Collections:Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 2

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