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Please use this identifier to cite or link to this item: https://oldena.lpnu.ua/handle/ntb/45173
Title: Lead adsorption by nano-hydroxyapatite granules in a fixed-bed column
Other Titles: Адсорбція свинцю наногранулами гідроксиапатиту в колоні з нерухомим шаром
Authors: Khademolhosseini, Mohamad Reza
Mobasherpour, Iman
Ghahremani, Davoud
Affiliation: Department of Engineering, Maybod Branch, Islamic Azad University, Maybod, Iran
Ceramics Department, Materials and Energy Research Center, Iran
Bibliographic description (Ukraine): Khademolhosseini M. R. Lead adsorption by nano-hydroxyapatite granules in a fixed-bed column / Mohamad Reza Khademolhosseini, Iman Mobasherpour, Davoud Ghahremani // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 372–378.
Bibliographic description (International): Khademolhosseini M. R. Lead adsorption by nano-hydroxyapatite granules in a fixed-bed column / Mohamad Reza Khademolhosseini, Iman Mobasherpour, Davoud Ghahremani // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 372–378.
Is part of: Chemistry & Chemical Technology, 3 (12), 2018
Journal/Collection: Chemistry & Chemical Technology
Issue: 3
Volume: 12
Issue Date: 20-Jan-2018
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Keywords: наногранули гідроксиапатиту
Pb2+
адсорбція
видалення
нерухомий шар
nano-hydroxyapatite granules
Pb2+
adsorption
removal
fixed-bed
Number of pages: 7
Page range: 372-378
Start page: 372
End page: 378
Abstract: З використанням гідроксиапатитових наногранул проведено сорбцію йонів Pb2+ в колоні з нерухомим шаром. Визначено, що час проникнення до розривання та вичерпування зменшувався зі збільшенням швидкості потоку, зменшенням глибини шару та збільшенням початкової концентрації свинцю. Запропоновано механізм процесу – часткове розчинення кальцію з наступним висадженням апатиту згідно йонообмінного механізму з формулою Ca10– xPbx(PO4)6(OH)2 і Pb10(PO4)6(OH)2.
The sorption of Pb2+ ions was conducted in a fixed-bed column by using nano-hydroxyapatite granules. The breakthrough and exhaustion time decreased with increasing flow rate, decreasing bed depth and increasing influent lead concentration. The proposed mechanism is a partial dissolution of calcium followed by the precipitation of an apatite by the ion-exchange mechanism with the formula Ca10−xPbx(PO4)6(OH)2 and Pb10(PO4)6(OH)2.
URI: https://ena.lpnu.ua/handle/ntb/45173
Copyright owner: © Національний університет „Львівська політехніка“, 2018
©Khademolhosseini M., Mobasherpour I., Ghahremani D., 2018
URL for reference material: https://doi.org/10.1016/j.envpol.2008.02.014
https://doi.org/10.1016/j.colsurfb.2007.11.013
https://doi.org/10.1016/j.jhazmat.2008.07.107
https://doi.org/10.1016/j.chemosphere.2012.07.028
https://doi.org/10.1016/j.jiec.2011.11.150
https://doi.org/10.1016/j.enggeo.2004.01.001
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https://doi.org/10.1016/j.jenvman.2009.05.030
https://doi.org/10.1016/s0032-9592(03)00132-8
https://doi.org/10.1021/ja01238a017
https://doi.org/10.1016/j.jhazmat.2005.10.019
https://doi.org/10.1016/j.jhazmat.2006.02.039
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[2] Aman T., Kazi A., Sabri M., Bano Q., Colloid Surface B, 2008,63, 116. https://doi.org/10.1016/j.colsurfb.2007.11.013
[3] Jiang Y., Pang H., Liao B., J. Hazard. Mater., 2009, 164, 1.https://doi.org/10.1016/j.jhazmat.2008.07.107
[4] Brostow W., Hagg Lobland H.:Materials: Introduction and Applications, John Wiley & Sons, New York 2017.
[5] ISIRI, (Bureau of Iran Standards) 1053, fifth revision, 2009.
[6] FAO/WHO, Evaluation of certain food additives and contaminants WHO, Lead in drinking-water 2011.
[7] Squadrone S., PrearoM., Brizio P. et al., Chemosphere, 2013,90, 358. https://doi.org/10.1016/j.chemosphere.2012.07.028
[8]Martin-LaraM., Blázquez G., Ronda A. et al., J. Ind. Eng. Chem., 2012, 18, 1006. https://doi.org/10.1016/j.jiec.2011.11.150
[9] Kalkan E., Akbulut S., Eng. Geolog., 2004, 73, 145.https://doi.org/10.1016/j.enggeo.2004.01.001
[10] Kalkan E., Appl. Clay Sci., 2009, 43, 296.https://doi.org/10.1016/j.clay.2008.09.002
[11] ZhengW., Li X., Wang F. et al., J. Hazard. Mater., 2008, 157,490. https://doi.org/10.1016/j.jhazmat.2008.01.029
[12] Krestou A., Xenidis A., Panias D.:Miner. Eng., 2004, 17, 373.https://doi.org/10.1016/j.mineng.2003.11.019
[13] Chen X., Wright J., Conca J., Peurrung L., Environ. Sci. Technol., 1997, 31, 624. https://doi.org/10.1021/es950882f
[14] CzerniczyniecM., Farias S., Magallanes J., Cicerone D., 11th Int. Conf. on Surface and Colloid Science, Brazil 2003, 269.
[15] Vega E., Pedregosa J., Narda G., J. Phys. Chem. Solids, 1999,60, 759. https://doi.org/10.1016/s0022-3697(98)00340-0
[16] Reichert J., Binner J., J. Mater Sci., 1996, 31, 1231.https://doi.org/10.1007/bf00353102
[17] Leyva A., Marrero J., Smichowski P., Cicerone D., Environ. Sci. Technol., 2001, 35, 3669. https://doi.org/10.1021/es0009929
[18] Fuller C., Bargar J., Davis J., PianaM., Environ. Sci. Technol.,2002, 36, 158. https://doi.org/10.1021/es0108483
[19]McGrellis S., Serafini J., Jean J. et al., Sep. Purif. Technol.,2001, 24, 129. https://doi.org/10.1016/s1383-5866(00)00223-9
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[21]Mobasherpour I., Salahi E., Pazouki M., J. Saudi Chem. Soc.,2011, 15, 105. https://doi.org/10.1016/j.jscs.2010.06.003
[22] Baral S., Das N., Ramulu T. et al., J. Hazard. Mater., 2009,161, 1427. https://doi.org/10.1016/j.jhazmat.2008.04.127
[23] CaleroM., Hernáinz F., Blázquez G. et al., J. Hazard. Mater.,2009, 171, 886. https://doi.org/10.1016/j.jhazmat.2009.06.082
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[27] UddinM., RukanuzzamanM., Rahman KhanM., IslamM., J. Environ. Manage., 2009, 90, 3443.https://doi.org/10.1016/j.jenvman.2009.05.030
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[29] Thomas H., J. Am. Chem. Soc., 1944, 66, 1664.https://doi.org/10.1021/ja01238a017
[30] Han R., Zhang J., Zou W. et al., J. Hazard. Mater., 2006, 133,262. https://doi.org/10.1016/j.jhazmat.2005.10.019
[31]Monteil Rivera F., FedoroffM., Encyclopedia of Surface and Colloid Science. Marcel Dekker. Inc, New York 2002.
[32] Baillez S., Nzihou A., Bernache-Assolant D. et al., J. Hazard. Mater., 2007, A139, 443.https://doi.org/10.1016/j.jhazmat.2006.02.039
Content type: Article
Appears in Collections:Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3

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