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Please use this identifier to cite or link to this item: https://oldena.lpnu.ua/handle/ntb/45157
Title: A preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol
Other Titles: Дослідження оксидів металу, як каталізаторів естерифікації лауринової кислоти з ізопропанолом
Authors: Krause, Fernanda
Maruyama, Swami Area
Wypych, Fernando
Affiliation: Federal University of Paraná
Bibliographic description (Ukraine): Krause F. A preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol / Fernanda Krause, Swami Area Maruyama, Fernando Wypych // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 158–166.
Bibliographic description (International): Krause F. A preliminary investigation concerning metal oxides as catalysts for esterification of lauric acid with isopropanol / Fernanda Krause, Swami Area Maruyama, Fernando Wypych // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 12. — No 2. — P. 158–166.
Is part of: Chemistry & Chemical Technology, 2 (12), 2018
Journal/Collection: Chemistry & Chemical Technology
Issue: 2
Volume: 12
Issue Date: 20-Jan-2018
Publisher: Lviv Politechnic Publishing House
Place of the edition/event: Lviv
Keywords: оксид металу
ізопропілаурат
есте- рифікація
лауринова кислота
ізопропіловий спирт
metal oxide
isopropyl laurate
esterification
lauric acid
isopropanol
Number of pages: 9
Page range: 158-166
Start page: 158
End page: 166
Abstract: Синтезовано ізопропілаурат з викорис- танням як каталізатора суміші оксидів металів. Найвищу кон- версію отримано за таких умов: 393 К, молярне співвідно- шення ізопропанол:лауринова кислота 10:1, склад каталіза- тора 33 % CuO, 33 % Ag2O і 33 % Al2O3, співвідношення каталізатор/лауринова кислота становить 8 мас %, час реакції 2 год. Показано, що оксиди каталізатора після естерифікації не перетворюються в інші речовини.
This paper reports the synthesis of isopropyl laurate while using a mixture of metal oxides as a catalyst. The best conversion value was obtained in the following conditions: 393 K, isopropanol:lauric acid molar ratio is10:1, composition of the catalyst is 33 % CuO, 33%Ag2O and 33 % Al2O3, catalyst/lauric acid ratio is 8%(w/w), and reaction time 2 h. Isolation of the catalysts after esterification showed that the oxides were not converted into other materials.
URI: https://ena.lpnu.ua/handle/ntb/45157
Copyright owner: © Національний університет „Львівська політехніка“, 2018
© Krause F., Maruyama S., Wypych F., 2018
URL for reference material: https://pubchem.ncbi.nlm.nih.gov/compound/25068
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[7] https://pubchem.ncbi.nlm.nih.gov/compound/1118#section=Toxicity
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[9] Sun J., Yang J., Li S. et al.: Catal. Commun., 2016, 83, 35.https://doi.org/10.1016/j.catcom.2016.05.002
[10] Cordeiro C., Silva R., Wypych F. et al.: Quim. Nova, 2011, 34,477. https://doi.org/10.1590/S0100-40422011000300021
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[25] Paiva E., Sterchele S., CorazzaM. et al.: Fuel, 2015, 153, 445.https://doi.org/10.1016/j.fuel.2015.03.021
[26] Lisboa F., Gardolinski J., Cordeiro C. et al.: J. Braz. Chem. Soc., 2012, 23, 46. https:// doi.org/10.1590/S0103-50532012000100008
References (International): [1] https://pubchem.ncbi.nlm.nih.gov/compound/25068
[2] http://www.panoleo.com/esters.html
[3] http://www.sigmaaldrich.com/catalog/
[4] Oliveira A., Sá A., Pimentel M.. et al., Spectrochim. Acta A,2017, 170, 56. https://doi.org/10.1016/j.saa.2016.07.006
[5] KuzminskaM., Backov R., Gaigneaux E., Catal. Commun.,2015, 59, 222. https://doi.org/10.1016/j.catcom.2014.10.033
[6] http://www.qca.ibilce.unesp.br/prevencao/produtos/acido_sulfurico.html
[7] https://pubchem.ncbi.nlm.nih.gov/compound/1118#section=Toxicity
[8] Piker A., Tabah B., Perkas N. et al., Fuel, 2016, 182, 34.https://doi.org/10.1016/j.fuel.2016.05.078
[9] Sun J., Yang J., Li S. et al., Catal. Commun., 2016, 83, 35.https://doi.org/10.1016/j.catcom.2016.05.002
[10] Cordeiro C., Silva R., Wypych F. et al., Quim. Nova, 2011, 34,477. https://doi.org/10.1590/S0100-40422011000300021
[11]Maruyama S., Kanda L., Wypych F., J. Braz. Chem. Soc.,2017, 28, 985. https://doi.org/10.21577/0103-5053.20160251
[12]Wyckoff R., Am. J. Sci., 1922, 5, 184.https://doi.org/10.2475/ajs.s5-3.15.184
[13] Yong N., Ahmad A., Mohammad A., Int. J. Sci. Eng. Res.,2013, 4, 155.
[14] Isernia L.:Mater. Res., 2013, 16, 792.https://doi.org/10.1590/S1516-14392013005000044
[15] Dubal D., Dhawale D., Salunkhe R. et al., J. Alloys Compd.,2010, 492, 26. https:// doi.org/10.1016/j.jallcom.2009.11.149
[16] Boumaza A., Djelloul A., Guerrab F., Powder Technol., 2010, 201, 177. https://doi.org/10.1016/j.powtec.2010.03.036
[17] SangappaM., Thiagarajan P., Indian J. Pharm. Sci., 2015, 77, 151.
[18] Azam A., Ahmed A., Oves M. et al., Int. J. Nanomed., 2012, 7, 3527. https://doi.org/10.2147/IJN.S29020
[19] Raul P., Senapati S., Sahoo A. et al., RSC Adv., 2014, 4, 40580. https:// doi.org/10.1039/P.4ra04619f
[20] Xu Y., Chen D., Jiao X., J. Phys. Chem. B, 2005, 109, 13561. https://doi.org/10.1021/jp051577b
[21]Moya-León A., Viales-Montero C., Arias-Carrillo M. et al., Cienc. Tecnol. (San Jose, Costa Rica), 2006, 24, 175.
[22] Voll F., da Silva C., Rossi C. et al., Biomass Bioenerg., 2011,35, 781. https://doi.org/10.1016/j.biombioe.2010.10.035
[23] Yan S., Salley S., Ng K., Appl. Catal. A, 2009, 353, 203.https://doi.org/10.1016/j.apcata.2008.10.053
[24] Paiva E., CorazzaM., Sierakowski M. et al., Biores. Technol.,2015, 193, 337. https://doi.org/10.1016/j.biortech.2015.06.079
[25] Paiva E., Sterchele S., CorazzaM. et al., Fuel, 2015, 153, 445.https://doi.org/10.1016/j.fuel.2015.03.021
[26] Lisboa F., Gardolinski J., Cordeiro C. et al., J. Braz. Chem. Soc., 2012, 23, 46. https:// doi.org/10.1590/S0103-50532012000100008
Content type: Article
Appears in Collections:Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 2

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