https://oldena.lpnu.ua/handle/ntb/43929
Title: | Target synthesis of functional biocompatible nanocomposites with “core-shell” structure |
Other Titles: | Цільовий синтезфункціональних біосумісних нанокомпозитів будови «ядро-оболонка» |
Authors: | Zaichenko, Alexander Mitina, Nataliya Miagkota, Olesia Hevus, Orest Bilyi, Rortyslav Stoika, Rostyslav Payuk, Olena Nadashkevych, Zoriana Voloshinovskii, Anatoliy |
Affiliation: | Lviv Polytechnic National University Institute of Cell Biology NAS of Ukraine Ivan Franko National University of Lviv |
Bibliographic description (Ukraine): | Target synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42. |
Bibliographic description (International): | Target synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42. |
Is part of: | Chemistry & Chemical Technology, 1 (12), 2-18 |
Issue: | 1 |
Volume: | 12 |
Issue Date: | 20-Jan-2018 |
Publisher: | Lviv Politechnic Publishing House |
Place of the edition/event: | Lviv |
Keywords: | дисперсійна полімеризація макроіні- ціатори композиційні полімерні частинки dispersion polymerization macroinitiators composite polymer particles |
Number of pages: | 14 |
Page range: | 29-42 |
Start page: | 29 |
End page: | 42 |
Abstract: | Металокомплексні макроініціатори були
успішно застосовані для синтезу полімерних нанокомпозитів зі
структурою “ядро-оболонка” методом двоступінчатої
вододисперсійної полімеризації. На першому етапі формування
монодисперсних полімерних частинок бажаного розміру і
функціональності досягається внаслідок цілеспрямованої зміни
концентрації макроініціатору, вмісту катіонів металів в його
структурі, і рН середовища. Ініціювання прищеплювальної
полімеризації з поверхні затравкових частинок забезпечується
залишковими пероксидними фрагментами макроініціатору. Metal-complex macroinitiators were successfully applied for the synthesis of polymer nanocomposites with core-shell structure by two-stage water dispersed polymerization. On the first stage, formation of monodispersed polymer particles of desired size and functionality is achieved by target variation of macroinitiator concentration, content of metal cations in its structure, and pH of medium. Initiation of grafted polymerization from the surface of seeded particles is provided by residual peroxide moieties of macroinitiator. |
URI: | https://ena.lpnu.ua/handle/ntb/43929 |
Copyright owner: | © Національний університет „Львівська політехніка“, 2018 © Zaichenko A., Mitina N., Miagkota O., Hevus O., Bilyi R., Stoika R., Payuk O., Nadashkevych Z., Voloshinovskii A., 2018 |
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