| DC Field | Value | Language |
|---|
| dc.contributor.author | Тарас, Т. М. | |
| dc.contributor.author | Дейчаківський, Ю. І. | |
| dc.contributor.author | Шупенюк, В. І. | |
| dc.contributor.author | Сабадах, О. П. | |
| dc.contributor.author | Болібрух, Л. Д. | |
| dc.contributor.author | Taras, T. M. | |
| dc.contributor.author | Dejchakivsky, Y. I. | |
| dc.contributor.author | Shupeniuk, V. I. | |
| dc.contributor.author | Sabadakh, O. P. | |
| dc.contributor.author | Bolibrukh, L. D. | |
| dc.date.accessioned | 2020-02-28T13:09:26Z | - |
| dc.date.available | 2020-02-28T13:09:26Z | - |
| dc.date.created | 2019-02-28 | |
| dc.date.issued | 2019-02-28 | |
| dc.identifier.citation | Особливості отримання триазенів антрахінонового ряду / Т. М. Тарас, Ю. І. Дейчаківський, В. І. Шупенюк, О. П. Сабадах, Л. Д. Болібрух // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Том 2. — № 1. — С. 92–96. | |
| dc.identifier.uri | https://ena.lpnu.ua/handle/ntb/46362 | - |
| dc.description.abstract | Надзвичайно важливим показником є висока чистота і стійкість вихідних та проміжних
продуктів, які використовують для синтезу триазенів, тому було розглянуто різні способи
отримання триазенів антрахінонового ряду, зокрема α- і β-аміно-9,10-антрацендіонів та
бромамінової кислоти з амінопохідними. Підібрано оптимальні умови реакції діазотування,
N-азосполучення та синтезу із високим виходом передбачуваних триазенів та здійснено їх
спектральну ідентифікацію. Мас-спектроскопією високої роздільної здатності досліджено
проблему прототропії 2-[2-(морфолін-4-іл) діазеніл] антрацен-9,10-діону з утворенням 2-гідро-
ксиантрацен-9,10-діону. | |
| dc.description.abstract | A very important indicator is the high purity and stability of the output and intermediate
products used for the synthesis of triazenes, therefore various methods for the preparation of triazenes
of the anthraquinones series, and in particular α- and β-amino-9,10-anthracenediones and bromaminic
acid with amino-derivatives, were considered. The optimal conditions for the reaction of diazotization,
N-azo coupling and synthesis with a high yield of triazenes are given and their spectral identification is
carried out. The problem of 2-[2-(morpholin-4-yl) diazenyl] anthracene-9,10-dione prototropy with the
formation of 2-hydroxyanthracene-9,10-dione was investigated with the high resolution mass
spectroscopy (HRMS). | |
| dc.format.extent | 92-96 | |
| dc.language.iso | uk | |
| dc.publisher | Lviv Politechnic Publishing House | |
| dc.relation.ispartof | Chemistry, Technology and Application of Substances, 1 (2), 2019 | |
| dc.subject | 2-[2-(морфолін-4-іл) діазеніл] антрацен-9 | |
| dc.subject | 10-діон | |
| dc.subject | бромамінова кислота | |
| dc.subject | діазотування | |
| dc.subject | N-азосполучення | |
| dc.subject | α-аміноантрацен-9 | |
| dc.subject | 10-діон | |
| dc.subject | β-аміноантрацен-9 | |
| dc.subject | 10-діон | |
| dc.subject | хромато-мас-спектр | |
| dc.subject | 2-[2-(morpholin-4-yl) diazenyl] anthracene-9 | |
| dc.subject | 10-dione | |
| dc.subject | bromaminic acid | |
| dc.subject | diazotization | |
| dc.subject | N-azocoupling | |
| dc.subject | α-aminoanthracene-9 | |
| dc.subject | 10-dione | |
| dc.subject | β-aminoanthracene-9 | |
| dc.subject | 10-dione | |
| dc.subject | chromaticmass spectrum | |
| dc.title | Особливості отримання триазенів антрахінонового ряду | |
| dc.title.alternative | Features of synthesis of triazenes of the anthraquinone series | |
| dc.type | Article | |
| dc.contributor.affiliation | Прикарпатський національний університет імені Василя Стефаника | |
| dc.contributor.affiliation | Національний університет “Львівська політехніка” | |
| dc.contributor.affiliation | Vasyl Stefanyk Precarpathian National University | |
| dc.contributor.affiliation | Lviv Polytechnic National University | |
| dc.format.pages | 5 | |
| dc.identifier.citationen | Features of synthesis of triazenes of the anthraquinone series / T. M. Taras, Y. I. Dejchakivsky, V. I. Shupeniuk, O. P. Sabadakh, L. D. Bolibrukh // Chemistry, Technology and Application of Substances. — Lviv : Lviv Politechnic Publishing House, 2019. — Vol 2. — No 1. — P. 92–96. | |
| dc.relation.references | 1. Gadjeva V. G. (2002). Two spin labeled triazenes: relationship between biochemical and biological activities Int. J. Pharm. 247, 39–45. | |
| dc.relation.references | 2. Kimball D. B., HaleyM. M. (2002). Triazenes: A Versatile Tool in Organic Synthesis Angew. Chem. Int. Ed. 41, 3338–3351. | |
| dc.relation.references | 3. Khramov D. M., Bielawski C. W. (2007). Donor – Acceptor Triazenes: Synthesis, Сharacterization, and study of Their Electronic and Thermal Properties J. Org. Chem. 72 (25), 9407–9417. DOI: 10.1021/jo070789x | |
| dc.relation.references | 4. Gornostaev L. M., Levdansky V. A. (1980). On the transformations of 1-azido-2- aryloxyanthraquinones and 3-aryloxyanthra [1,9-cd]-6- isoxazolones Russ. J. Org. Chem., Vol. 16, 10, 2209–2215. | |
| dc.relation.references | 5. Stefane B., Kocevar M., Polanc S. (1997). Nitrosation with Sodium Hexanitrocobaltate J. Org. Chem. 62, 7165–7169. | |
| dc.relation.references | 6. Baines K. M., Vaughan K., Hooper D. L., Leveck L. F. (1983). Open-chain nitrogen compound. Part IV. Synthesis of 5-hydroxy-1,2,3-triazoles from 1- aryl-3-(ethoxycarbonylmethyl) triazenes: a new route to α-diazo-N-arylacetamides Can. J. CHem., 61, 1549–1556. | |
| dc.relation.references | 7. Bulgakova N. A., Gornostaev L. M., Sakilidi V. T. (2000). Synthesis and structure of some triazenes of the 9,10-anthraquinone series Russ. J. Org. Chem., Vol. 36, 10, 1519–1520. | |
| dc.relation.references | 8. Bulgakova N. A. (2002). Sintez, struktura i svojstva nekotoryh proyzvodnyh 9,10-antrahinonu, soderzhashhih svjaz' azot-azot [Synthesis, structure and properties of some 9,10-anthraquinone derivatives containing a nitrogen-nitrogen bond]: abstract of the thesis for the degree of Candidate of Chemical Sciences, Krasnoyarsk State Pedagogical University named after V. P. Astafyev, Krasnoyarsk [in Russian]. | |
| dc.relation.references | 9. Wacker L. (1902). Ueber den Austausch der Diazogruppe durch die Amidogruppe Chem. Ber. 35, 2593–2602. | |
| dc.relation.references | 10. Sabadakh O. P., Taras T. N., Luchkevich E. R., Novikov V. P. (2015). Synthesis of triazene derivatives of 9,10-anthraquinone. Russ. J. Org. Chem., Vol. 51, 2, 277–278. DOI: 10.1134/S1070428015020244 | |
| dc.relation.references | 11. Dejchakivsky Y. I., Luchkevich E. R., Taras T. N., Bolibrukh L. D., Hubytska I. I. (2015). Pro diazotuvannja β-amino-9,10-antrahinonu [About diazotization of β-amino-9,10-anthrahinone] Journal of Lviv Polytechnic National University Series of Chemistry, Materials Technology and their Application, 812, 237–238 [in Ukrainian]. | |
| dc.relation.references | 12. Shupeniuk V. I., Dejchakivsky Y. I., Taras T. M., Bolibrukh L. D., Hubytska I. I. (2017). Pro osoblyvosti diazotuvannja aminopohidnyh 9,10- antrahinonu [About features of the diazotization of amino derivatives of 9,10-anthraquinone] Journal of Lviv Polytechnic National University Series of Chemistry, Materials Technology and their Application, 868, 186–195 [in Ukrainian]. | |
| dc.relation.references | 13. Shupeniuk V. I., Taras T. M., Bolibrukh L. D., Zhurakhivska L. R., Hubytska I. I. (2018). Interaction between structure and activity of synthesize triazenes at 4-substituted 9,10- anthraquinone. Journal of Lviv Polytechnic National University Series of Chemistry, Materials Technology and their Application, 868, 136–145 [in Ukrainian]. | |
| dc.relation.references | 14. Bulgakova N. A., Gornostaev L. M. (2001). Cyclization of 1-Aryl-3-[4-aryl (cyclohexyl) amino-9,10-dioxo-1-anthryl] triazenes to 3-Aryl-5-aryl (cyclohexyl)-aminoanthra [1,2 d][1,2,3] triazole-6,11-diones. Russian Journal of Organic Chemistry, vol. 37, no. 9, 1351–1352. | |
| dc.relation.references | 15. Amoroso J. W. (2014). Reactive Probes for Manipulating Polyketide Synthases, and Photoreactive Probes for Strained Alkyne Click Chemistry (Doctoral Dissertations). University of Massachusetts – Amherst. | |
| dc.relation.referencesen | 1. Gadjeva V. G. (2002). Two spin labeled triazenes: relationship between biochemical and biological activities Int. J. Pharm. 247, 39–45. | |
| dc.relation.referencesen | 2. Kimball D. B., HaleyM. M. (2002). Triazenes: A Versatile Tool in Organic Synthesis Angew. Chem. Int. Ed. 41, 3338–3351. | |
| dc.relation.referencesen | 3. Khramov D. M., Bielawski C. W. (2007). Donor – Acceptor Triazenes: Synthesis, Sharacterization, and study of Their Electronic and Thermal Properties J. Org. Chem. 72 (25), 9407–9417. DOI: 10.1021/jo070789x | |
| dc.relation.referencesen | 4. Gornostaev L. M., Levdansky V. A. (1980). On the transformations of 1-azido-2- aryloxyanthraquinones and 3-aryloxyanthra [1,9-cd]-6- isoxazolones Russ. J. Org. Chem., Vol. 16, 10, 2209–2215. | |
| dc.relation.referencesen | 5. Stefane B., Kocevar M., Polanc S. (1997). Nitrosation with Sodium Hexanitrocobaltate J. Org. Chem. 62, 7165–7169. | |
| dc.relation.referencesen | 6. Baines K. M., Vaughan K., Hooper D. L., Leveck L. F. (1983). Open-chain nitrogen compound. Part IV. Synthesis of 5-hydroxy-1,2,3-triazoles from 1- aryl-3-(ethoxycarbonylmethyl) triazenes: a new route to α-diazo-N-arylacetamides Can. J. CHem., 61, 1549–1556. | |
| dc.relation.referencesen | 7. Bulgakova N. A., Gornostaev L. M., Sakilidi V. T. (2000). Synthesis and structure of some triazenes of the 9,10-anthraquinone series Russ. J. Org. Chem., Vol. 36, 10, 1519–1520. | |
| dc.relation.referencesen | 8. Bulgakova N. A. (2002). Sintez, struktura i svojstva nekotoryh proyzvodnyh 9,10-antrahinonu, soderzhashhih svjaz' azot-azot [Synthesis, structure and properties of some 9,10-anthraquinone derivatives containing a nitrogen-nitrogen bond]: abstract of the thesis for the degree of Candidate of Chemical Sciences, Krasnoyarsk State Pedagogical University named after V. P. Astafyev, Krasnoyarsk [in Russian]. | |
| dc.relation.referencesen | 9. Wacker L. (1902). Ueber den Austausch der Diazogruppe durch die Amidogruppe Chem. Ber. 35, 2593–2602. | |
| dc.relation.referencesen | 10. Sabadakh O. P., Taras T. N., Luchkevich E. R., Novikov V. P. (2015). Synthesis of triazene derivatives of 9,10-anthraquinone. Russ. J. Org. Chem., Vol. 51, 2, 277–278. DOI: 10.1134/S1070428015020244 | |
| dc.relation.referencesen | 11. Dejchakivsky Y. I., Luchkevich E. R., Taras T. N., Bolibrukh L. D., Hubytska I. I. (2015). Pro diazotuvannja b-amino-9,10-antrahinonu [About diazotization of b-amino-9,10-anthrahinone] Journal of Lviv Polytechnic National University Series of Chemistry, Materials Technology and their Application, 812, 237–238 [in Ukrainian]. | |
| dc.relation.referencesen | 12. Shupeniuk V. I., Dejchakivsky Y. I., Taras T. M., Bolibrukh L. D., Hubytska I. I. (2017). Pro osoblyvosti diazotuvannja aminopohidnyh 9,10- antrahinonu [About features of the diazotization of amino derivatives of 9,10-anthraquinone] Journal of Lviv Polytechnic National University Series of Chemistry, Materials Technology and their Application, 868, 186–195 [in Ukrainian]. | |
| dc.relation.referencesen | 13. Shupeniuk V. I., Taras T. M., Bolibrukh L. D., Zhurakhivska L. R., Hubytska I. I. (2018). Interaction between structure and activity of synthesize triazenes at 4-substituted 9,10- anthraquinone. Journal of Lviv Polytechnic National University Series of Chemistry, Materials Technology and their Application, 868, 136–145 [in Ukrainian]. | |
| dc.relation.referencesen | 14. Bulgakova N. A., Gornostaev L. M. (2001). Cyclization of 1-Aryl-3-[4-aryl (cyclohexyl) amino-9,10-dioxo-1-anthryl] triazenes to 3-Aryl-5-aryl (cyclohexyl)-aminoanthra [1,2 d][1,2,3] triazole-6,11-diones. Russian Journal of Organic Chemistry, vol. 37, no. 9, 1351–1352. | |
| dc.relation.referencesen | 15. Amoroso J. W. (2014). Reactive Probes for Manipulating Polyketide Synthases, and Photoreactive Probes for Strained Alkyne Click Chemistry (Doctoral Dissertations). University of Massachusetts – Amherst. | |
| dc.citation.issue | 1 | |
| dc.citation.spage | 92 | |
| dc.citation.epage | 96 | |
| dc.coverage.placename | Lviv | |
| dc.coverage.placename | Lviv | |
| Appears in Collections: | Chemistry, Technology and Application of Substances. – 2019. – Vol. 2, No. 1
|
