Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity on Oxidation of Hexacyanoferrate(II) by Periodate Ion in Water Samples

Srivastava, Abhishek; Sharma, Vivek; Prajapati, Anjali; Srivastava, Neetu; Naik, R. M.

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DC Field	Value	Language
dc.contributor.author	Srivastava, Abhishek
dc.contributor.author	Sharma, Vivek
dc.contributor.author	Prajapati, Anjali
dc.contributor.author	Srivastava, Neetu
dc.contributor.author	Naik, R. M.
dc.date.accessioned	2020-03-02T13:09:21Z	-
dc.date.available	2020-03-02T13:09:21Z	-
dc.date.created	2019-02-28
dc.date.issued	2019-02-28
dc.identifier.citation	Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity on Oxidation of Hexacyanoferrate(II) by Periodate Ion in Water Samples / Abhishek Srivastava, Vivek Sharma, Anjali Prajapati, Neetu Srivastava, R. M. Naik // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 3. — P. 275–279.
dc.identifier.uri	https://ena.lpnu.ua/handle/ntb/46477	-
dc.description.abstract	Для визначення рутенію(III) на мікрорівні застосовано каталітичний ефект хлориду рутенію на зов- нішнє перенесення електронів гексаціаноферрату(II) періодат- ним йоном у водному лужному середовищі. Встановлено оптимальні умови реакції та необхідний час. Лінійна залежність між поглинальною здатністю та концентрацією Ru(III) використана для визначення слідів Ru(III). Показано, що додавання інтерферентних йонів (в концентраціях, до 71 разів вищих за концентрацію Ru) істотно не впливає на ката- літичну активність Ru(III) при окисненні гексаціано- феррату(II) періодатним йоном. Поліамінокарбоксилати пригнічують його каталітичну здатність до максимального значення, якщо допустима межа є більшою за 14,29. Враховуючи відтворюваність, стабільність та селективность цього методу, запропоновано використовувати його для різних типів зразків води для визначення рутенію(III) на мікрорівні.
dc.description.abstract	The catalytic effect of ruthenium chloride on the outer sphere electron transfer of hexacyanoferrate(II) by periodate ion in aqueous alkaline medium has been effectively employed to determine ruthenium(III) at micro level. The optimum reaction condition has been established and fixed time procedure is adopted. A linear relationship between changes in absorbance and added Ru(III) concentration has been utilized for the trace level determination of Ru(III). The results reveal that the addition of interfering ions (up to 71 times higher concentration of Ru) does not have significant effect on the catalytic activity of Ru(III) on oxidation of hexacyanoferrate(II) by periodate ion. Polyaminocarboxylates (HEDTA, EDTA and IDA) suppress its catalytic power to maximum, if tolerance limit is more than 14.29 times. Due to the reproducibility, stability and selectivity, this method can also be quantitatively applied in different types of water samples for determination of ruthenium(III) at micro level.
dc.format.extent	275-279
dc.language.iso	en
dc.publisher	Видавництво Львівської політехніки
dc.publisher	Lviv Politechnic Publishing House
dc.relation.ispartof	Chemistry & Chemical Technology, 3 (13), 2019
dc.relation.uri	https://doi.org/10.1080/10408340290765524
dc.relation.uri	https://doi.org/10.1006/abio.1999.4364
dc.relation.uri	https://doi.org/10.1590/S0103-50532004000200004
dc.relation.uri	https://doi.org/10.1016/j.jpba.2006.03.011
dc.relation.uri	https://doi.org/10.4028/www.scientific.net/AMR.602-604.1289
dc.relation.uri	https://doi.org/10.4028/www.scientific.net/AMM.217-219.2397
dc.relation.uri	https://doi.org/10.2174/1876214X01104010001
dc.relation.uri	https://doi.org/10.1007/s12039-009-0030-y
dc.relation.uri	https://doi.org/10.1007/s12039-016-1067-3
dc.relation.uri	https://doi.org/10.1039/c3cc46239k
dc.relation.uri	https://doi.org/10.1039/c2dt32216a
dc.relation.uri	https://doi.org/10.1016/j.jpowsour.2015.09.119
dc.relation.uri	https://doi.org/10.1038/ncomms3466
dc.relation.uri	https://doi.org/10.1021/ml400390c
dc.relation.uri	https://doi.org/10.1016/j.tsf.2012.12.037
dc.relation.uri	https://doi.org/10.1080/01496395.2014.983245
dc.relation.uri	https://doi.org/10.1016/j.saa.2007.03.030
dc.relation.uri	https://doi.org/10.1016/j.saa.2007.10.011
dc.relation.uri	https://doi.org/10.1007/BF00323114
dc.relation.uri	https://doi.org/10.1021/a1000004b
dc.relation.uri	https://doi.org/10.1007/BF02076032
dc.relation.uri	https://doi.org/10.1081/AL-120014292
dc.relation.uri	https://doi.org/10.1007/BF03245812
dc.subject	кінетика
dc.subject	механізм
dc.subject	гексаціаноферрат(II)
dc.subject	періодат
dc.subject	рутеній(III)
dc.subject	kinetics
dc.subject	mechanism
dc.subject	hexacyanoferrate(II)
dc.subject	periodate
dc.subject	ruthenium(III)
dc.title	Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity on Oxidation of Hexacyanoferrate(II) by Periodate Ion in Water Samples
dc.title.alternative	Спектрофотометричне визначення рутенію з використанням його каталітичної активності на окиснення гексацианоферрата(II) періодатним йоном в зразках води
dc.type	Article
dc.rights.holder	© Національний університет „Львівська політехніка“, 2019
dc.rights.holder	© Srivastava A., Sharma V., Prajapati A., Srivastava N., Naik R. M., 2019
dc.contributor.affiliation	G.L.A. University
dc.contributor.affiliation	D.D.U. Gorakhpur University
dc.contributor.affiliation	Lucknow University
dc.format.pages	5
dc.identifier.citationen	Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity on Oxidation of Hexacyanoferrate(II) by Periodate Ion in Water Samples / Abhishek Srivastava, Vivek Sharma, Anjali Prajapati, Neetu Srivastava, R. M. Naik // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 3. — P. 275–279.
dc.relation.references	1. BalcerzakM.: Rev. Anal. Chem., 2002, 32, 181. https://doi.org/10.1080/10408340290765524
dc.relation.references	2. Druskovic V., Vojkovic V., Jelic T.: Croatica Chem. Acta, 2005, Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity… 279
dc.relation.references	3. Berggren K., Steinberg T., Lauber W. et al.: Anal. Biochem., 1999, 276, 129. https://doi.org/10.1006/abio.1999.4364
dc.relation.references	4. Lindino C., Bulhoes L.: J. Braz. Chem. Soc., 2004, 15, 178. https://doi.org/10.1590/S0103-50532004000200004
dc.relation.references	5. Alarfa N., El-Razeq S.: J. Pharm. Biomed. Anal., 2006, 41, 1423. https://doi.org/10.1016/j.jpba.2006.03.011
dc.relation.references	6. Zhou Z., Zhang I.: Adv. Mater. Res., 2013, 602-604, 1289. https://doi.org/10.4028/www.scientific.net/AMR.602-604.1289
dc.relation.references	7. Zhou Z., Zhang I.: Appl. MechanicsMater., 2012, 217-219, 2397. https://doi.org/10.4028/www.scientific.net/AMM.217-219.2397
dc.relation.references	8. Byadagi K., Nandibewoor S., Chimatadar S.: Acta Chim. Slov., 2013, 60, 617.
dc.relation.references	9. Sharanabasamma K., Angadi A., Tuwar S.: The Open Catal. J., 2011, 4, 1. https://doi.org/10.2174/1876214X01104010001
dc.relation.references	10. KeyvanfardM.:World Acad. Sci. Eng. Tech. 2008, 43.
dc.relation.references	11. Hosamani R., Nandibewoor S.: J. Chem. Sci., 2009, 121, 275. https://doi.org/10.1007/s12039-009-0030-y
dc.relation.references	12. Srivastava S., Chaudhary L., Singh K.: Int. J. Res. in Phys. Chem., 2012, 2, 6.
dc.relation.references	13. Babasaheb D., Bhosale A., Gokavib G.: Adv. Appl. Sci. Res. 2012, 3, 785.
dc.relation.references	14. Mishra K., Chaturvedi R., ShuklaM.: Ind. J. Chem. 2010, 49A, 185.
dc.relation.references	15. Kumar A., Reddy P., Reddy V.: Int. J. ChemTech. Res., 2013, 5, 1442.
dc.relation.references	16. RitikaM., Barhate V.: Int. J. ChemTech. Res., 2013, 5, 1578.
dc.relation.references	17. Sateesh B., Shastry V., Shashidhar S., Manoj K.: Int. J. Chem. Sci., 2014, 14, 1109.
dc.relation.references	18. Fawaz A.: J. Chem. Sci., 2016, 128, 733. https://doi.org/10.1007/s12039-016-1067-3
dc.relation.references	19. Gorakh S., Antonio D., Jyoti G. et al.: Chem. Commun., 2013, 49, 11533. https://doi.org/10.1039/c3cc46239k
dc.relation.references	20. Lakomska I., FandzlochM., Muziol T. et al.: Dalton Trans., 2013, 42, 6219. https://doi.org/10.1039/c2dt32216a
dc.relation.references	21. Sharma A., Gangrade, Bakshi D., John J.: Int. J. ChemTech. Res., 2014, 4, 828.
dc.relation.references	22. Schoekel A., Melke J., BurnsM. et al.: J. Power Sources, 2016, 301, 210. https://doi.org/10.1016/j.jpowsour.2015.09.119
dc.relation.references	23. Hsieh Y., Zang Y., Su D. et al.: Nat. Commun., 2013, 2466. https://doi.org/10.1038/ncomms3466
dc.relation.references	24. Messori L., Camarri M., Ferraro T. et al.: A.C.S. Med. Chem. Lett., 2013, 4, 1124. https://doi.org/10.1021/ml400390c
dc.relation.references	25. Brunken S., Kratzig A., Bogdanoff P. et al.: Thin Solid Films, 2013, 527, 16. https://doi.org/10.1016/j.tsf.2012.12.037
dc.relation.references	26. Madan P., Barhate V.: Int. J. Sci. Res., 2016, 5, 778.
dc.relation.references	27. Shelar S., Bhor R., AnuseM., Naval R.: Sep. Sci. Tech., 2015, 50, 1190. https://doi.org/10.1080/01496395.2014.983245
dc.relation.references	28. Prasad S., Naik R., Srivastava A.: Spectrochim. Acta A, 2008, 69, 193. https://doi.org/10.1016/j.saa.2007.03.030
dc.relation.references	29. Naik R., Srivastava A., Prasad S.: Spectrochim. Acta A, 2008, 70, 958. https://doi.org/10.1016/j.saa.2007.10.011
dc.relation.references	30. Zhou Z., Zhang L.: Appl. Mech. Mater., 2012, 204-208, 4067.
dc.relation.references	31. Sreekanth B., Jonnalagadda, Brijesh P.: Anal. Lett., 2011, 1868.
dc.relation.references	32. Jonnalagadda S., Chinake C., Love I.: Fresenius Anal. Chem., 1994, 349, 829. https://doi.org/10.1007/BF00323114
dc.relation.references	33. KeyvanfardM., Rezaei B.: Can. J. Anal. Sci. Spectrosc., 2005, 50, 221.
dc.relation.references	34. Crouch S., Scheeline A., Kirkor E.: Anal. Chem., 2000, 72, 53. https://doi.org/10.1021/a1000004b
dc.relation.references	35. Prasad S.: Asian J. Chem., 2002, 14, 799.
dc.relation.references	36. Prasad K., Rao N.: React. Kinet. Catal. Lett., 1995, 56, 273. https://doi.org/10.1007/BF02076032
dc.relation.references	37. Khayamian T., Ensafi A., Atabati M.: Anal. Lett., 2002, 35, 2039. https://doi.org/10.1081/AL-120014292
dc.relation.references	38. Bhagwat V., Vijay R., Jonnalagadda S., Pare B.: Indian J. Chem. Technol., 2006, 13, 644.
dc.relation.references	39. Naik R., Srivastava A., Asthana A.: J. Iran. Chem. Soc., 2008, 5, 29. https://doi.org/10.1007/BF03245812
dc.relation.referencesen	1. BalcerzakM., Rev. Anal. Chem., 2002, 32, 181. https://doi.org/10.1080/10408340290765524
dc.relation.referencesen	2. Druskovic V., Vojkovic V., Jelic T., Croatica Chem. Acta, 2005, Spectrophotometric Determination of Ruthenium Utilizing its Catalytic Activity… 279
dc.relation.referencesen	3. Berggren K., Steinberg T., Lauber W. et al., Anal. Biochem., 1999, 276, 129. https://doi.org/10.1006/abio.1999.4364
dc.relation.referencesen	4. Lindino C., Bulhoes L., J. Braz. Chem. Soc., 2004, 15, 178. https://doi.org/10.1590/S0103-50532004000200004
dc.relation.referencesen	5. Alarfa N., El-Razeq S., J. Pharm. Biomed. Anal., 2006, 41, 1423. https://doi.org/10.1016/j.jpba.2006.03.011
dc.relation.referencesen	6. Zhou Z., Zhang I., Adv. Mater. Res., 2013, 602-604, 1289. https://doi.org/10.4028/www.scientific.net/AMR.602-604.1289
dc.relation.referencesen	7. Zhou Z., Zhang I., Appl. MechanicsMater., 2012, 217-219, 2397. https://doi.org/10.4028/www.scientific.net/AMM.217-219.2397
dc.relation.referencesen	8. Byadagi K., Nandibewoor S., Chimatadar S., Acta Chim. Slov., 2013, 60, 617.
dc.relation.referencesen	9. Sharanabasamma K., Angadi A., Tuwar S., The Open Catal. J., 2011, 4, 1. https://doi.org/10.2174/1876214X01104010001
dc.relation.referencesen	10. KeyvanfardM.:World Acad. Sci. Eng. Tech. 2008, 43.
dc.relation.referencesen	11. Hosamani R., Nandibewoor S., J. Chem. Sci., 2009, 121, 275. https://doi.org/10.1007/s12039-009-0030-y
dc.relation.referencesen	12. Srivastava S., Chaudhary L., Singh K., Int. J. Res. in Phys. Chem., 2012, 2, 6.
dc.relation.referencesen	13. Babasaheb D., Bhosale A., Gokavib G., Adv. Appl. Sci. Res. 2012, 3, 785.
dc.relation.referencesen	14. Mishra K., Chaturvedi R., ShuklaM., Ind. J. Chem. 2010, 49A, 185.
dc.relation.referencesen	15. Kumar A., Reddy P., Reddy V., Int. J. ChemTech. Res., 2013, 5, 1442.
dc.relation.referencesen	16. RitikaM., Barhate V., Int. J. ChemTech. Res., 2013, 5, 1578.
dc.relation.referencesen	17. Sateesh B., Shastry V., Shashidhar S., Manoj K., Int. J. Chem. Sci., 2014, 14, 1109.
dc.relation.referencesen	18. Fawaz A., J. Chem. Sci., 2016, 128, 733. https://doi.org/10.1007/s12039-016-1067-3
dc.relation.referencesen	19. Gorakh S., Antonio D., Jyoti G. et al., Chem. Commun., 2013, 49, 11533. https://doi.org/10.1039/P.3cc46239k
dc.relation.referencesen	20. Lakomska I., FandzlochM., Muziol T. et al., Dalton Trans., 2013, 42, 6219. https://doi.org/10.1039/P.2dt32216a
dc.relation.referencesen	21. Sharma A., Gangrade, Bakshi D., John J., Int. J. ChemTech. Res., 2014, 4, 828.
dc.relation.referencesen	22. Schoekel A., Melke J., BurnsM. et al., J. Power Sources, 2016, 301, 210. https://doi.org/10.1016/j.jpowsour.2015.09.119
dc.relation.referencesen	23. Hsieh Y., Zang Y., Su D. et al., Nat. Commun., 2013, 2466. https://doi.org/10.1038/ncomms3466
dc.relation.referencesen	24. Messori L., Camarri M., Ferraro T. et al., A.C.S. Med. Chem. Lett., 2013, 4, 1124. https://doi.org/10.1021/ml400390c
dc.relation.referencesen	25. Brunken S., Kratzig A., Bogdanoff P. et al., Thin Solid Films, 2013, 527, 16. https://doi.org/10.1016/j.tsf.2012.12.037
dc.relation.referencesen	26. Madan P., Barhate V., Int. J. Sci. Res., 2016, 5, 778.
dc.relation.referencesen	27. Shelar S., Bhor R., AnuseM., Naval R., Sep. Sci. Tech., 2015, 50, 1190. https://doi.org/10.1080/01496395.2014.983245
dc.relation.referencesen	28. Prasad S., Naik R., Srivastava A., Spectrochim. Acta A, 2008, 69, 193. https://doi.org/10.1016/j.saa.2007.03.030
dc.relation.referencesen	29. Naik R., Srivastava A., Prasad S., Spectrochim. Acta A, 2008, 70, 958. https://doi.org/10.1016/j.saa.2007.10.011
dc.relation.referencesen	30. Zhou Z., Zhang L., Appl. Mech. Mater., 2012, 204-208, 4067.
dc.relation.referencesen	31. Sreekanth B., Jonnalagadda, Brijesh P., Anal. Lett., 2011, 1868.
dc.relation.referencesen	32. Jonnalagadda S., Chinake C., Love I., Fresenius Anal. Chem., 1994, 349, 829. https://doi.org/10.1007/BF00323114
dc.relation.referencesen	33. KeyvanfardM., Rezaei B., Can. J. Anal. Sci. Spectrosc., 2005, 50, 221.
dc.relation.referencesen	34. Crouch S., Scheeline A., Kirkor E., Anal. Chem., 2000, 72, 53. https://doi.org/10.1021/a1000004b
dc.relation.referencesen	35. Prasad S., Asian J. Chem., 2002, 14, 799.
dc.relation.referencesen	36. Prasad K., Rao N., React. Kinet. Catal. Lett., 1995, 56, 273. https://doi.org/10.1007/BF02076032
dc.relation.referencesen	37. Khayamian T., Ensafi A., Atabati M., Anal. Lett., 2002, 35, 2039. https://doi.org/10.1081/AL-120014292
dc.relation.referencesen	38. Bhagwat V., Vijay R., Jonnalagadda S., Pare B., Indian J. Chem. Technol., 2006, 13, 644.
dc.relation.referencesen	39. Naik R., Srivastava A., Asthana A., J. Iran. Chem. Soc., 2008, 5, 29. https://doi.org/10.1007/BF03245812
dc.citation.issue	3
dc.citation.spage	275
dc.citation.epage	279
dc.coverage.placename	Львів
dc.coverage.placename	Lviv
Appears in Collections:	Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 3

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