ZnCl2-Catalyzed Four-Component Domino Reaction for One-Pot Eco-Safe and Convenient Synthesis of Polyfunctionalized Dihydro-2-oxopyrroles at Ambient Temperature

Mohamadpour, Farzaneh

Please use this identifier to cite or link to this item: https://oldena.lpnu.ua/handle/ntb/46471

Title:	ZnCl2-Catalyzed Four-Component Domino Reaction for One-Pot Eco-Safe and Convenient Synthesis of Polyfunctionalized Dihydro-2-oxopyrroles at Ambient Temperature
Other Titles:	Чотирикомпонентна ланцюгова реакція на ZnCl2 каталізаторі для одноступеневого екобезпечного синтезу поліфункціональних дигідро-2-оксопіролів за кімнатної температури
Authors:	Mohamadpour, Farzaneh
Affiliation:	Islamic Azad University
Bibliographic description (Ukraine):	Mohamadpour F. ZnCl2-Catalyzed Four-Component Domino Reaction for One-Pot Eco-Safe and Convenient Synthesis of Polyfunctionalized Dihydro-2-oxopyrroles at Ambient Temperature / Farzaneh Mohamadpour // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 2. — P. 157–162.
Bibliographic description (International):	Mohamadpour F. ZnCl2-Catalyzed Four-Component Domino Reaction for One-Pot Eco-Safe and Convenient Synthesis of Polyfunctionalized Dihydro-2-oxopyrroles at Ambient Temperature / Farzaneh Mohamadpour // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 13. — No 2. — P. 157–162.
Is part of:	Chemistry & Chemical Technology, 2 (13), 2019
Issue:	2
Issue Date:	28-Feb-2019
Publisher:	Видавництво Львівської політехніки Lviv Politechnic Publishing House
Place of the edition/event:	Львів Lviv
Keywords:	ZnCl2 полізаміщені дигідро-2-оксопіроли каталізатор одноступеневий синтез Фур‘є- та ЯМР спектроскопія ZnCl2 polysubstituted dihydro-2-oxopyrroles catalyst one-pot synthesis FTIR 1H NMR spectroscopy
Number of pages:	6
Page range:	157-162
Start page:	157
End page:	162
Abstract:	В присутності екологічно безпечного і ефективного каталізатора Фріделя-Крафта ZnCl2 проведено одноступеневий чотирикомпонентний синтез полізаміщеного дигідро-2-оксопіролу за кімнатної температури з викорис- танням діалкилацетилендикарбоксилату, формальдегіду та амінів (ароматичних та аліфатичних). Показаний ряд переваг такого синтезу: легкість, дешевизна, екологічно безпечний каталізатор, короткий час реакції, високі виходи, легке оброблення (тільки звичайна фільтрація) та простота експ- луатації. Визначено характеристику одержаних продуктів за допомогою Фур‘є- та ЯМР-спектроскопії. In this study, ZnCl2 was applied as an environmentally friendly and efficient Lewis acid catalyst for the one-pot four-component synthesis of polysubstituted dihydro-2-oxopyrroles from the reaction between dialkyl acetylenedicarboxylate, formaldehyde and amines (aromatic and aliphatic) at ambient temperature. This methodology has a number of advantages such as use of inexpensive, eco-safety of catalyst, short reaction times, high yields, easy work-up (just simple filtration), and simplicity of operation. All products are characterized by comparison of FT-IR and 1H NMR spectroscopic data.
URI:	https://ena.lpnu.ua/handle/ntb/46471
Copyright owner:	© Національний університет „Львівська політехніка“, 2019 © Mohamadpour F., 2019
URL for reference material:	https://doi.org/10.1002/jlac.18500750103 https://doi.org/10.1007/s11164-016-2565-0 https://doi.org/10.1007/s13738-016-0871-5 https://doi.org/10.1007/s40995-016-0049-0 https://doi.org/10.1007/s40995-016-0122-8 https://doi.org/10.1021/jm101212e https://doi.org/10.1016/00404-0399(50)1049N- https://doi.org/10.1021/jo050236r https://doi.org/10.1021/jm00060a012 https://doi.org/10.1016/j.bmc.2007.05.052 https://doi.org/10.1021/jo010828j https://doi.org/10.1021/jo048605r https://doi.org/10.1021/jo00126a071 https://doi.org/10.1016/j.tetlet.2012.03.046 https://doi.org/10.1016/j.cclet.2013.10.010 https://doi.org/10.1007/s11164-012-0998-7 https://doi.org/10.1007/s13738-013-0222-8 https://doi.org/10.1021/cc900046f https://doi.org/10.3184/174751912X13547952669204 https://doi.org/10.1021/co300148c http://dx.doi.org/10.3998/ark.5550190.0009.h23 https://doi.org/10.1016/j.catcom.2015.02.009
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Appears in Collections:	Chemistry & Chemical Technology. – 2019. – Vol. 13, No. 2

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