https://oldena.lpnu.ua/handle/ntb/45180| Title: | Grape pomace extract as green vapor phase corrosion inhibitor |
| Other Titles: | Дослідження екстракту жмиху винограду як екологічно безпечного леткого інгібітору корозії сталі |
| Authors: | Vorobyova, Viktoria Chygyrynets’, Olena Skiba, Margarita Trus, Inna Frolenkova, Svitlana |
| Affiliation: | National Technical University of Ukraine «Igor Sikorsky Kyiv Polytechnic Institute» Ukrainian State Chemical-Engineering University, Dnipro, Ukraine |
| Bibliographic description (Ukraine): | Grape pomace extract as green vapor phase corrosion inhibitor / Viktoria Vorobyova, Olena Chygyrynets’, Margarita Skiba, Inna Trus, Svitlana Frolenkova // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 410–418. |
| Bibliographic description (International): | Grape pomace extract as green vapor phase corrosion inhibitor / Viktoria Vorobyova, Olena Chygyrynets’, Margarita Skiba, Inna Trus, Svitlana Frolenkova // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 3. — P. 410–418. |
| Is part of: | Chemistry & Chemical Technology, 3 (12), 2018 |
| Journal/Collection: | Chemistry & Chemical Technology |
| Issue: | 3 |
| Volume: | 12 |
| Issue Date: | 20-Jan-2018 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | екстракт жмиху винограду леткий інгібітор корозії сталі альдегіди квантово-хімічні розрахунки grape pomace extract volatile corrosion inhibitor aldehyde quantum-chemical calculation |
| Number of pages: | 9 |
| Page range: | 410-418 |
| Start page: | 410 |
| End page: | 418 |
| Abstract: | Екстракт жмиху винограду досліджено як
новий екологічно безпечний леткий інгібітор атмосферної коро-
зії сталі. Протикорозійні властивості оцінено масометричним
та електрохімічними методами. Методом ІЧ-спектроскопії та
газової хромато-мас-спектрометрії досліджено компонентний
складу ізопропанольного екстракту жмиху винограду. Дослід-
жено морфологію захисної плівки. Для оцінки адсорбційної здат-
ності головних компонентів рослинного екстракту проведені
квантово-хімічні розрахунки енергетичних параметрів молекул The inhibition effect of the grape pomace extract during the early stage of steel corrosion under adsorbed thin electrolyte layers was investigated. The present study was carried out to identify the components present in the 2-propanol grape pomace extract by GCMS analysis. Gravimetric, electrochemical impedance spectroscopy, potentiodynamic polarization, scanning electron microscopy, and FTIR techniques were used to study the corrosion inhibitive. Polarization measurements have indicated that these green inhibitors acted through mixed type inhibition. SEM studies have evidenced the formation of a protective film over metal surface while FTIR supported by molecular modelling has proved that this shielding effect was caused by aldehydes particularly 2-phenylacetaldehyde and 3,7-dimethylocta-2,6-dienal. |
| URI: | https://ena.lpnu.ua/handle/ntb/45180 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2018 ©Vorobyova V., Chygyrenets’ O., Skiba M., Trus I., Florenkova S., 2018 |
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| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 3 |
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| 2018v12n3_Vorobyova_V-Grape_pomace_extract_410-418.pdf | 656.61 kB | Adobe PDF | View/Open | |
| 2018v12n3_Vorobyova_V-Grape_pomace_extract_410-418__COVER.png | 526.73 kB | image/png | View/Open |
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