https://oldena.lpnu.ua/handle/ntb/55794| Title: | Ferrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization |
| Other Titles: | Ферроценілметилнуклеїнові основи: синтез, розрахунок ДПФ, електрохімічна та спектроскопічна характеристика |
| Authors: | Lanez, Elhafnaoui Bechki, Lazhar Lanez, Touhami |
| Affiliation: | University of El Oued University of Ouargla |
| Bibliographic description (Ukraine): | Lanez E. Ferrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization / Elhafnaoui Lanez, Lazhar Bechki, Touhami Lanez // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 146–153. |
| Bibliographic description (International): | Lanez E. Ferrocenylmethylnucleobases: Synthesis, DFT Calculations, Electrochemical and Spectroscopic Characterization / Elhafnaoui Lanez, Lazhar Bechki, Touhami Lanez // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 146–153. |
| Is part of: | Chemistry & Chemical Technology, 2 (14), 2020 |
| Issue: | 2 |
| Volume: | 14 |
| Issue Date: | 24-Jan-2020 |
| Publisher: | Видавництво Львівської політехніки Lviv Politechnic Publishing House |
| Place of the edition/event: | Львів Lviv |
| DOI: | doi.org/10.23939/chcht14.02.146 |
| Keywords: | нуклеїнові основи фероцен циклічна вольтамперометрія УФ-спектроскопія ДПФ nucleobases ferrocene cyclic voltammetry Uv-Vis spectroscopy DFT |
| Number of pages: | 8 |
| Page range: | 146-153 |
| Start page: | 146 |
| End page: | 153 |
| Abstract: | Синтезовані три ферроценілметилнуклеїнові основи (FcMeNb). За допомогою методів циклічної
вольтамперометрії, абсорбційної електронної спектроскопії,
Фур‘є-спектроскопії та ЯМР-спектроскопії охарактеризовано
синтезовані сполуки. Енергію прикордонних молекулярних
орбіталей визначено за методом DFT/B3LYP у поєднанні з
базовим набором 6-311++G(d, p) в ацетонітрилі. Встановлено,
що нижчі стандартні константи швидкостей сполук FcMeNb
порівняно з ферроценом вказують на більш повільну кінетику переносу електронів. Three ferrocenylmethylnucleobases (FcMeNb) were synthesized and characterized by cyclic voltammetry, electronic absorption, FT-IR and NMR spectroscopy. The energy of frontier molecular orbitals was determined using DFT/B3LYP method combined with 6-311++G(d,p) basis set in acetonitrile. The lower standard rate constant values of the FcMeNb compounds as compared to ferrocene indicated slower electron transfer kinetics. |
| URI: | https://ena.lpnu.ua/handle/ntb/55794 |
| Copyright owner: | © Національний університет “Львівська політехніка”, 2020 © Lanez E., Bechki L., Lanez T., 2020 |
| URL for reference material: | https://doi.org/10.1039/P19890002075 https://doi.org/10.1039/P19900002437 https://doi.org/10.1002/aoc.3664 https://doi.org/10.2174/1389557516666161031141620 https://doi.org/10.1016/S0022-328X(00)90515-1 https://doi.org/10.1039/DT9960004115 https://doi.org/10.1039/A905168F https://doi.org/10.1002/cplu.201600462 https://doi.org/10.1016/j.ccr.2016.02.008 https://doi.org/10.1002/ejoc.200390025 https://doi.org/10.1021/jm0110284 https://doi.org/10.1016/S0960-894X(99)00133-X https://doi.org/10.1016/S0968-0896(02)00253-5 https://doi.org/10.1038/323464a0 https://doi.org/10.2165/00003495-199447010-00009 https://doi.org/10.1016/j.ejmech.2011.10.050 https://doi.org/10.1021/bc049697u https://doi.org/10.1016/0223-5234(91)90070-4 https://doi.org/10.23939/chcht13.01.011 https://doi.org/ https://doi.org/10.1002/aoc.1500 https://doi.org/10.1021/om5000453 https://doi.org/10.1039/JR9580000656 https://doi.org/10.1021/ac60210a007 https://doi.org/10.1021/ac60230a016 https://doi.org/10.1021/ja00905a001 |
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| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 2 |
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