https://oldena.lpnu.ua/handle/ntb/42103| Title: | Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents |
| Other Titles: | Термодинамічні властивості розчинності 2-метил-5-арилфуран-3-карбонових кислот в органічних розчинниках |
| Authors: | Sobechko, Iryna Dibrivnyi, Volodymyr Horak, Yuri Velychkivska, Nadiia Kochubei, Victoriia Obushak, Mykola |
| Affiliation: | Lviv Polytechnic National University Ivan Franko National University of Lviv Institute of Macromolecular Chemistry AS CR |
| Bibliographic description (Ukraine): | Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents / Iryna Sobechko, Volodymyr Dibrivnyi, Yuri Horak, Nadiia Velychkivska, Victoriia Kochubei, Mykola Obushak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 4. — P. 397–404. |
| Bibliographic description (International): | Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents / Iryna Sobechko, Volodymyr Dibrivnyi, Yuri Horak, Nadiia Velychkivska, Victoriia Kochubei, Mykola Obushak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 4. — P. 397–404. |
| Is part of: | Chemistry & Chemical Technology, 4 (11), 2017 |
| Issue: | 4 |
| Volume: | 11 |
| Issue Date: | 20-Jan-2017 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | ентальпія ентропія та енергія Гіббса розчинності змішування і плавлення 2-метил-5-фенілфуран-3- карбонова кислота та 2-метил-5-(4-метилфеніл)-фуран-3- карбонова кислота enthalpy entropy Gibbs energy of solubility mixing and fusion 2-methyl-5-phenylfuran-3-carboxylic acid 2-methyl-5-(4-methylphenyl)-furan-3-carboxylic acid |
| Number of pages: | 8 |
| Page range: | 397-404 |
| Start page: | 397 |
| End page: | 404 |
| Abstract: | Досліджені температурні залежності роз-
чинності обох кислот в ацетонітрилі, диметилкетоні, ізо-про-
панолі, етилацетаті та бензені. Результати представлені ліній-
ною формою рівняння Шредера, за яким визначені ентальпії,
ентропії та енергії Гіббса розчинності за 298 К. Теплоти
плавлення кислот визначені методом диференційно-термічного
аналізу, за якими розраховані ентальпії, ентропії та енергії
Гіббса змішування. Виявлений компенсаційний ефект змішування
для всіх розчинників, що містять карбонільну групу. The temperature dependencies of both acids solubility in acetonitrile, dimethylketone, isopropanol, ethylacetate and benzene were investigated. The results were represented by Shredder’s equation according to which enthalpies, entropies and Gibbs energy of solubility at 298 K were determined. Fusion heats of the acids were determined using differential thermal analysis. In accordance with obtained values the enthalpies, entropies and Gibbs energy of mixing were calculated. The compensating effect of mixing was observed for al solvents with carboxy group. |
| URI: | https://ena.lpnu.ua/handle/ntb/42103 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2017 © Sobechko I., Dibrivnyi V., Horak Y., Velychkivska N., Kochubei V., Obushak M., 2017 |
| URL for reference material: | https://doi.org/10.1021/jo026686q https://doi.org/10.1016/S0014-827X(00)00030-6 https://doi.org/10.1021/ja072817z https://doi.org/10.1134/S1070428008110213 https://doi.org/10.1134/S1070428009090103 https://doi.org/10.1134/S003602441506028X https://doi.org/10.1134/S0036024416030274 https://doi.org/10.1016/j.jct.2015.11.025 https://doi.org/10.1016/j.jct.2016.09.033 https://doi.org/10.1063/1.1529214 http://webbook.nist.gov |
| References (Ukraine): | [1] Fürstner A., Castanet A., Radkowski K., Lehmann C.: J. Org. Chem., 2003, 68, 1521. https://doi.org/10.1021/jo026686q [2] Holla B., Akberali P., ShivanandaM.: Farmaco, 2000, 55, 256.https://doi.org/10.1016/S0014-827X(00)00030-6 [3]Williams D., LeeM.-R., Song Y.-A. et al.: J. Am. Chem. Soc.,2007, 129, 9258. https://doi.org/10.1021/ja072817z [4] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R.: Russ. J. Org. Chem., 2008, 44, 1689.https://doi.org/10.1134/S1070428008110213 [5] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R.: Russ. J. Org. Chem., 2009, 45, 541. https://doi.org/10.1134/S1070428009090103 [6] Obushak N., Lesyuk A., Gorak Yu., Matiichuk V.: Russ. J. Org. Chem., 2009, 45, 1375.https://doi.org/10.1134/S1070428009090103 [7] Obushak N., Lesyuk A., Ganushchak N. et al.: J. Org. Chem. USSR (Engl. Transl.), 1986, 22, 2093. [8] Obushak N., Ganushchak N., Lesyuk A. et al.: J. Org. Chem. USSR (Engl. Transl.), 1990, 26, 748. [9] Zhu J., Bienayme H. (Eds.):Multicomponent Reactions. Wiley- VCH, Weinheim 2005. [10] Sobechko I., Van-Chin-Syan Yu., Gorak Yu. et al.: Rus. J. Phys. Chem., 2015, 89, 919.https://doi.org/10.1134/S003602441506028X [11] Sobechko I., Gorak Yu., Van-Chin-Syan Yu. et al.: Izv. Vys. Ucheb. Zaved., 2015, 58, 45. [12] Sobechko I., Prokop R., Gorak Yu. et al.: Voprosy Khimii i Khim. Techn., 2013, 4, 12. [13] Sobechko I.: Voprosy Khimii i Khim. Techn., 2014, 5-6, 48. [14] Serheyev V.: Chem. Chem. Technol., 2012, 6, 15. [15] Serheyev V.: Chem. Chem. Technol., 2015, 9, 1. [16] Serheyev V.: Rus. J. Phys. Chem., 2016, 90, 575.https://doi.org/10.1134/S0036024416030274 [17] Han S., Meng L., Du C. et al.: J. Chem. Thermodyn., 2017, 97, 17. https://doi.org/10.1016/j.jct.2015.11.025 [18] Li X., Du C., Cong Y., Zhao H.: J. Chem. Thermodyn., 2017,104, 189. https://doi.org/10.1016/j.jct.2016.09.033 [19] Chickos J., Acree W. Jr.: J. Phys. Chem. Ref. Data, 2003, 32,519. https://doi.org/10.1063/1.1529214 [20] http://webbook.nist.gov (March 18th, 2015) [21] Vasil’ev I., Petrov V.: Thermodynamicheskie Svoistva Kislorod-soderzhashih Organicheskih Veshestv. Khimiya,Leningrad 1984. |
| References (International): | [1] Fürstner A., Castanet A., Radkowski K., Lehmann C., J. Org. Chem., 2003, 68, 1521. https://doi.org/10.1021/jo026686q [2] Holla B., Akberali P., ShivanandaM., Farmaco, 2000, 55, 256.https://doi.org/10.1016/S0014-827X(00)00030-6 [3]Williams D., LeeM.-R., Song Y.-A. et al., J. Am. Chem. Soc.,2007, 129, 9258. https://doi.org/10.1021/ja072817z [4] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R., Russ. J. Org. Chem., 2008, 44, 1689.https://doi.org/10.1134/S1070428008110213 [5] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R., Russ. J. Org. Chem., 2009, 45, 541. https://doi.org/10.1134/S1070428009090103 [6] Obushak N., Lesyuk A., Gorak Yu., Matiichuk V., Russ. J. Org. Chem., 2009, 45, 1375.https://doi.org/10.1134/S1070428009090103 [7] Obushak N., Lesyuk A., Ganushchak N. et al., J. Org. Chem. USSR (Engl. Transl.), 1986, 22, 2093. [8] Obushak N., Ganushchak N., Lesyuk A. et al., J. Org. Chem. USSR (Engl. Transl.), 1990, 26, 748. [9] Zhu J., Bienayme H. (Eds.):Multicomponent Reactions. Wiley- VCH, Weinheim 2005. [10] Sobechko I., Van-Chin-Syan Yu., Gorak Yu. et al., Rus. J. Phys. Chem., 2015, 89, 919.https://doi.org/10.1134/S003602441506028X [11] Sobechko I., Gorak Yu., Van-Chin-Syan Yu. et al., Izv. Vys. Ucheb. Zaved., 2015, 58, 45. [12] Sobechko I., Prokop R., Gorak Yu. et al., Voprosy Khimii i Khim. Techn., 2013, 4, 12. [13] Sobechko I., Voprosy Khimii i Khim. Techn., 2014, 5-6, 48. [14] Serheyev V., Chem. Chem. Technol., 2012, 6, 15. [15] Serheyev V., Chem. Chem. Technol., 2015, 9, 1. [16] Serheyev V., Rus. J. Phys. Chem., 2016, 90, 575.https://doi.org/10.1134/S0036024416030274 [17] Han S., Meng L., Du C. et al., J. Chem. Thermodyn., 2017, 97, 17. https://doi.org/10.1016/j.jct.2015.11.025 [18] Li X., Du C., Cong Y., Zhao H., J. Chem. Thermodyn., 2017,104, 189. https://doi.org/10.1016/j.jct.2016.09.033 [19] Chickos J., Acree W. Jr., J. Phys. Chem. Ref. Data, 2003, 32,519. https://doi.org/10.1063/1.1529214 [20] http://webbook.nist.gov (March 18th, 2015) [21] Vasil’ev I., Petrov V., Thermodynamicheskie Svoistva Kislorod-soderzhashih Organicheskih Veshestv. Khimiya,Leningrad 1984. |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2017. – Vol. 11, No. 4 |
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| 2017v11n4_Sobechko_I-Thermodynamic_properties_397-404.pdf | 432.56 kB | Adobe PDF | View/Open | |
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