Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones

Mohamadpour, Farzaneh

doi:doi.org/10.23939/chcht14.01.014

Full metadata record

DC Field	Value	Language
dc.contributor.author	Mohamadpour, Farzaneh
dc.date.accessioned	2020-12-23T13:23:58Z	-
dc.date.available	2020-12-23T13:23:58Z	-
dc.date.created	2020-01-24
dc.date.issued	2020-01-24
dc.identifier.citation	Mohamadpour F. Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones / Farzaneh Mohamadpour // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 1. — P. 14–19.
dc.identifier.uri	https://ena.lpnu.ua/handle/ntb/55772	-
dc.description.abstract	Досліджено октадекагідрат алюмінію сульфату (Al2(SO4)3·18H2O) як ефективний та екологічно безпечний каталізатор для одностадійного чотирикомпонентного синтезу багатозаміщених дигідропірол-2-онів за реакцією діалкилацетилендикарбоксилату, формальдегіду та амінів (ароматичних та аліфатичних) за температури навколишнього середовища. Встановлено, що в присутності такого каталізатора виходи продуктів є високими, а час реакції малий. Показано, що найбільшими перевагами такого синтезу є ефективність, екологічність, недорога вартість та нетоксичність каталізатора, простота експлуатації, чіткий перебіг реакції та легкість виділення продукту без необхідності хроматографічного очищення. Визначено температури топлення продуктів та проведено 1H ЯМР-спектроскопічні дослідження.
dc.description.abstract	Aluminum sulfate octadecahydrate (Al2(SO4)3·18H2O) as an efficient, mild and eco-safe catalyst for one-pot four-component synthesis of polysubstituted dihydropyrrol-2-ones from reaction between dialkyl acetylenedicarboxylate, formaldehyde and amines (aromatic and aliphatic) under ambient temperature with good to high yields and short reaction times is reported. The most benefits of this synthetic method are efficiency, environmentally benign nature, inexpensive and non-toxic catalyst, operational simplicity, clean reaction profile and ease of product isolation with no necessity of chromatographic purification steps. Products have been characterized by melting points and 1H NMR spectroscopy.
dc.format.extent	14-19
dc.language.iso	en
dc.publisher	Видавництво Львівської політехніки
dc.publisher	Lviv Politechnic Publishing House
dc.relation.ispartof	Chemistry & Chemical Technology, 1 (14), 2020
dc.relation.uri	https://doi.org/10.1021/jm0102203
dc.relation.uri	https://doi.org/10.1021/jo010828j
dc.relation.uri	https://doi.org/10.1021/jm00060a012
dc.relation.uri	https://doi.org/10.7164/antibiotics.47.851
dc.relation.uri	https://doi.org/10.1021/jo050236r
dc.relation.uri	https://doi.org/10.1021/jm0509400
dc.relation.uri	https://doi.org/10.1021/jo00126a071
dc.relation.uri	https://doi.org/10.1016/j.bmc.2007.05.052
dc.relation.uri	https://doi.org/10.1016/j.bmc.2010.09.036
dc.relation.uri	https://doi.org/10.1007/s11164-016-2565-0
dc.relation.uri	https://doi.org/10.1007/s40995-016-0049-0
dc.relation.uri	https://doi.org/10.1007/s13738-016-0871-5
dc.relation.uri	https://doi.org/10.4067/s0717-97072018000103811
dc.relation.uri	https://doi.org/10.1007/s40995-016-0122-8
dc.relation.uri	https://doi.org/10.1021/co300148c
dc.relation.uri	https://doi.org/10.1016/j.cclet.2013.10.010
dc.relation.uri	https://doi.org/10.1016/j.tetlet.2012.03.046
dc.relation.uri	https://doi.org/10.1021/cc900046f
dc.relation.uri	https://doi.org/10.1007/s11164-012-0998-7
dc.relation.uri	https://doi.org/10.1007/s13738-013-0222-8
dc.relation.uri	https://doi.org/10.3184/174751912X13547952669204
dc.relation.uri	https://doi.org/10.1007/s11164-015-2178-z
dc.relation.uri	https://doi.org/10.1002/jccs.201200597
dc.relation.uri	https://doi.org/10.1007/s11164-013-1364-0
dc.relation.uri	https://doi.org/10.1007/s11164-017-2979-3
dc.relation.uri	https://doi.org/10.1002/jhet.2352
dc.subject	багатозамещені дигідропірол-2-они
dc.subject	октадегідрат алюмінію сульфату
dc.subject	екологічно безпечний та ефективний каталізатор
dc.subject	одностадійний синтез
dc.subject	багатокомпонентна реакція
dc.subject	polysubstituted dihydropyrrol-2-ones
dc.subject	aluminum sulfate octadecahydrate
dc.subject	eco-safe and efficient catalyst
dc.subject	one-pot and facile procedure
dc.subject	multi-component reaction
dc.title	Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones
dc.title.alternative	Al2(SO4)3·18H2O як еко-безпечний каталізатор для синтезу полізаміщених дигідропірол-2-онів
dc.type	Article
dc.rights.holder	© Національний університет “Львівська політехніка”, 2020
dc.rights.holder	© Mohamadpour F., 2020
dc.contributor.affiliation	Apadana Institute of Higher Education
dc.format.pages	6
dc.identifier.citationen	Mohamadpour F. Al2(SO4)3·18H2O as an Eco-Safe Catalyst Promoting Synthesis of Polysubstituted Dihydropyrrol-2-ones / Farzaneh Mohamadpour // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2020. — Vol 14. — No 1. — P. 14–19.
dc.identifier.doi	doi.org/10.23939/chcht14.01.014
dc.relation.references	[1] Borthwick A., Crame A., Ertl P. et al.: J. Med. Chem., 2002, 45, 1. https://doi.org/10.1021/jm0102203
dc.relation.references	[2] Li W., Lin S., Hsu N., Chern M.: J. Org. Chem., 2002, 67, 4702. https://doi.org/10.1021/jo010828j
dc.relation.references	[3] Lampe Y., Chou R., Hanna R. et al.: J. Med. Chem., 1993, 36, 1041. https://doi.org/10.1021/jm00060a012
dc.relation.references	[4] Shiozawa H., Takahashi S.: J. Antibiot., 1994, 47, 851. https://doi.org/10.7164/antibiotics.47.851
dc.relation.references	[5] Chen Y., Zeng D., Xie N., Dang Y.: J. Org. Chem., 2005, 70, 5001. https://doi.org/10.1021/jo050236r
dc.relation.references	[6] Grunwald C., Rundfeldt C., Lankau H. et al.: J. Med. Chem., 2006, 49, 1855. https://doi.org/10.1021/jm0509400
dc.relation.references	[7] Singh S., Goetz M., Jones E. et al.: J. Org. Chem., 1995, 60, 7040. https://doi.org/10.1021/jo00126a071
dc.relation.references	[8] Kawasuji T., Fuji M., Yoshinaga T. et al.: J. Bioorg. Med. Chem., 2007, 15, 5487. https://doi.org/10.1016/j.bmc.2007.05.052
dc.relation.references	[9] Zhang L., Tan Y., Wang N. et al. J. Bioorg. Med. Chem., 2010, 18, 7948. https://doi.org/10.1016/j.bmc.2010.09.036
dc.relation.references	[10] Maghsoodlou M., Heydari R., Mohamadpour F., Lashkari M.: Iran. J. Chem. Chem. Eng., 2017, 36(4), 31.
dc.relation.references	[11] Maghsoodlou M., Heydari R., Lashkari M., Mohamadpour F.: Indian J. Chem., 2017, 56 B, 160.
dc.relation.references	[12] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M.: Res. Chem. Intermed., 2016, 42, 7841. https://doi.org/10.1007/s11164-016-2565-0
dc.relation.references	[13] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M.: Iran. J. Sci. Technol. Trans. Sci., 2017, 41, 843. https://doi.org/10.1007/s40995-016-0049-0
dc.relation.references	[14] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M.: J. Iran. Chem. Soc., 2016, 13, 1549. https://doi.org/10.1007/s13738-016-0871-5
dc.relation.references	[15] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M.: Iran. J. Catal., 2016, 6, 127.
dc.relation.references	[16] Mohamadpour F., Lashkari M., Maghsoodlou M., Heydari R.: J. Chil. Chem. Soc., 2018, 63, 3788. https://doi.org/10.4067/s0717-97072018000103811
dc.relation.references	[17] Lashkari M., Heydari R., Mohamadpour F.: Iran. J. Sci. Technol. Trans. Sci., 2018, 42, 1191. https://doi.org/10.1007/s40995-016-0122-8
dc.relation.references	[18] Lv L., Zheng S., Cai X., Chen Z., Zhu Q., Liu S.: ACS Comb. Chem., 2013, 15, 183. https://doi.org/10.1021/co300148c
dc.relation.references	[19] Sajadikhah S S., Maghsoodlou M T., Hazeri N.: Chin. Chem. Lett., 2014, 25, 58. https://doi.org/10.1016/j.cclet.2013.10.010
dc.relation.references	[20] Khan A., Ghosh A., Musawwer Khan M.: Tetrahedron Lett., 2012, 53, 2622. https://doi.org/10.1016/j.tetlet.2012.03.046
dc.relation.references	[21] Zhu Q., Jiang H., Li J. et al.: ACS Comb. Chem., 2009, 11, 685. https://doi.org/10.1021/cc900046f
dc.relation.references	[22] Sajadikhah S., Hazeri N.: Res. Chem. Intermed., 2014, 40, 737. https://doi.org/10.1007/s11164-012-0998-7
dc.relation.references	[23] Sajadikhah S., Hazeri N., Maghsoodlou M. et al. J. Iran. Chem. Soc., 2013, 10, 863. https://doi.org/10.1007/s13738-013-0222-8
dc.relation.references	[24] Sajadikhah S., Hazeri N., Maghsoodlou M.: J. Chem. Res., 2013, 37, 40. https://doi.org/10.3184/174751912X13547952669204
dc.relation.references	[25] Sajadikhah S., Maghsoodlou M., Hazeri N., Mohamadian-Souri S.: Res. Chem. Intermed., 2016, 42, 2805. https://doi.org/10.1007/s11164-015-2178-z
dc.relation.references	[26] Sajadikhah S., Hazeri N., Maghsoodlou M., Habibi-Khorassani S.: J. Chin. Chem. Soc., 2013, 60, 1003. https://doi.org/10.1002/jccs.201200597
dc.relation.references	[27] Sajadikhah S., Maghsoodlou M., Hazeri N.: Res. Chem. Intermed., 2015, 41, 2503. https://doi.org/10.1007/s11164-013-1364-0
dc.relation.references	[28] Kaur R., Gupta A., Kapoor K.: Res. Chem. Intermed., 2017, 43, 6099. https://doi.org/10.1007/s11164-017-2979-3
dc.relation.references	[29] Mohammadi A., Salman Taheri S., Amouzegar A.: J. Heterocyclic Chem., 2016, 53, 805. https://doi.org/10.1002/jhet.2352
dc.relation.referencesen	[1] Borthwick A., Crame A., Ertl P. et al., J. Med. Chem., 2002, 45, 1. https://doi.org/10.1021/jm0102203
dc.relation.referencesen	[2] Li W., Lin S., Hsu N., Chern M., J. Org. Chem., 2002, 67, 4702. https://doi.org/10.1021/jo010828j
dc.relation.referencesen	[3] Lampe Y., Chou R., Hanna R. et al., J. Med. Chem., 1993, 36, 1041. https://doi.org/10.1021/jm00060a012
dc.relation.referencesen	[4] Shiozawa H., Takahashi S., J. Antibiot., 1994, 47, 851. https://doi.org/10.7164/antibiotics.47.851
dc.relation.referencesen	[5] Chen Y., Zeng D., Xie N., Dang Y., J. Org. Chem., 2005, 70, 5001. https://doi.org/10.1021/jo050236r
dc.relation.referencesen	[6] Grunwald C., Rundfeldt C., Lankau H. et al., J. Med. Chem., 2006, 49, 1855. https://doi.org/10.1021/jm0509400
dc.relation.referencesen	[7] Singh S., Goetz M., Jones E. et al., J. Org. Chem., 1995, 60, 7040. https://doi.org/10.1021/jo00126a071
dc.relation.referencesen	[8] Kawasuji T., Fuji M., Yoshinaga T. et al., J. Bioorg. Med. Chem., 2007, 15, 5487. https://doi.org/10.1016/j.bmc.2007.05.052
dc.relation.referencesen	[9] Zhang L., Tan Y., Wang N. et al. J. Bioorg. Med. Chem., 2010, 18, 7948. https://doi.org/10.1016/j.bmc.2010.09.036
dc.relation.referencesen	[10] Maghsoodlou M., Heydari R., Mohamadpour F., Lashkari M., Iran. J. Chem. Chem. Eng., 2017, 36(4), 31.
dc.relation.referencesen	[11] Maghsoodlou M., Heydari R., Lashkari M., Mohamadpour F., Indian J. Chem., 2017, 56 B, 160.
dc.relation.referencesen	[12] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M., Res. Chem. Intermed., 2016, 42, 7841. https://doi.org/10.1007/s11164-016-2565-0
dc.relation.referencesen	[13] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M., Iran. J. Sci. Technol. Trans. Sci., 2017, 41, 843. https://doi.org/10.1007/s40995-016-0049-0
dc.relation.referencesen	[14] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M., J. Iran. Chem. Soc., 2016, 13, 1549. https://doi.org/10.1007/s13738-016-0871-5
dc.relation.referencesen	[15] Mohamadpour F., Maghsoodlou M., Heydari R., Lashkari M., Iran. J. Catal., 2016, 6, 127.
dc.relation.referencesen	[16] Mohamadpour F., Lashkari M., Maghsoodlou M., Heydari R., J. Chil. Chem. Soc., 2018, 63, 3788. https://doi.org/10.4067/s0717-97072018000103811
dc.relation.referencesen	[17] Lashkari M., Heydari R., Mohamadpour F., Iran. J. Sci. Technol. Trans. Sci., 2018, 42, 1191. https://doi.org/10.1007/s40995-016-0122-8
dc.relation.referencesen	[18] Lv L., Zheng S., Cai X., Chen Z., Zhu Q., Liu S., ACS Comb. Chem., 2013, 15, 183. https://doi.org/10.1021/co300148c
dc.relation.referencesen	[19] Sajadikhah S S., Maghsoodlou M T., Hazeri N., Chin. Chem. Lett., 2014, 25, 58. https://doi.org/10.1016/j.cclet.2013.10.010
dc.relation.referencesen	[20] Khan A., Ghosh A., Musawwer Khan M., Tetrahedron Lett., 2012, 53, 2622. https://doi.org/10.1016/j.tetlet.2012.03.046
dc.relation.referencesen	[21] Zhu Q., Jiang H., Li J. et al., ACS Comb. Chem., 2009, 11, 685. https://doi.org/10.1021/cc900046f
dc.relation.referencesen	[22] Sajadikhah S., Hazeri N., Res. Chem. Intermed., 2014, 40, 737. https://doi.org/10.1007/s11164-012-0998-7
dc.relation.referencesen	[23] Sajadikhah S., Hazeri N., Maghsoodlou M. et al. J. Iran. Chem. Soc., 2013, 10, 863. https://doi.org/10.1007/s13738-013-0222-8
dc.relation.referencesen	[24] Sajadikhah S., Hazeri N., Maghsoodlou M., J. Chem. Res., 2013, 37, 40. https://doi.org/10.3184/174751912X13547952669204
dc.relation.referencesen	[25] Sajadikhah S., Maghsoodlou M., Hazeri N., Mohamadian-Souri S., Res. Chem. Intermed., 2016, 42, 2805. https://doi.org/10.1007/s11164-015-2178-z
dc.relation.referencesen	[26] Sajadikhah S., Hazeri N., Maghsoodlou M., Habibi-Khorassani S., J. Chin. Chem. Soc., 2013, 60, 1003. https://doi.org/10.1002/jccs.201200597
dc.relation.referencesen	[27] Sajadikhah S., Maghsoodlou M., Hazeri N., Res. Chem. Intermed., 2015, 41, 2503. https://doi.org/10.1007/s11164-013-1364-0
dc.relation.referencesen	[28] Kaur R., Gupta A., Kapoor K., Res. Chem. Intermed., 2017, 43, 6099. https://doi.org/10.1007/s11164-017-2979-3
dc.relation.referencesen	[29] Mohammadi A., Salman Taheri S., Amouzegar A., J. Heterocyclic Chem., 2016, 53, 805. https://doi.org/10.1002/jhet.2352
dc.citation.issue	1
dc.citation.spage	14
dc.citation.epage	19
dc.coverage.placename	Львів
dc.coverage.placename	Lviv
Appears in Collections:	Chemistry & Chemical Technology. – 2020. – Vol. 14, No. 1

File	Description	Size	Format
2020v14n1_Mohamadpour_F-Al2_SO4_318H2O_as_an_14-19.pdf		315.79 kB	Adobe PDF	View/Open
2020v14n1_Mohamadpour_F-Al2_SO4_318H2O_as_an_14-19__COVER.png		500.7 kB	image/png	View/Open

putin IS MURDERER