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Please use this identifier to cite or link to this item: https://oldena.lpnu.ua/handle/ntb/43929
Title: Target synthesis of functional biocompatible nanocomposites with “core-shell” structure
Other Titles: Цільовий синтезфункціональних біосумісних нанокомпозитів будови «ядро-оболонка»
Authors: Zaichenko, Alexander
Mitina, Nataliya
Miagkota, Olesia
Hevus, Orest
Bilyi, Rortyslav
Stoika, Rostyslav
Payuk, Olena
Nadashkevych, Zoriana
Voloshinovskii, Anatoliy
Affiliation: Lviv Polytechnic National University
Institute of Cell Biology NAS of Ukraine
Ivan Franko National University of Lviv
Bibliographic description (Ukraine): Target synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42.
Bibliographic description (International): Target synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42.
Is part of: Chemistry & Chemical Technology, 1 (12), 2-18
Issue: 1
Volume: 12
Issue Date: 20-Jan-2018
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Keywords: дисперсійна полімеризація
макроіні- ціатори
композиційні полімерні частинки
dispersion polymerization
macroinitiators
composite polymer particles
Number of pages: 14
Page range: 29-42
Start page: 29
End page: 42
Abstract: Металокомплексні макроініціатори були успішно застосовані для синтезу полімерних нанокомпозитів зі структурою “ядро-оболонка” методом двоступінчатої вододисперсійної полімеризації. На першому етапі формування монодисперсних полімерних частинок бажаного розміру і функціональності досягається внаслідок цілеспрямованої зміни концентрації макроініціатору, вмісту катіонів металів в його структурі, і рН середовища. Ініціювання прищеплювальної полімеризації з поверхні затравкових частинок забезпечується залишковими пероксидними фрагментами макроініціатору.
Metal-complex macroinitiators were successfully applied for the synthesis of polymer nanocomposites with core-shell structure by two-stage water dispersed polymerization. On the first stage, formation of monodispersed polymer particles of desired size and functionality is achieved by target variation of macroinitiator concentration, content of metal cations in its structure, and pH of medium. Initiation of grafted polymerization from the surface of seeded particles is provided by residual peroxide moieties of macroinitiator.
URI: https://ena.lpnu.ua/handle/ntb/43929
Copyright owner: © Національний університет „Львівська політехніка“, 2018
© Zaichenko A., Mitina N., Miagkota O., Hevus O., Bilyi R., Stoika R., Payuk O., Nadashkevych Z., Voloshinovskii A., 2018
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