| DC Field | Value | Language |
|---|
| dc.contributor.author | Мельник, Ю. Я. | |
| dc.contributor.author | Кос, П. О. | |
| dc.contributor.author | Суберляк, О. В. | |
| dc.contributor.author | Melnyk, Yu. | |
| dc.contributor.author | Kos, P. | |
| dc.contributor.author | Suberlyak, O. | |
| dc.date.accessioned | 2021-01-28T11:24:15Z | - |
| dc.date.available | 2021-01-28T11:24:15Z | - |
| dc.date.created | 2020-02-24 | |
| dc.date.issued | 2020-02-24 | |
| dc.identifier.citation | Мельник Ю. Я. Дослідження кінетики прищепленої полімеризації у тонкому шарі 2-гідроксіетилметакрилату з полівінілпіролідоном / Ю. Я. Мельник, П. О. Кос, О. В. Суберляк // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Том 3. — № 1. — С. 209–213. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/56087 | - |
| dc.description.abstract | Досліджено кінетику полімеризації 2-гідроксіетилметакрилату з полівінілпіролідоном
у тонкому шарі. Побудовано екзотерми реакції (ко)полімеризації в масі. Визначено порядок
реакції за ініціатором, мономером і полімером та виведено математичну залежність
сумарної швидкості прищепленої кополімеризації ГЕМА до ПВП. Визначено залежність
кількості ПВП, що бере участь у реакції прищепленої полімеризації від його концентрації в
композиції, природи та концентрації ініціатора і температури процесу. | |
| dc.description.abstract | The kinetics of polymerization of 2-hydroxyethyl methacrylate with polyvinylpyrrolidone in a thin
layer were studied. The dependences of the conversion for polymerization HEMA with PVP in mass and in
solvent were determined. (Co)polymerization exotherms for the reaction in mass were calculated. The
reaction order by initiator, monomer and polymer was determined and the mathematical dependence of the
total rate of grafted copolymerization of HEMA to PVP was calculated. Amount of the reacted PVP in the
graft polymerization reaction in dependence on concentration, nature and concentration of the initiator in
the composition and temperature was determined. | |
| dc.format.extent | 209-213 | |
| dc.language.iso | uk | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry, Technology and Application of Substances, 1 (3), 2020 | |
| dc.relation.uri | https://doi.org/10.1016/S0142-9612(01)00035-7 | |
| dc.relation.uri | https://doi.org/10.23939/ctas2019.01.121 | |
| dc.relation.uri | https://doi.org/10.1021/ac60081a031 | |
| dc.relation.uri | https://doi.org/10.1002/apmc.1983.051180101 | |
| dc.subject | 2-гідроксіетилметакрилат | |
| dc.subject | полівінілпіролідон | |
| dc.subject | полімеризація | |
| dc.subject | тонкий шар | |
| dc.subject | кінетика | |
| dc.subject | прищеплений кополімер | |
| dc.subject | 2-hydroxyethyl methacrylate | |
| dc.subject | polyvinylpyrrolidone | |
| dc.subject | polymerization | |
| dc.subject | kinetics | |
| dc.subject | thin layer | |
| dc.subject | graft copolymer | |
| dc.title | Дослідження кінетики прищепленої полімеризації у тонкому шарі 2-гідроксіетилметакрилату з полівінілпіролідоном | |
| dc.title.alternative | Investigation of the kinetics of graft polymerization in a thin layer of 2-hydroxiethyl methacrylate with polyvinylpyrrolidone | |
| dc.type | Article | |
| dc.rights.holder | © Національний університет “Львівська політехніка”, 2020 | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.format.pages | 5 | |
| dc.identifier.citationen | Melnyk Yu. Investigation of the kinetics of graft polymerization in a thin layer of 2-hydroxiethyl methacrylate with polyvinylpyrrolidone / Yu. Melnyk, P. Kos, O. Suberlyak // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 3. — No 1. — P. 209–213. | |
| dc.identifier.doi | doi.org/10.23939/ctas2020.01.209 | |
| dc.relation.references | 1. Lavrov, N. A., &Kryzhanovskaya, T. S. (1995). Poliakrilaty v meditsine. Plasticheskiye massy, 2, 42–43. | |
| dc.relation.references | 2. Lavrov, N. A.,& Nikolayev, A. F. (1986). Oblasti primeneniya polimerov na osnove 2-gidroksietilmetakrilata. Plasticheskiye massy, 8, 55–57. | |
| dc.relation.references | 3. García-Millán, E., Koprivnik, S., &Otero-Espinar, F. J. (2015). Drug loading optimization and extended drug delivery of corticoids from pHEMA based soft contact lenses hydrogels via chemical and microstructural modifications. International Journal of Pharmaceutics, 487(1-2), 260-269. doi: 10.1016/j.ijpharm.2015.04.037 | |
| dc.relation.references | 4. Hoch, G., Chauhan, A., & Radke, C. J. (2003). Permeability and diffusivity for water transport through hydrogel membranes. Journal of Membrane Science, 214(2), 199–209. doi: 10.1016/S0376-7388(02)00546-X | |
| dc.relation.references | 5. Dziubla, T. D., Torjman, M. C., Joseph, J. I., Murphy- Tatum, M., & Lowman, A. M. (2001). Evaluation of porous networks of poly(2-hydroxyethyl methacrylate) as interfacial drug delivery devices. Biomaterials, 22(21), 2893–2899. https://doi.org/10.1016/S0142-9612(01)00035-7 | |
| dc.relation.references | 6. Saini, R. K., Bagri, L. P., & Bajpai, A. K. (2014). Poly(2-hydroxyethyl methacrylate) (PHEMA) based nanoparticles for drug delivery applications: A review. Nano Science and Nano Technology: An Indian Journal, 8(11), 416–427. | |
| dc.relation.references | 7. Skorokhoda, V., Melnyk, Y., Semenyuk, N, & Suberlyak, O. (2015). Obtaining peculiarities and properties of polyvinylpyrrolidone copolymers with hydrophobic vinyl monomers. Chemistry& Chemical Technology, 9(1), 55–59. | |
| dc.relation.references | 8. Skorokhoda, V. Y., Melnyk, Yu. Ya., Shalata, V. Ya., Skorokhoda, T. V., & Suberliak, S. A. (2017). An investigation of obtaining patterns, structure and diffusion properties of biomedical purpose hydrogel membranes. Eastern-European Journal of Enterprise Technologies.1, 6(85), 50-55. doi: 10.15587/1729-4061.2017.92368 | |
| dc.relation.references | 9. Skorokhoda, V., Melnyk, Y., Semenyuk, N., Ortynska, N., & Suberlyak, O. (2017). Film hydrogels on the basis of polyvinylpyrrolidone copolymers with regulated sorption-desorption characteristics. Chemistry & Chemical Technolog, 11(2), 171–174. doi: 10.15587/1729-4061.2017.92368 | |
| dc.relation.references | 10. Skorokhoda, V. Y., Semenyuk, N. B., Dzyaman, I. Z., Levyts’ka, KH. V., &Dudok H. D. (2018). Vplyv pryrody kal’tsiyevmisnoho napovnyuvacha na zakonomirnosti oderzhannya ta vlastyvosti osteoplastychnykh porystykh kompozytiv. Pytannya khimiyi i khimichnoyi tekhnolohiyi, 2(117), 101–108. | |
| dc.relation.references | 11. Skorokhoda, V. Y., Dudok, H. D., Dzyaman, I. Z., &Kysil’, KH. V. (2019). Intensyfikatsiya protsesu oderzhannya osteoplastychnykh porystykh kompozytiv z vykorystannyam ul’trazvuku. Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2(1), 121–126. doi: https://doi.org/10.23939/ctas2019.01.121 | |
| dc.relation.references | 12. Levy, G. B., Fergus, D. (1953). Microdetermination of polyvinylpyrrolidone in aqueous solution and in body fluids. Аnа1ytical Chemistry, 25(9), 1408–1410. https://doi.org/10.1021/ac60081a031 | |
| dc.relation.references | 13. Baghdasaryan, X. S. (1966). The theory of radical polymerization. Moscow: Science. | |
| dc.relation.references | 14. Berlin, A. A., Vol’fson, S. A., & Yenikopyan, N. S. (1978). Kinetika polimerizatsionnykh protsessov. Moskva: Khimiya. | |
| dc.relation.references | 15. Staszewska, D. U. (1983). The oxidation of poly- (vinyl pyrrolidone) with Ce(IV). MacromolecularMaterials and Engineering, 118(1), 1-17. doi:https://doi.org/10.1002/apmc.1983.051180101 | |
| dc.relation.references | 16. Suberlyak, O. V., Skorokhoda,V. I., &Tir, I. G. (1989). Vliyaniye kompleksoobrazovaniya na polimerizatsiyu 2-oksietilenmetakrilata v prisutstvii polivinilpirrolidona. Vysokomolekulyarnyye soyedineniya, 31(5B), 336–340. | |
| dc.relation.referencesen | 1. Lavrov, N. A., &Kryzhanovskaya, T. S. (1995). Poliakrilaty v meditsine. Plasticheskiye massy, 2, 42–43. | |
| dc.relation.referencesen | 2. Lavrov, N. A.,& Nikolayev, A. F. (1986). Oblasti primeneniya polimerov na osnove 2-gidroksietilmetakrilata. Plasticheskiye massy, 8, 55–57. | |
| dc.relation.referencesen | 3. García-Millán, E., Koprivnik, S., &Otero-Espinar, F. J. (2015). Drug loading optimization and extended drug delivery of corticoids from pHEMA based soft contact lenses hydrogels via chemical and microstructural modifications. International Journal of Pharmaceutics, 487(1-2), 260-269. doi: 10.1016/j.ijpharm.2015.04.037 | |
| dc.relation.referencesen | 4. Hoch, G., Chauhan, A., & Radke, C. J. (2003). Permeability and diffusivity for water transport through hydrogel membranes. Journal of Membrane Science, 214(2), 199–209. doi: 10.1016/S0376-7388(02)00546-X | |
| dc.relation.referencesen | 5. Dziubla, T. D., Torjman, M. C., Joseph, J. I., Murphy- Tatum, M., & Lowman, A. M. (2001). Evaluation of porous networks of poly(2-hydroxyethyl methacrylate) as interfacial drug delivery devices. Biomaterials, 22(21), 2893–2899. https://doi.org/10.1016/S0142-9612(01)00035-7 | |
| dc.relation.referencesen | 6. Saini, R. K., Bagri, L. P., & Bajpai, A. K. (2014). Poly(2-hydroxyethyl methacrylate) (PHEMA) based nanoparticles for drug delivery applications: A review. Nano Science and Nano Technology: An Indian Journal, 8(11), 416–427. | |
| dc.relation.referencesen | 7. Skorokhoda, V., Melnyk, Y., Semenyuk, N, & Suberlyak, O. (2015). Obtaining peculiarities and properties of polyvinylpyrrolidone copolymers with hydrophobic vinyl monomers. Chemistry& Chemical Technology, 9(1), 55–59. | |
| dc.relation.referencesen | 8. Skorokhoda, V. Y., Melnyk, Yu. Ya., Shalata, V. Ya., Skorokhoda, T. V., & Suberliak, S. A. (2017). An investigation of obtaining patterns, structure and diffusion properties of biomedical purpose hydrogel membranes. Eastern-European Journal of Enterprise Technologies.1, 6(85), 50-55. doi: 10.15587/1729-4061.2017.92368 | |
| dc.relation.referencesen | 9. Skorokhoda, V., Melnyk, Y., Semenyuk, N., Ortynska, N., & Suberlyak, O. (2017). Film hydrogels on the basis of polyvinylpyrrolidone copolymers with regulated sorption-desorption characteristics. Chemistry & Chemical Technolog, 11(2), 171–174. doi: 10.15587/1729-4061.2017.92368 | |
| dc.relation.referencesen | 10. Skorokhoda, V. Y., Semenyuk, N. B., Dzyaman, I. Z., Levyts’ka, KH. V., &Dudok H. D. (2018). Vplyv pryrody kal’tsiyevmisnoho napovnyuvacha na zakonomirnosti oderzhannya ta vlastyvosti osteoplastychnykh porystykh kompozytiv. Pytannya khimiyi i khimichnoyi tekhnolohiyi, 2(117), 101–108. | |
| dc.relation.referencesen | 11. Skorokhoda, V. Y., Dudok, H. D., Dzyaman, I. Z., &Kysil’, KH. V. (2019). Intensyfikatsiya protsesu oderzhannya osteoplastychnykh porystykh kompozytiv z vykorystannyam ul’trazvuku. Khimiya, tekhnolohiya rechovyn ta yikh zastosuvannya, 2(1), 121–126. doi: https://doi.org/10.23939/ctas2019.01.121 | |
| dc.relation.referencesen | 12. Levy, G. B., Fergus, D. (1953). Microdetermination of polyvinylpyrrolidone in aqueous solution and in body fluids. Ana1ytical Chemistry, 25(9), 1408–1410. https://doi.org/10.1021/ac60081a031 | |
| dc.relation.referencesen | 13. Baghdasaryan, X. S. (1966). The theory of radical polymerization. Moscow: Science. | |
| dc.relation.referencesen | 14. Berlin, A. A., Vol’fson, S. A., & Yenikopyan, N. S. (1978). Kinetika polimerizatsionnykh protsessov. Moskva: Khimiya. | |
| dc.relation.referencesen | 15. Staszewska, D. U. (1983). The oxidation of poly- (vinyl pyrrolidone) with Ce(IV). MacromolecularMaterials and Engineering, 118(1), 1-17. doi:https://doi.org/10.1002/apmc.1983.051180101 | |
| dc.relation.referencesen | 16. Suberlyak, O. V., Skorokhoda,V. I., &Tir, I. G. (1989). Vliyaniye kompleksoobrazovaniya na polimerizatsiyu 2-oksietilenmetakrilata v prisutstvii polivinilpirrolidona. Vysokomolekulyarnyye soyedineniya, 31(5B), 336–340. | |
| dc.citation.issue | 1 | |
| dc.citation.spage | 209 | |
| dc.citation.epage | 213 | |
| dc.coverage.placename | Lviv | |
| dc.coverage.placename | Lviv | |
| Appears in Collections: | Chemistry, Technology and Application of Substances. – 2020. – Vol. 3, No. 1
|
