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dc.contributor.authorZaichenko, Alexander
dc.contributor.authorMitina, Nataliya
dc.contributor.authorMiagkota, Olesia
dc.contributor.authorHevus, Orest
dc.contributor.authorBilyi, Rortyslav
dc.contributor.authorStoika, Rostyslav
dc.contributor.authorPayuk, Olena
dc.contributor.authorNadashkevych, Zoriana
dc.contributor.authorVoloshinovskii, Anatoliy
dc.date.accessioned2019-01-29T12:53:44Z-
dc.date.available2019-01-29T12:53:44Z-
dc.date.created2018-01-20
dc.date.issued2018-01-20
dc.identifier.citationTarget synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42.
dc.identifier.urihttps://ena.lpnu.ua/handle/ntb/43929-
dc.description.abstractМеталокомплексні макроініціатори були успішно застосовані для синтезу полімерних нанокомпозитів зі структурою “ядро-оболонка” методом двоступінчатої вододисперсійної полімеризації. На першому етапі формування монодисперсних полімерних частинок бажаного розміру і функціональності досягається внаслідок цілеспрямованої зміни концентрації макроініціатору, вмісту катіонів металів в його структурі, і рН середовища. Ініціювання прищеплювальної полімеризації з поверхні затравкових частинок забезпечується залишковими пероксидними фрагментами макроініціатору.
dc.description.abstractMetal-complex macroinitiators were successfully applied for the synthesis of polymer nanocomposites with core-shell structure by two-stage water dispersed polymerization. On the first stage, formation of monodispersed polymer particles of desired size and functionality is achieved by target variation of macroinitiator concentration, content of metal cations in its structure, and pH of medium. Initiation of grafted polymerization from the surface of seeded particles is provided by residual peroxide moieties of macroinitiator.
dc.format.extent29-42
dc.language.isoen
dc.publisherLviv Politechnic Publishing House
dc.relation.ispartofChemistry & Chemical Technology, 1 (12), 2-18
dc.relation.urihttps://doi.org/10.2174/1874764710801010034
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dc.relation.urihttps://doi.org/10.1002/(SICI)1097-4628(20000523)76:8<1228::AID-APP3>3.0.CO;2-8
dc.relation.urihttps://doi.org/10.1002/masy.200750839
dc.relation.urihttps://doi.org/10.1016/j.polymer.2004.11.040
dc.relation.urihttps://doi.org/10.1021/la904296h
dc.relation.urihttps://dx.doi.org/10.1002/pola.21977
dc.relation.urihttps://doi.org/10.1002/adfm.200600462
dc.relation.urihttps://doi.org/10.1088/0022-3727/43/44/445001
dc.relation.urihttps://doi.org/10.1373/clinchem.2006.071555
dc.relation.urihttps://doi.org/10.1134/S1070363208120323
dc.relation.urihttps://doi.org/10.1021/ja0680820
dc.relation.urihttps://doi.org/10.1021/ja2086323
dc.relation.urihttps://doi.org/10.1021/ac902573p
dc.relation.urihttps://doi.org/10.1002/masy.200750818
dc.relation.urihttps://doi.org/10.1002/(SICI)1099-0518(20000201)38:3<516::AID-POLA18>3.0.CO;2-R
dc.relation.urihttps://doi.org/10.1002/(SICI)1097-4628(19980207)67:6<1061::AID-APP13>3.0.CO;2-3
dc.relation.urihttps://doi.org/10.1016/j.optmat.2011.05.034
dc.subjectдисперсійна полімеризація
dc.subjectмакроіні- ціатори
dc.subjectкомпозиційні полімерні частинки
dc.subjectdispersion polymerization
dc.subjectmacroinitiators
dc.subjectcomposite polymer particles
dc.titleTarget synthesis of functional biocompatible nanocomposites with “core-shell” structure
dc.title.alternativeЦільовий синтезфункціональних біосумісних нанокомпозитів будови «ядро-оболонка»
dc.typeArticle
dc.rights.holder© Національний університет „Львівська політехніка“, 2018
dc.rights.holder© Zaichenko A., Mitina N., Miagkota O., Hevus O., Bilyi R., Stoika R., Payuk O., Nadashkevych Z., Voloshinovskii A., 2018
dc.contributor.affiliationLviv Polytechnic National University
dc.contributor.affiliationInstitute of Cell Biology NAS of Ukraine
dc.contributor.affiliationIvan Franko National University of Lviv
dc.format.pages14
dc.identifier.citationenTarget synthesis of functional biocompatible nanocomposites with “core-shell” structure / Alexander Zaichenko, Nataliya Mitina, Olesia Miagkota, Orest Hevus, Rortyslav Bilyi, Rostyslav Stoika, Olena Payuk, Zoriana Nadashkevych, Anatoliy Voloshinovskii // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 29–42.
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