https://oldena.lpnu.ua/handle/ntb/46374| Title: | Одержання і характеристика катіонних крохмалів |
| Other Titles: | Preparation and characteristics of cationic starches |
| Authors: | Костик, О. А. Будішевська, О. Г. Вострес, В. Б. Надашкевич, З. Я. Воронов, С. А. Kostyk, O. A. Budishevska, O. H. Vostres, V. B. Nadashkevych, Z. Y. Voronov, S. A. |
| Affiliation: | Національний університет “Львівська політехніка” Lviv Polytechnic National University |
| Bibliographic description (Ukraine): | Одержання і характеристика катіонних крохмалів / О. А. Костик, О. Г. Будішевська, В. Б. Вострес, З. Я. Надашкевич, С. А. Воронов // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Том 2. — № 1. — С. 159–165. |
| Bibliographic description (International): | Preparation and characteristics of cationic starches / O. A. Kostyk, O. H. Budishevska, V. B. Vostres, Z. Y. Nadashkevych, S. A. Voronov // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 2. — No 1. — P. 159–165. |
| Is part of: | Chemistry, Technology and Application of Substances, 1 (2), 2019 |
| Issue: | 1 |
| Issue Date: | 28-Feb-2019 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv Lviv |
| Keywords: | катіонний крохмаль ступінь заміщення триетиламін cationic starch degree of substitution triethylamine |
| Number of pages: | 7 |
| Page range: | 159-165 |
| Start page: | 159 |
| End page: | 165 |
| Abstract: | Досліджено процес одержання катіонізованих крохмалів із ступенем заміщення DS 0,02–
0,45 взаємодією амінуючого реагенту 3-хлоро-2-гідроксипропілтриетиламоній хлориду (АР) з
кукурудзяним крохмалем напівсухим методом у присутності натрій гідроксиду. АР одержано в
одному реакторі взаємодією триетиламіну з HCl з подальшою взаємодією з епіхлоргідрином у
присутності каталізатора триметилцетиламоній броміду. Показано, що катіонізований крохмаль з
найвищим ступенем заміщення утворюється за мольного співвідношення NaOH: АР = 1,2–2,0.
Найбільша ефективність реакції катіонування крохмалю у досліджуваному інтервалі
спостерігалась за співвідношення АР: крохмаль=1,0. The process of obtaining cationized starches with the degree of substitution equal to DS 0.02–0.45 by interaction of the 3-chloro-2-hydroxypropyltrietilammonium chloride (AR) amine reagent with corn starch by a semi-dry method in the presence of sodium hydroxide was investigated. AR was obtained by the one-pot interaction of triethylamine with HCl followed by reaction with epichlorohydrin in the presence of cetyltrimethylammonium bromide as a catalyst. It was shown that cationized starch with the highest degree of substitution was formed at a molar ratio NaOH: AP = 1.2–2.0. The greatest efficiency of the cationization of starch in the investigated interval was observed at the ratio of AP: starch = 1.0. |
| URI: | https://ena.lpnu.ua/handle/ntb/46374 |
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| Content type: | Article |
| Appears in Collections: | Chemistry, Technology and Application of Substances. – 2019. – Vol. 2, No. 1 |
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| 2019v2n1_Kostyk_O_A-Preparation_and_characteristics_159-165__COVER.png | 445.78 kB | image/png | View/Open |
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