| DC Field | Value | Language |
|---|
| dc.contributor.author | Sobechko, Iryna | |
| dc.contributor.author | Horak, Yuri | |
| dc.contributor.author | Dibrivnyi, Volodymyr | |
| dc.contributor.author | Obushak, Mykola | |
| dc.contributor.author | Goshko, Lubomyr | |
| dc.date.accessioned | 2020-03-02T13:09:27Z | - |
| dc.date.available | 2020-03-02T13:09:27Z | - |
| dc.date.created | 2019-02-28 | |
| dc.date.issued | 2019-02-28 | |
| dc.identifier.citation | Thermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents / Iryna Sobechko, Yuri Horak, Volodymyr Dibrivnyi, Mykola Obushak, Lubomyr Goshko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 3. — P. 280–287. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/46488 | - |
| dc.description.abstract | Експериментально визначено температурні
залежності розчинності 2-метил-5-(2-хлор-5-трифторметил-
феніл)-фуран-3-карбонової та 2-метил-5-(2,5-дихлорфеніл)-
фуран-3-карбонової кислот в ацетонітрилі, диметилкетоні,
ізо-пропанолі та етилацетаті. Розраховані ентальпії плав-
лення досліджених речовин та їх ентальпії та ентропії
змішування за 298 К. Встановлено рівняння зв’язку концент-
рації насиченого розчину з величинами ентальпії і ентропії
розчинності за 298 К. Виявлений компенсаційний ефект
змішування досліджених кислот зі всіма розчинниками, що
містять карбонільну групу. | |
| dc.description.abstract | The temperature dependences of the solubility
of 2-methyl-5-(2-chloro-5-trifluoromethylphenyl)-furan-
3-carboxylic acid and 2-methyl-5-(2,5-dichlorophenyl)-
furan-3-carboxylic acid in acetonitrile, dimethyl ketone,
isopropanol and ethyl acetate have been experimentally
determined. The enthalpies of fusion of the investigated
substances, as well as their enthalpies and entropies of
mixing at 298 K have been calculated. The dependence of
the saturated solution concentration on the values of
enthalpy and entropy of solubility at 298 K has been
determined. The compensating effect of mixing the
investigated acids with all solvents containing the
carbonyl group has been established. | |
| dc.format.extent | 280-287 | |
| dc.language.iso | en | |
| dc.publisher | Видавництво Львівської політехніки | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry & Chemical Technology, 3 (13), 2019 | |
| dc.relation.uri | https://doi.org/10.1016/S0079-6700(97)00004-X | |
| dc.relation.uri | https://doi.org/10.1016/S0014-827X(00)00030-6 | |
| dc.relation.uri | https://doi.org/10.1515/hc.2003.9.6.625 | |
| dc.relation.uri | https://doi.org/10.1021/ja072817z | |
| dc.relation.uri | https://doi.org/10.1021/acs.jmedchem.8b00399 | |
| dc.relation.uri | https://doi.org/10.1021/acs.jmedchem.8b00084 | |
| dc.relation.uri | https://doi.org/10.1016/S0960-894X(03)00680-2 | |
| dc.relation.uri | https://doi.org/10.3390/ijms140918488 | |
| dc.relation.uri | https://doi.org/10.3390/ijms151120800 | |
| dc.relation.uri | https://doi.org/10.1016/j.ijbiomac.2013.04.045 | |
| dc.relation.uri | https://doi.org/10.1134/S003602441506028X | |
| dc.relation.uri | https://doi/org/10.23939/chcht11.04.397 | |
| dc.relation.uri | https://doi/org/10.23939/chcht11.02.131 | |
| dc.relation.uri | http://webbook.nist.gov | |
| dc.subject | ентальпія | |
| dc.subject | ентропія розчинності | |
| dc.subject | змішування і плавлення | |
| dc.subject | 2-метил-5-(2-хлор-5-трифторметил-феніл)-фуран-3-карбонова кислота | |
| dc.subject | 2-метил-5-(2 | |
| dc.subject | 5-дихлор-феніл)-фуран-3-карбонова кислота | |
| dc.subject | enthalpy | |
| dc.subject | entropy of solubility | |
| dc.subject | mixing | |
| dc.subject | melting | |
| dc.subject | 2-methyl-5-(2-chloro-5-trifluoromethylphenyl)-furan-3-carboxylic acid | |
| dc.subject | 2-methyl-5-(2 | |
| dc.subject | 5-dichlorophenyl)-furan-3-carboxylic acid | |
| dc.title | Thermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents | |
| dc.title.alternative | Термодинамічні властивості розчинів хлорпохідних 2-метил-5-арилфуран-3-карбоксильних кислот в органічних розчинниках | |
| dc.type | Article | |
| dc.rights.holder | © Національний університет „Львівська політехніка“, 2019 | |
| dc.rights.holder | © Sobechko I., Horak Y., Dibrivnyi V., Obushak M., Goshko L., 2019 | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.contributor.affiliation | Ivan Franko National University of Lviv | |
| dc.format.pages | 8 | |
| dc.identifier.citationen | Thermodynamic Properties of 2-Methyl-5-arylfuran-3 Carboxylic Acids Chlorine Derivatives in Organic Solvents / Iryna Sobechko, Yuri Horak, Volodymyr Dibrivnyi, Mykola Obushak, Lubomyr Goshko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 3. — P. 280–287. | |
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| dc.relation.referencesen | 20. Kochubei V., Horak Yu., SObechko I. et al., Visnyk Lviv. Univ., 2015, 56, 301. | |
| dc.citation.issue | 3 | |
| dc.citation.spage | 280 | |
| dc.citation.epage | 287 | |
| dc.coverage.placename | Львів | |
| dc.coverage.placename | Lviv | |
| Appears in Collections: | Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 3
|
