https://oldena.lpnu.ua/handle/ntb/45174| Title: | Obtaining of coumarone-indene resins based on light fraction of coal tar 3. Coumarone-indene resins with methacrylic fragments |
| Other Titles: | Одержання інден-кумаронових смол з легкої фракції кам‘яно-вугільної смоли 3. Інден-кумаронові смоли з метакрилатними фрагментами |
| Authors: | Bratychak, Michael Astakhova, Olena Prysiazhnyi, Yuriy Shved, Mariia Shyshchak, Olena Namiesnik, Jacek Plonska-Brzezinska, Marta |
| Affiliation: | Lviv Polytechnic National University Gdansk University of Technology,Poland University of Bialystok, Poland |
| Bibliographic description (Ukraine): | Obtaining of coumarone-indene resins based on light fraction of coal tar 3. Coumarone-indene resins with methacrylic fragments / Michael Bratychak, Olena Astakhova, Yuriy Prysiazhnyi, Mariia Shved, Olena Shyshchak, Jacek Namiesnik, Marta Plonska-Brzezinska // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 379–385. |
| Bibliographic description (International): | Obtaining of coumarone-indene resins based on light fraction of coal tar 3. Coumarone-indene resins with methacrylic fragments / Michael Bratychak, Olena Astakhova, Yuriy Prysiazhnyi, Mariia Shved, Olena Shyshchak, Jacek Namiesnik, Marta Plonska-Brzezinska // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 379–385. |
| Is part of: | Chemistry & Chemical Technology, 3 (12), 2018 |
| Journal/Collection: | Chemistry & Chemical Technology |
| Issue: | 3 |
| Volume: | 12 |
| Issue Date: | 20-Jan-2018 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | інден-кумаронова смола кам’яно- вугільна смола метилметакрилат азоініціатор ІЧ-спектро- скопія ЯМР-спектроскопія бітум-полімерна суміш coumarone-indene resin coal tar methyl methacrylate azoinitiator IR spectroscopy NMR spectroscopy bitumen-polymeric mixture |
| Number of pages: | 7 |
| Page range: | 379-385 |
| Start page: | 379 |
| End page: | 385 |
| Abstract: | З використанням легкої фракції кам’яно-
вугільної смоли та отриманої на її основі фракції, що википає
за температур 423-463 К, з додаванням метилметакрилатy
розроблено метод одержання інден-кумаронових смол з
метакрилатними фрагментами (CIRM). CIRM отримано за
радикальною коолігомеризацією з використанням як ініціатор
2,2’-азобіс(2-метил-пропіонітрилу). Встановлено вплив кіль-
кості ініціатора, температури та тривалості реакції на
вихід, температуру розм’якшення та молекулярну масу CIRM.
Структуру синтезованих CIRM підтверджено ІЧ– та ЯМР-
спектроскопічними дослідженнями. Запропоновано використо-
вувати CIRM як полімерну складову бітум-полімерних сумішей
(БПС). Вивчено вплив кількості CIRM, температури та
тривалості на основні характеристики БПС. The method for obtaining coumarone-indene resins with methacrylic fragments (CIRM) was developed with the addition of methyl methacrylate, using a light fraction of coal tar and its fraction boiling within 423– 463 К. CIRM was obtained via radical cooligomerization using 2,2'-azobis (2-methyl-propionitrile) as the initiator. The effect of the initiator amount, temperature and reaction time on the yield, softening temperature and molecular weight of CIRM has been established. The structure of the synthesized CIRM has been confirmed by IR and NMR spectroscopy. It is proposed to use CIRM as a polymer component of bitumen-polymeric mixtures (BPS). The effect of CIRM amount, temperature and time on the main characteristics of BPS has been studied. |
| URI: | https://ena.lpnu.ua/handle/ntb/45174 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2018 ©Bratychak M., Astakhova O., Prysiazhnyi Y., Shved M., Shyshchak O., Namiesnik J., Plonska-Brzezinska M., 2018 |
| URL for reference material: | https://doi.org/10.1023/B:JMSC.0000012927.00747.83 https://doi.org/10.1002/pc.20390 https://doi.org/10.23939/chcht10.04si.631 https://doi.org/10.23939/chcht11.01.049 https://doi.org/10.1007/s11741-010-0651-3 https://doi.org/10.23939/chcht11.04.509 https://doi.org/10.23939/chcht12.01.093 https://www.chemicalbook.com/ChemicalProductProperty_ |
| References (Ukraine): | [1]McNally T. (Ed.): PolymerModified Bitumen. Properties and Characterization. Woodhead Publ., 2011. [2] Airey G.: J. Mater. Sci., 2004, 39, 951.https://doi.org/10.1023/B:JMSC.0000012927.00747.83 [3] Fang C., Li T., Zhang Z., Jing D.: Polym. Composite., 2008, 29,500. https://doi.org/10.1002/pc.20390 [4] Pyshyev S., Gunka V., Grytsenko Y., BratychakM.: Chem. Chem. Technol., 2016, 10, 631.https://doi.org/10.23939/chcht10.04si.631 [5] Bahl J., Atheya N., Singh H. et al.: Erdoel Kohle, Erdgas, Petrochem., 1993, 46, 22. [6] BratychakM., Chervinskyy T., Astakhova O. et al.: Chem. Chem. Technol., 2010, 4, 325. [7] BratychakM., Grynyshyn O., Astakhova O. et al.: Ecolog. Chem. Eng. S, 2010, 17, 309. [8] Grynyshyn O., Astakhova O., Chervinskyy T.: Chem. Chem. Technol., 2010, 4, 241. [9] Strap G., Astakhova O., Lazorko O. et al.: Chem. Chem. Technol., 2013, 7, 279. [10] BratychakM., Iatsyshyn O., Shyshchak O. et al.: Chem. Chem. Technol., 2017, 11, 49. https://doi.org/10.23939/chcht11.01.049 [11] BratychakM., GaginM., Shyshchak O., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 15. [12] BratychakM., GaginM., Shyshchak O., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 21. [13] GaginM., BratychakM., Shyshchak O., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 27. [14] Chervinskyy T., BratychakM., GaginM., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 1225. [15] Skibitskiy V., Grynyshyn O., BratychakM., Waclawek W.: Chemia i Inzyneria Ekologiczna, 2004, 11, 41. [16] BratychakM., Grynyshyn O., Shyshchak O. et al.: Ecolog. Chem. Eng., 2007, 14, 225. [17] Grynyshyn O., BratychakM., Krynytskiy V., Donchak V.: Chem. Chem. Technol., 2008, 2, 47. [18]Wu Y., Li J., Xu J. et al.: J. Shanghai Univ. Engl. Ed., 2010,14, 313. https://doi.org/10.1007/s11741-010-0651-3 [19] Sokolov V.: Inden-Kumaronovye Smoly. Metalurgia, Moskva 1978. [20] Pyshyev S., Grytsenko Y., Solodkyy S. et al.: Chem. Chem. Technol., 2015, 9, 359. [21] BratychakM., Astakhova O., Shyshchak O. et al.: Chem. Chem. Technol., 2017, 11, 509.https://doi.org/10.23939/chcht11.04.509 [22] BratychakM., Ripak O., Namiesnik J. et al.: Chem. Chem. Technol., 2018, 12, 93. https://doi.org/10.23939/chcht12.01.093 [23] https://www.chemicalbook.com/ChemicalProductProperty_ EN_CB3415111.htm. [24] BS EN 13589:2008. European Standard. Bitumen and bituminous binders. Determination of the tensile properties of modified bitumen by the force ductility method [25] BS EN 1426:2000. European Standard. Bitumen and bituminous binders. Methods of tests for petroleum and its products. Determination of needle penetration [26] BS EN 1427:2007. European Standard. Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method [27] BS EN 13614:2011. European Standard. Bitumen and bituminous binders. Determination of adhesivity of ituminous emulstions by water immersion test |
| References (International): | [1]McNally T. (Ed.): PolymerModified Bitumen. Properties and Characterization. Woodhead Publ., 2011. [2] Airey G., J. Mater. Sci., 2004, 39, 951.https://doi.org/10.1023/B:JMSC.0000012927.00747.83 [3] Fang C., Li T., Zhang Z., Jing D., Polym. Composite., 2008, 29,500. https://doi.org/10.1002/pc.20390 [4] Pyshyev S., Gunka V., Grytsenko Y., BratychakM., Chem. Chem. Technol., 2016, 10, 631.https://doi.org/10.23939/chcht10.04si.631 [5] Bahl J., Atheya N., Singh H. et al., Erdoel Kohle, Erdgas, Petrochem., 1993, 46, 22. [6] BratychakM., Chervinskyy T., Astakhova O. et al., Chem. Chem. Technol., 2010, 4, 325. [7] BratychakM., Grynyshyn O., Astakhova O. et al., Ecolog. Chem. Eng. S, 2010, 17, 309. [8] Grynyshyn O., Astakhova O., Chervinskyy T., Chem. Chem. Technol., 2010, 4, 241. [9] Strap G., Astakhova O., Lazorko O. et al., Chem. Chem. Technol., 2013, 7, 279. [10] BratychakM., Iatsyshyn O., Shyshchak O. et al., Chem. Chem. Technol., 2017, 11, 49. https://doi.org/10.23939/chcht11.01.049 [11] BratychakM., GaginM., Shyshchak O., Waclawek W., Chemia i Inzyneria Ekologiczna, 2004, 11, 15. [12] BratychakM., GaginM., Shyshchak O., Waclawek W., Chemia i Inzyneria Ekologiczna, 2004, 11, 21. [13] GaginM., BratychakM., Shyshchak O., Waclawek W., Chemia i Inzyneria Ekologiczna, 2004, 11, 27. [14] Chervinskyy T., BratychakM., GaginM., Waclawek W., Chemia i Inzyneria Ekologiczna, 2004, 11, 1225. [15] Skibitskiy V., Grynyshyn O., BratychakM., Waclawek W., Chemia i Inzyneria Ekologiczna, 2004, 11, 41. [16] BratychakM., Grynyshyn O., Shyshchak O. et al., Ecolog. Chem. Eng., 2007, 14, 225. [17] Grynyshyn O., BratychakM., Krynytskiy V., Donchak V., Chem. Chem. Technol., 2008, 2, 47. [18]Wu Y., Li J., Xu J. et al., J. Shanghai Univ. Engl. Ed., 2010,14, 313. https://doi.org/10.1007/s11741-010-0651-3 [19] Sokolov V., Inden-Kumaronovye Smoly. Metalurgia, Moskva 1978. [20] Pyshyev S., Grytsenko Y., Solodkyy S. et al., Chem. Chem. Technol., 2015, 9, 359. [21] BratychakM., Astakhova O., Shyshchak O. et al., Chem. Chem. Technol., 2017, 11, 509.https://doi.org/10.23939/chcht11.04.509 [22] BratychakM., Ripak O., Namiesnik J. et al., Chem. Chem. Technol., 2018, 12, 93. https://doi.org/10.23939/chcht12.01.093 [23] https://www.chemicalbook.com/ChemicalProductProperty_ EN_CB3415111.htm. [24] BS EN 13589:2008. European Standard. Bitumen and bituminous binders. Determination of the tensile properties of modified bitumen by the force ductility method [25] BS EN 1426:2000. European Standard. Bitumen and bituminous binders. Methods of tests for petroleum and its products. Determination of needle penetration [26] BS EN 1427:2007. European Standard. Bitumen and bituminous binders. Determination of the softening point. Ring and Ball method [27] BS EN 13614:2011. European Standard. Bitumen and bituminous binders. Determination of adhesivity of ituminous emulstions by water immersion test |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3 |
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| 2018v12n3_Bratychak_M-Obtaining_of_coumarone_379-385.pdf | 432.14 kB | Adobe PDF | View/Open | |
| 2018v12n3_Bratychak_M-Obtaining_of_coumarone_379-385__COVER.png | 526.4 kB | image/png | View/Open |
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