| DC Field | Value | Language |
|---|
| dc.contributor.author | Sobechko, Iryna | |
| dc.contributor.author | Dibrivnyi, Volodymyr | |
| dc.contributor.author | Horak, Yuri | |
| dc.contributor.author | Velychkivska, Nadiia | |
| dc.contributor.author | Kochubei, Victoriia | |
| dc.contributor.author | Obushak, Mykola | |
| dc.date.accessioned | 2018-06-22T13:26:09Z | - |
| dc.date.available | 2018-06-22T13:26:09Z | - |
| dc.date.created | 2017-01-20 | |
| dc.date.issued | 2017-01-20 | |
| dc.identifier.citation | Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents / Iryna Sobechko, Volodymyr Dibrivnyi, Yuri Horak, Nadiia Velychkivska, Victoriia Kochubei, Mykola Obushak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 4. — P. 397–404. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/42103 | - |
| dc.description.abstract | Досліджені температурні залежності роз-
чинності обох кислот в ацетонітрилі, диметилкетоні, ізо-про-
панолі, етилацетаті та бензені. Результати представлені ліній-
ною формою рівняння Шредера, за яким визначені ентальпії,
ентропії та енергії Гіббса розчинності за 298 К. Теплоти
плавлення кислот визначені методом диференційно-термічного
аналізу, за якими розраховані ентальпії, ентропії та енергії
Гіббса змішування. Виявлений компенсаційний ефект змішування
для всіх розчинників, що містять карбонільну групу. | |
| dc.description.abstract | The temperature dependencies of both acids
solubility in acetonitrile, dimethylketone, isopropanol,
ethylacetate and benzene were investigated. The results
were represented by Shredder’s equation according to
which enthalpies, entropies and Gibbs energy of solubility
at 298 K were determined. Fusion heats of the acids were
determined using differential thermal analysis. In
accordance with obtained values the enthalpies, entropies
and Gibbs energy of mixing were calculated. The
compensating effect of mixing was observed for al
solvents with carboxy group. | |
| dc.format.extent | 397-404 | |
| dc.language.iso | en | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry & Chemical Technology, 4 (11), 2017 | |
| dc.relation.uri | https://doi.org/10.1021/jo026686q | |
| dc.relation.uri | https://doi.org/10.1016/S0014-827X(00)00030-6 | |
| dc.relation.uri | https://doi.org/10.1021/ja072817z | |
| dc.relation.uri | https://doi.org/10.1134/S1070428008110213 | |
| dc.relation.uri | https://doi.org/10.1134/S1070428009090103 | |
| dc.relation.uri | https://doi.org/10.1134/S003602441506028X | |
| dc.relation.uri | https://doi.org/10.1134/S0036024416030274 | |
| dc.relation.uri | https://doi.org/10.1016/j.jct.2015.11.025 | |
| dc.relation.uri | https://doi.org/10.1016/j.jct.2016.09.033 | |
| dc.relation.uri | https://doi.org/10.1063/1.1529214 | |
| dc.relation.uri | http://webbook.nist.gov | |
| dc.subject | ентальпія | |
| dc.subject | ентропія та енергія Гіббса розчинності | |
| dc.subject | змішування і плавлення | |
| dc.subject | 2-метил-5-фенілфуран-3- карбонова кислота та 2-метил-5-(4-метилфеніл)-фуран-3- карбонова кислота | |
| dc.subject | enthalpy | |
| dc.subject | entropy | |
| dc.subject | Gibbs energy of solubility | |
| dc.subject | mixing and fusion | |
| dc.subject | 2-methyl-5-phenylfuran-3-carboxylic acid | |
| dc.subject | 2-methyl-5-(4-methylphenyl)-furan-3-carboxylic acid | |
| dc.title | Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents | |
| dc.title.alternative | Термодинамічні властивості розчинності 2-метил-5-арилфуран-3-карбонових кислот в органічних розчинниках | |
| dc.type | Article | |
| dc.rights.holder | © Національний університет „Львівська політехніка“, 2017 | |
| dc.rights.holder | © Sobechko I., Dibrivnyi V., Horak Y., Velychkivska N., Kochubei V., Obushak M., 2017 | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.affiliation | Ivan Franko National University of Lviv | |
| dc.contributor.affiliation | Institute of Macromolecular Chemistry AS CR | |
| dc.format.pages | 8 | |
| dc.identifier.citationen | Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents / Iryna Sobechko, Volodymyr Dibrivnyi, Yuri Horak, Nadiia Velychkivska, Victoriia Kochubei, Mykola Obushak // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 4. — P. 397–404. | |
| dc.relation.references | [1] Fürstner A., Castanet A., Radkowski K., Lehmann C.: J. Org. Chem., 2003, 68, 1521. https://doi.org/10.1021/jo026686q | |
| dc.relation.references | [2] Holla B., Akberali P., ShivanandaM.: Farmaco, 2000, 55, 256.https://doi.org/10.1016/S0014-827X(00)00030-6 | |
| dc.relation.references | [3]Williams D., LeeM.-R., Song Y.-A. et al.: J. Am. Chem. Soc.,2007, 129, 9258. https://doi.org/10.1021/ja072817z | |
| dc.relation.references | [4] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R.: Russ. J. Org. Chem., 2008, 44, 1689.https://doi.org/10.1134/S1070428008110213 | |
| dc.relation.references | [5] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R.: Russ. J. Org. Chem., 2009, 45, 541. https://doi.org/10.1134/S1070428009090103 | |
| dc.relation.references | [6] Obushak N., Lesyuk A., Gorak Yu., Matiichuk V.: Russ. J. Org. Chem., 2009, 45, 1375.https://doi.org/10.1134/S1070428009090103 | |
| dc.relation.references | [7] Obushak N., Lesyuk A., Ganushchak N. et al.: J. Org. Chem. USSR (Engl. Transl.), 1986, 22, 2093. | |
| dc.relation.references | [8] Obushak N., Ganushchak N., Lesyuk A. et al.: J. Org. Chem. USSR (Engl. Transl.), 1990, 26, 748. | |
| dc.relation.references | [9] Zhu J., Bienayme H. (Eds.):Multicomponent Reactions. Wiley- VCH, Weinheim 2005. | |
| dc.relation.references | [10] Sobechko I., Van-Chin-Syan Yu., Gorak Yu. et al.: Rus. J. Phys. Chem., 2015, 89, 919.https://doi.org/10.1134/S003602441506028X | |
| dc.relation.references | [11] Sobechko I., Gorak Yu., Van-Chin-Syan Yu. et al.: Izv. Vys. Ucheb. Zaved., 2015, 58, 45. | |
| dc.relation.references | [12] Sobechko I., Prokop R., Gorak Yu. et al.: Voprosy Khimii i Khim. Techn., 2013, 4, 12. | |
| dc.relation.references | [13] Sobechko I.: Voprosy Khimii i Khim. Techn., 2014, 5-6, 48. | |
| dc.relation.references | [14] Serheyev V.: Chem. Chem. Technol., 2012, 6, 15. | |
| dc.relation.references | [15] Serheyev V.: Chem. Chem. Technol., 2015, 9, 1. | |
| dc.relation.references | [16] Serheyev V.: Rus. J. Phys. Chem., 2016, 90, 575.https://doi.org/10.1134/S0036024416030274 | |
| dc.relation.references | [17] Han S., Meng L., Du C. et al.: J. Chem. Thermodyn., 2017, 97, 17. https://doi.org/10.1016/j.jct.2015.11.025 | |
| dc.relation.references | [18] Li X., Du C., Cong Y., Zhao H.: J. Chem. Thermodyn., 2017,104, 189. https://doi.org/10.1016/j.jct.2016.09.033 | |
| dc.relation.references | [19] Chickos J., Acree W. Jr.: J. Phys. Chem. Ref. Data, 2003, 32,519. https://doi.org/10.1063/1.1529214 | |
| dc.relation.references | [20] http://webbook.nist.gov (March 18th, 2015) | |
| dc.relation.references | [21] Vasil’ev I., Petrov V.: Thermodynamicheskie Svoistva Kislorod-soderzhashih Organicheskih Veshestv. Khimiya,Leningrad 1984. | |
| dc.relation.referencesen | [1] Fürstner A., Castanet A., Radkowski K., Lehmann C., J. Org. Chem., 2003, 68, 1521. https://doi.org/10.1021/jo026686q | |
| dc.relation.referencesen | [2] Holla B., Akberali P., ShivanandaM., Farmaco, 2000, 55, 256.https://doi.org/10.1016/S0014-827X(00)00030-6 | |
| dc.relation.referencesen | [3]Williams D., LeeM.-R., Song Y.-A. et al., J. Am. Chem. Soc.,2007, 129, 9258. https://doi.org/10.1021/ja072817z | |
| dc.relation.referencesen | [4] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R., Russ. J. Org. Chem., 2008, 44, 1689.https://doi.org/10.1134/S1070428008110213 | |
| dc.relation.referencesen | [5] Obushak N., Gorak Yu., Matiichuk V., Lytvyn R., Russ. J. Org. Chem., 2009, 45, 541. https://doi.org/10.1134/S1070428009090103 | |
| dc.relation.referencesen | [6] Obushak N., Lesyuk A., Gorak Yu., Matiichuk V., Russ. J. Org. Chem., 2009, 45, 1375.https://doi.org/10.1134/S1070428009090103 | |
| dc.relation.referencesen | [7] Obushak N., Lesyuk A., Ganushchak N. et al., J. Org. Chem. USSR (Engl. Transl.), 1986, 22, 2093. | |
| dc.relation.referencesen | [8] Obushak N., Ganushchak N., Lesyuk A. et al., J. Org. Chem. USSR (Engl. Transl.), 1990, 26, 748. | |
| dc.relation.referencesen | [9] Zhu J., Bienayme H. (Eds.):Multicomponent Reactions. Wiley- VCH, Weinheim 2005. | |
| dc.relation.referencesen | [10] Sobechko I., Van-Chin-Syan Yu., Gorak Yu. et al., Rus. J. Phys. Chem., 2015, 89, 919.https://doi.org/10.1134/S003602441506028X | |
| dc.relation.referencesen | [11] Sobechko I., Gorak Yu., Van-Chin-Syan Yu. et al., Izv. Vys. Ucheb. Zaved., 2015, 58, 45. | |
| dc.relation.referencesen | [12] Sobechko I., Prokop R., Gorak Yu. et al., Voprosy Khimii i Khim. Techn., 2013, 4, 12. | |
| dc.relation.referencesen | [13] Sobechko I., Voprosy Khimii i Khim. Techn., 2014, 5-6, 48. | |
| dc.relation.referencesen | [14] Serheyev V., Chem. Chem. Technol., 2012, 6, 15. | |
| dc.relation.referencesen | [15] Serheyev V., Chem. Chem. Technol., 2015, 9, 1. | |
| dc.relation.referencesen | [16] Serheyev V., Rus. J. Phys. Chem., 2016, 90, 575.https://doi.org/10.1134/S0036024416030274 | |
| dc.relation.referencesen | [17] Han S., Meng L., Du C. et al., J. Chem. Thermodyn., 2017, 97, 17. https://doi.org/10.1016/j.jct.2015.11.025 | |
| dc.relation.referencesen | [18] Li X., Du C., Cong Y., Zhao H., J. Chem. Thermodyn., 2017,104, 189. https://doi.org/10.1016/j.jct.2016.09.033 | |
| dc.relation.referencesen | [19] Chickos J., Acree W. Jr., J. Phys. Chem. Ref. Data, 2003, 32,519. https://doi.org/10.1063/1.1529214 | |
| dc.relation.referencesen | [20] http://webbook.nist.gov (March 18th, 2015) | |
| dc.relation.referencesen | [21] Vasil’ev I., Petrov V., Thermodynamicheskie Svoistva Kislorod-soderzhashih Organicheskih Veshestv. Khimiya,Leningrad 1984. | |
| dc.citation.volume | 11 | |
| dc.citation.issue | 4 | |
| dc.citation.spage | 397 | |
| dc.citation.epage | 404 | |
| dc.coverage.placename | Lviv | |
| Appears in Collections: | Chemistry & Chemical Technology. – 2017. – Vol. 11, No. 4
|
