https://oldena.lpnu.ua/handle/ntb/55781| Title: | Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes |
| Other Titles: | Електрохімічний синтез пероксиоцтової кислоти на Pt/PtO та PbO2 анодах |
| Authors: | Bilous, Tetiana Tulskaya, Alena Ryshchenko, Igor Chahine, Issam Bairachnyi, Volodymyr |
| Affiliation: | National Technical University “Kharkiv Polytechnic Institute” |
| Bibliographic description (Ukraine): | Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes / Tetiana Bilous, Alena Tulskaya, Igor Ryshchenko, Issam Chahine, Volodymyr Bairachnyi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 135–138. |
| Bibliographic description (International): | Electrochemical Synthesis of Peroxyacetic Acid on Pt/PtO and PbO2 Anodes / Tetiana Bilous, Alena Tulskaya, Igor Ryshchenko, Issam Chahine, Volodymyr Bairachnyi // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 2. — P. 135–138. |
| Is part of: | Chemistry & Chemical Technology, 2 (14), 2020 |
| Issue: | 2 |
| Volume: | 14 |
| Issue Date: | 24-Jan-2020 |
| Publisher: | Видавництво Львівської політехніки Lviv Politechnic Publishing House |
| Place of the edition/event: | Львів Lviv |
| DOI: | doi.org/10.23939/chcht14.02.135 |
| Keywords: | пероксиоцтова кислота оцтова кислота платиновий анод диоксид свинцевий анод промотор перокси-частинки peroxyacetic acid acetic acid platinum anode lead-dioxide anode promoter peroxide particles |
| Number of pages: | 4 |
| Page range: | 135-138 |
| Start page: | 135 |
| End page: | 138 |
| Abstract: | Вивчена кінетика анодних процесів на Pt/PtO та PbO2 анодах у водних розчинах оцтової кислоти.
Встановлено, що додавання сульфатної кислоти має каталітичний ефект в електрохімічному синтезі пероксиоцтової
кислоти. Обґрунтовано вибір промоторів утворення пероксичастинок. Виявлено, що I–, Cl– (вихід за струмом 1.2–1.5 %)
частинки є найбільш ефективними для платинового аноду та I–, F–(вихід за струмом 0.50–0.55 %) – найбільш ефективні для диоксид свинцевого аноду. The kinetics of anodic processes on Pt/PtO and PbO2 anodes has been studied in water solutions of acetic acid. The addition of sulfuric acid has a catalytic effect in the electrochemical synthesis of peroxyacetic acid. The choice of promoters of peroxide-particles formation has been proved. I–, Cl–(current efficiency is 1.2–1.5 %) particles have been defined as the most effective for platinum anode and I–, F–(current efficiency is 0.50–0.55 %) have been defined as the most effective for lead-dioxide anode. |
| URI: | https://ena.lpnu.ua/handle/ntb/55781 |
| Copyright owner: | © Національний університет “Львівська політехніка”, 2020 © Bilous T., Tulskaya A., Ryshchenko I., Chahine I., Bairachnyi V., 2020 |
| URL for reference material: | https://doi.org/10.1007/s11176-005-0378-8 https://doi.org/10.1016/j.molcata.2007.03.012 https://doi.org/10.1016/j.molcata.2008.01.003 https://doi.org/10.1016/S1004-9541(11)60078-5 https://doi.org/10.1016/S1004-9541(07)60087-1 https://doi.org/10.1016/j.elecom.2016.10.010 https://doi.org/10.1016/S1388-2481(03)00097-3 https://doi.org/10.1021/ie2009422 https://doi.org/10.3103/S106837551406009X https://doi.org/10.1007/s10800-009-9792-7 https://doi.org/10.1007/s11175-005-0198-5 |
| References (Ukraine): | [1] Dul’neva L., Moskvin A.: Russ. J. Gen. Chem., 2005, 75, 1125. https://doi.org/10.1007/s11176-005-0378-8 [2] Zhao X., Zhang T., Zhou Y., Liu D.: J. Mol. Catal. A, 2007, 271, 246. https://doi.org/10.1016/j.molcata.2007.03.012 [3] Zhao X., Cheng K., Hao J., Liu D.: J. Mol. Catal. A, 2008, 284, 58. https://doi.org/10.1016/j.molcata.2008.01.003 [4] Zhao X., Zhang T., Zhou Y., Liu D.: Chinese J. Process Eng., 2008, 8, 35. [5] Sun X., Zhao X., Du W., Liu D.: Chinese J. Chem. Eng., 2011, 19, 964. https://doi.org/10.1016/S1004-9541(11)60078-5 [6] Zhang T., Luo J., Chuang K., Zhong L.: Chinese J. Chem. Eng., 2007, 15, 320. https://doi.org/10.1016/S1004-9541(07)60087-1 [7] Moraleda I., Llanos J., Sáez C. et al.: Electrochem. Commun., 2016, 73, 1. https://doi.org/10.1016/j.elecom.2016.10.010 [8] Saha M., Denggerile A., Nishiki Y. et al.: Electrochem. Commun., 2003, 5, 445. https://doi.org/10.1016/S1388-2481(03)00097-3 [9] Cotillas S., Sánchez-Carretero A., Cañizares P. et al.: Ind. Eng. Chem. Res., 2011, 50, 10889. https://doi.org/10.1021/ie2009422 [10] Ruiz-Ruiz E., Meas Y., Ortega-Borges R., Baizabal J.: Surf. Eng. Appl. Electrochem., 2014, 50, 478. https://doi.org/10.3103/S106837551406009X [11] Cañizares P., Sáez C., Sánchez-Carretero A., Rodrigo M.: J. Appl. Electrochem., 2009, 39, 2143. https://doi.org/10.1007/s10800-009-9792-7 [12] Bilous T., Tulsky G.: Kinetics of Anodic Processes in Acetic Acid Solutions. [in:] Barsukov V. (Ed.), Promising Materials and Processes in Technical Electrochemistry. KNUTD, Kyiv 2016, 244-248. [13] Bilous T., Tulskaya A., Matrunchyk O.: The Choice of Anode Material for the Electrochemical Synthesis of Peroxyacetic Acid. [in:] Barsukov V. (Ed.), Promising Materials and Processes in Applied Electrochemistry. KNUTD, Kyiv 2017, 230-234. [14] Bilous T., Tulsky G., Korohodska A., Podustov M.: Visnyk NTU “KhPI”, 2017, 48, 24. [15] Khidirov Sh.: Russ. J. Electrochem., 1992, 2, 158. [16] Khidirov Sh., Khibiev Kh.: Russ. J. Electrochem., 2005, 11,1176. https://doi.org/10.1007/s11175-005-0198-5 |
| References (International): | [1] Dul’neva L., Moskvin A., Russ. J. Gen. Chem., 2005, 75, 1125. https://doi.org/10.1007/s11176-005-0378-8 [2] Zhao X., Zhang T., Zhou Y., Liu D., J. Mol. Catal. A, 2007, 271, 246. https://doi.org/10.1016/j.molcata.2007.03.012 [3] Zhao X., Cheng K., Hao J., Liu D., J. Mol. Catal. A, 2008, 284, 58. https://doi.org/10.1016/j.molcata.2008.01.003 [4] Zhao X., Zhang T., Zhou Y., Liu D., Chinese J. Process Eng., 2008, 8, 35. [5] Sun X., Zhao X., Du W., Liu D., Chinese J. Chem. Eng., 2011, 19, 964. https://doi.org/10.1016/S1004-9541(11)60078-5 [6] Zhang T., Luo J., Chuang K., Zhong L., Chinese J. Chem. Eng., 2007, 15, 320. https://doi.org/10.1016/S1004-9541(07)60087-1 [7] Moraleda I., Llanos J., Sáez C. et al., Electrochem. Commun., 2016, 73, 1. https://doi.org/10.1016/j.elecom.2016.10.010 [8] Saha M., Denggerile A., Nishiki Y. et al., Electrochem. Commun., 2003, 5, 445. https://doi.org/10.1016/S1388-2481(03)00097-3 [9] Cotillas S., Sánchez-Carretero A., Cañizares P. et al., Ind. Eng. Chem. Res., 2011, 50, 10889. https://doi.org/10.1021/ie2009422 [10] Ruiz-Ruiz E., Meas Y., Ortega-Borges R., Baizabal J., Surf. Eng. Appl. Electrochem., 2014, 50, 478. https://doi.org/10.3103/S106837551406009X [11] Cañizares P., Sáez C., Sánchez-Carretero A., Rodrigo M., J. Appl. Electrochem., 2009, 39, 2143. https://doi.org/10.1007/s10800-009-9792-7 [12] Bilous T., Tulsky G., Kinetics of Anodic Processes in Acetic Acid Solutions. [in:] Barsukov V. (Ed.), Promising Materials and Processes in Technical Electrochemistry. KNUTD, Kyiv 2016, 244-248. [13] Bilous T., Tulskaya A., Matrunchyk O., The Choice of Anode Material for the Electrochemical Synthesis of Peroxyacetic Acid. [in:] Barsukov V. (Ed.), Promising Materials and Processes in Applied Electrochemistry. KNUTD, Kyiv 2017, 230-234. [14] Bilous T., Tulsky G., Korohodska A., Podustov M., Visnyk NTU "KhPI", 2017, 48, 24. [15] Khidirov Sh., Russ. J. Electrochem., 1992, 2, 158. [16] Khidirov Sh., Khibiev Kh., Russ. J. Electrochem., 2005, 11,1176. https://doi.org/10.1007/s11175-005-0198-5 |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 2 |
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| 2020v14n2_Bilous_T-Electrochemical_Synthesis_135-138.pdf | 328.26 kB | Adobe PDF | View/Open | |
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