| DC Field | Value | Language |
|---|
| dc.contributor.author | Mukbaniani, Omari | |
| dc.contributor.author | Aneli, Jimsher | |
| dc.contributor.author | Plonska-Brzezinska, Marta | |
| dc.contributor.author | Tatrishvili, Tamar | |
| dc.contributor.author | Markarashvili, Eliza | |
| dc.date.accessioned | 2020-03-03T09:04:24Z | - |
| dc.date.available | 2020-03-03T09:04:24Z | - |
| dc.date.created | 2019-02-28 | |
| dc.date.issued | 2019-02-28 | |
| dc.identifier.citation | Fluorine-Containing Siloxane Based Polymer Electrolyte Membranes / Omari Mukbaniani, Jimsher Aneli, Marta Plonska-Brzezinska, Tamar Tatrishvili, Eliza Markarashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 4. — P. 444–450. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/46513 | - |
| dc.description.abstract | Проведено реакції гідросилілування 2,4,6,8-тетрагідро-2,4,6,8-тетраметилциклотетра-силоксану (D4
H) з 2,2,3,3-тетрафлуорпропіл акрилатом та вінілтриетоксисиланом у присутності платинових каталізаторів (платино
хлориста воднева кислота, каталізатор Карстеда і каталізатора Pt/C (10%) за температури 323 К) та одержано
відповідний адукт (D4 R,R‘). За допомогою Фур‘є-спектроскопії,
1H, 13C, та 29Si ЯМР спектроскопії проведено аналіз синтезованого продукту D4
R,R‘. Вивчено золь-гель реакції D4 R,R‘, допованого трифлуорметилсульфонатом літію (трифлат) та
одержано тверді полімер-електролітні мембрани. Із застосуванням електроімпендасної спектроскопії визначено електропровідність твердих полімерних електролітних мембран. | |
| dc.description.abstract | The hydrosilylation reaction of 2,4,6,8-tetrahydro-2,4,6,8-tetramethylcyclotetrasiloxane (D4
H) with 2,2,3,3-tetrafluoropropyl acrylate and vinyltriethoxysilane
in the presence of platinum catalysts (platinum
hydrochloric acid, Karstedt’s catalysts and Pt/C (10%) at
323 K) has been carried out and corresponding addition
adduct (D4 R,R‘) has been obtained. The synthesized
product D4 R,R was analyzed by FT-IR, 1H, 13C, and 29Si
NMR spectroscopy. Sol-gel reactions of D4 R,R doped with lithium trifluoromethylsulfonate (triflate) have been
studied and solid polymer electrolyte membranes have
been obtained. Electric conductivity of solid polymer
electrolyte membranes has been determined via electrical impedance spectroscopy. | |
| dc.format.extent | 444-450 | |
| dc.language.iso | en | |
| dc.publisher | Видавництво Львівської політехніки | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry & Chemical Technology, 4 (13), 2019 | |
| dc.relation.uri | https://doi.org/10.1080/15583724.2015.1011966 | |
| dc.relation.uri | https://doi.org/10.1016/j.nanoen.2017.01.028 | |
| dc.relation.uri | https://doi.org/10.1021/ja3091438 | |
| dc.relation.uri | https://doi.org/10.1016/j.progsolidstchem.2014.04.004 | |
| dc.relation.uri | https://doi.org/10.1016/j.ensm.2016.07.003 | |
| dc.relation.uri | https://doi.org/10.1016/j.polymer.2013.08.049 | |
| dc.relation.uri | https://doi.org/10.1016/j.electacta.2016.10.122 | |
| dc.relation.uri | https://doi.org/10.1039/C7RA01542A | |
| dc.relation.uri | https://doi.org/10.1016/j.jpowsour.2016.06.034 | |
| dc.relation.uri | https://doi.org/10.1515/pac-2017-0805 | |
| dc.relation.uri | https://doi.org/10.1002/pola.1993.080311023 | |
| dc.relation.uri | https://doi.org/10.1021/ma00181a019 | |
| dc.relation.uri | https://doi.org/10.1039/b806290k | |
| dc.relation.uri | https://doi.org/10.1016/j.ssi.2008.04.034 | |
| dc.relation.uri | https://doi.org/10.1017/CBO9781139644075 | |
| dc.subject | гідросилілування | |
| dc.subject | золь-гель реакції | |
| dc.subject | спектроскопія | |
| dc.subject | полімерна електролітна мембрана | |
| dc.subject | електропровідність | |
| dc.subject | hydrosilylation | |
| dc.subject | sol-gel reactions | |
| dc.subject | spectroscopy | |
| dc.subject | polymer electrolyte membrane | |
| dc.subject | electric conductivity | |
| dc.title | Fluorine-Containing Siloxane Based Polymer Electrolyte Membranes | |
| dc.title.alternative | Флуоровмісні тверді полімер-електролітні мембрани на основі силоксану | |
| dc.type | Article | |
| dc.rights.holder | © Національний університет „Львівська політехніка“, 2019 | |
| dc.rights.holder | © Mukbaniani O., Aneli J., Plonska-Brzezinska M., Tatrishvili T., Markarashvili E., 2019 | |
| dc.contributor.affiliation | Iv. Javakhishvili Tbilisi State University | |
| dc.contributor.affiliation | University of Bialystok | |
| dc.format.pages | 7 | |
| dc.identifier.citationen | Fluorine-Containing Siloxane Based Polymer Electrolyte Membranes / Omari Mukbaniani, Jimsher Aneli, Marta Plonska-Brzezinska, Tamar Tatrishvili, Eliza Markarashvili // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 4. — P. 444–450. | |
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| dc.relation.references | 14. Mukbaniani O., Aneli J., Tatrishvili T. et al.:E-polymers, 2012, 089, 1. https://doi.org/10.1021/ma00181a019 | |
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| dc.relation.referencesen | 1. Muldoon J., Bucur C., Boaretto N. et al., Polym. Rev., 2015, 55, 208. https://doi.org/10.1080/15583724.2015.1011966 | |
| dc.relation.referencesen | 2. Sun Ch., Liu J., Gong Yu. et al., Nano Energ., 2017, 33, 363. https://doi.org/10.1016/j.nanoen.2017.01.028 | |
| dc.relation.referencesen | 3. Goodenough J., Park K-S., J. Am. Chem. Soc., 2013, 135, 1167. https://doi.org/10.1021/ja3091438 | |
| dc.relation.referencesen | 4. GrünebaumM., Hiller M., Jankowsky S. et al., Prog. in Sol. State Chem., 2014, 42, 85. https://doi.org/10.1016/j.progsolidstchem.2014.04.004 | |
| dc.relation.referencesen | 5. Yue L., Ma J., Zhang J. et al., Energ. StorageMater., 2016, 5, 139. https://doi.org/10.1016/j.ensm.2016.07.003 | |
| dc.relation.referencesen | 6. Kim D.-G., Shim J.,Lee J. et al., Polymer, 2013, 54, 5812. https://doi.org/10.1016/j.polymer.2013.08.049 | |
| dc.relation.referencesen | 7. Ben youcef H., Garcia-Calvo O., Lago N. et al., Electrochim. Acta, 2016, 220, 587. https://doi.org/10.1016/j.electacta.2016.10.122 | |
| dc.relation.referencesen | 8. Liu T.-M., Saikia D., Ho S.-Y. et al., RSC Adv., 2017, 7, 20373. https://doi.org/10.1039/P.7RA01542A | |
| dc.relation.referencesen | 9. Boaretto N., Joost Ch., SeyfriedM. et al., J. Power Sources, 2016, 325, 427. https://doi.org/10.1016/j.jpowsour.2016.06.034 | |
| dc.relation.referencesen | 10. Tatrishvili T., Titvinidze G., Pirckheliani N. et al., Oxid. Commun., 2015, 2, 776. | |
| dc.relation.referencesen | 11. Mukbaniani O., Brostow W., Aneli J. et al., J. Pure Appl. Chem., 2018, 90, 989. https://doi.org/10.1515/pac-2017-0805 | |
| dc.relation.referencesen | 12. Iwahara T., KusakabeM., ChibaM., Yonezawa K., J. Polym. Sci. A, 1993, 31, 2617. https://doi.org/10.1002/pola.1993.080311023 | |
| dc.relation.referencesen | 13. Spindler R., Shriver D.:Macromolecules, 1988, 21, 648. https://doi.org/10.1021/ma00181a019 | |
| dc.relation.referencesen | 14. Mukbaniani O., Aneli J., Tatrishvili T. et al.:E-polymers, 2012, 089, 1. https://doi.org/10.1021/ma00181a019 | |
| dc.relation.referencesen | 15. Zhang L., Zhang Z., Harring S. et al., J. Mater. Chem., 2008, 18, 3713. https://doi.org/10.1039/b806290k | |
| dc.relation.referencesen | 16. Karan N., Pradhan D., Thomas R. et al., Solid State Ionics, 2008, 179, 689. https://doi.org/10.1016/j.ssi.2008.04.034 | |
| dc.relation.referencesen | 17. Ziman J., Principles of the Theory of Solids, Cambridge University Press, Cambridge 1964. https://doi.org/10.1017/CBO9781139644075 | |
| dc.citation.issue | 4 | |
| dc.citation.spage | 444 | |
| dc.citation.epage | 450 | |
| dc.coverage.placename | Львів | |
| dc.coverage.placename | Lviv | |
| Appears in Collections: | Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 4
|
