https://oldena.lpnu.ua/handle/ntb/45034| Title: | Improvement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment |
| Other Titles: | Вдосконалення гомогенно-каталітичного процесу окиснення алкілароматичних сполук за допомогою поєднання бінарних каталітичних систем і ультразвукового оброблення |
| Authors: | Реутський, В. В. Гринчук, Ю. М. Олійник, Л. Р. Reutskyy, V. V. Hrynchuk, Y. M. Olijnyk, L. P. |
| Affiliation: | Національний університет ”Львівська політехніка” |
| Bibliographic description (Ukraine): | Reutskyy V. V. Improvement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment / V. V. Reutskyy, Y. M. Hrynchuk, L. P. Olijnyk // Chemistry, Technology and Application of Substance. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 1. — No 1. — P. 54–58. |
| Bibliographic description (International): | Reutskyy V. V. Improvement of homogeneous catalytic process of oxidation of alkylaromatic compounds by combination of binary catalytic systems and ultrasound treatment / V. V. Reutskyy, Y. M. Hrynchuk, L. P. Olijnyk // Chemistry, Technology and Application of Substance. — Lviv : Lviv Politechnic Publishing House, 2018. — Vol 1. — No 1. — P. 54–58. |
| Is part of: | Chemistry, Technology and Application of Substance, 1 (1), 2018 |
| Journal/Collection: | Chemistry, Technology and Application of Substance |
| Issue: | 1 |
| Volume: | 1 |
| Issue Date: | 26-Feb-2018 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | окиснення етилбензол поверхнево-активні сполуки каталітичні системи гідропероксид етилбензолу ацетофенон ультразвук oxidation ethylbenzene surface active compounds catalytic systems hydroperoxide of ethylbenzene acetophenone ultrasound |
| Number of pages: | 5 |
| Page range: | 54-58 |
| Start page: | 54 |
| End page: | 58 |
| Abstract: | Досліджено вплив сумісного застосування каталітичних систем на основі
промислових каталізаторів окиснення та поверхнево-активних речовин різної природи (йонно- та нейонногенних) і ультразвукового оброблення реакційної суміші на процес
рідиннофазного окиснення алкілароматичних сполук. Одержані результати дають змогу
стверджувати, що сумісне застосування каталітичних систем та ультразвукового
оброблення впливає на окиснення етилбензолу. Створені каталітичні системи не лише
збільшують продуктивність реакційного обладнання за цільовими продуктами, але й
здатні змінювати селективність процесу в бік утворення необхідного продукту. Article is devoted to research of impact of combined use of catalytic systems based on industrial oxidation catalysts and surface-active compounds of different nature (ion- and noniongenic) with ultrasonic treat ment of reaction mixture at alkylaromatic compounds liquidphase oxidation process. Obtained results showed that combined use of catalytic system and ultrasound has impact on ethylbenzene oxidation. Created catalytic systems not only increase productivity of reaction volume (for aim products), but also allow to shift process selectivity towards creation of desired product. |
| URI: | https://ena.lpnu.ua/handle/ntb/45034 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2018 © Реутський В. В., Гринчук Ю. М., Олійник Л. П., 2018 |
| References (Ukraine): | 1. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. The influence of crownethers by catalytic oxidation of cyclohexane // Reports of NAS of Ukraine, 1 (2001), 154–157. 2. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. Influence of polyglicols on catalytic oxidation of cyclohexane // Bulletin of NU“Lvivska politechnika”. Chemistry, technology of materials and their applications. 2001 426, 91–94. 3. Emanuel N. M., GalD. Oxidation of ethylbenzene. (Model Rection). Moscow: Nauka, 1984. – 376 p. 4. Reutskyy V. V., Melnyk Yu. R., Starchevskyy V. L. Influence of surface-active matters on ethylbenzene oxidation // Book of abstracts of 17 th International Symposium on Homogeneous Catalysis. Poznan, Poland, 2010, p. 201. 5. Haifeng Xiong, Yuhua Zhang, Kongyong Liew, Jinlin Li Ruthenium promotion of Co/SBA catalysts with high cobalt loading for Fisher-Tropsh synthesis // Fuel Processing Technology, 90, Issue 2(2009), 237–246. 6. Shanghong Zeng, Dongping Du, Fenghua Bai, Haiquan Su Bridging complexes of rare earth and cobalt cluster as catalyst precursor for Fisher-Tropsh synthesis // Journal of Rare Earths, 29, Issue 4(2011),349–353. 7. Cancheng Guo, Quingjing Peng, Qiang Liu Selective oxidation of ethylbenzene with air catalyzed by simple μ-oxo dimeric metalloporphyrins under mild conditions in the absence of additives. // Journal of Molecular Catalysis A: Chemical, 192, Issues 1-2(2003), 295–302. 8. Arshadi M., Ghiaci M., Rahmanian A., Ghaziaskar H., Gil A. Oxidation of ethylbenzene to acetophenone by a Mn catalyst supported on a modified nanosized SiO2/Al2O3 mixed-oxide in supercritical carbon dioxide // Applied Catalysis B: Environmental, 119–120(2012), 81–90. 9. Xiao Gang Li, Jing Wang, Ren HeSelective oxidation of ethylbenzene catalyzed by fluorinated metalloporphyrins with molecular oxygen // Chinese Chemical Letters, 18, Issue 9 (2007), 1053–1056. 10. Ahmadrez aEsmaeilbeig, Hamidreza Samouei, Sedigheh Abedanzadeh, Zahra Amirghofran Synthesis, characterization and antitumor activity study of some cyclometalatedorganoplatinum (II) complexes containing aromatic N-donor ligands. // Journal of Organometallic Chemistry, 696, Issue 20(2011), 3135–3142. 11. Реутский В. В. Каталитическое окисление циклогексана в акустическом поле: дисс. ... канд. хим. наук. – Львов, 1988. – 119 с. |
| References (International): | 1. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. The influence of crownethers by catalytic oxidation of cyclohexane, Reports of NAS of Ukraine, 1 (2001), 154–157. 2. Melnyk Y. R., Reutskyy V. V., Mokryj E. M. Influence of polyglicols on catalytic oxidation of cyclohexane, Bulletin of NU"Lvivska politechnika". Chemistry, technology of materials and their applications. 2001 426, 91–94. 3. Emanuel N. M., GalD. Oxidation of ethylbenzene. (Model Rection). Moscow: Nauka, 1984, 376 p. 4. Reutskyy V. V., Melnyk Yu. R., Starchevskyy V. L. Influence of surface-active matters on ethylbenzene oxidation, Book of abstracts of 17 th International Symposium on Homogeneous Catalysis. Poznan, Poland, 2010, p. 201. 5. Haifeng Xiong, Yuhua Zhang, Kongyong Liew, Jinlin Li Ruthenium promotion of Co/SBA catalysts with high cobalt loading for Fisher-Tropsh synthesis, Fuel Processing Technology, 90, Issue 2(2009), 237–246. 6. Shanghong Zeng, Dongping Du, Fenghua Bai, Haiquan Su Bridging complexes of rare earth and cobalt cluster as catalyst precursor for Fisher-Tropsh synthesis, Journal of Rare Earths, 29, Issue 4(2011),349–353. 7. Cancheng Guo, Quingjing Peng, Qiang Liu Selective oxidation of ethylbenzene with air catalyzed by simple m-oxo dimeric metalloporphyrins under mild conditions in the absence of additives., Journal of Molecular Catalysis A: Chemical, 192, Issues 1-2(2003), 295–302. 8. Arshadi M., Ghiaci M., Rahmanian A., Ghaziaskar H., Gil A. Oxidation of ethylbenzene to acetophenone by a Mn catalyst supported on a modified nanosized SiO2/Al2O3 mixed-oxide in supercritical carbon dioxide, Applied Catalysis B: Environmental, 119–120(2012), 81–90. 9. Xiao Gang Li, Jing Wang, Ren HeSelective oxidation of ethylbenzene catalyzed by fluorinated metalloporphyrins with molecular oxygen, Chinese Chemical Letters, 18, Issue 9 (2007), 1053–1056. 10. Ahmadrez aEsmaeilbeig, Hamidreza Samouei, Sedigheh Abedanzadeh, Zahra Amirghofran Synthesis, characterization and antitumor activity study of some cyclometalatedorganoplatinum (II) complexes containing aromatic N-donor ligands., Journal of Organometallic Chemistry, 696, Issue 20(2011), 3135–3142. 11. Reutskii V. V. Kataliticheskoe okislenie tsikloheksana v akusticheskom pole: diss. ... kand. khim. nauk, Lvov, 1988, 119 p. |
| Content type: | Article |
| Appears in Collections: | Chemistry, Technology and Application of Substances. – 2018. – Vol. 1, No. 1 |
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| 2018v1n1_Reutskyy_V_V-Improvement_of_homogeneous_54-58.pdf | 334.36 kB | Adobe PDF | View/Open | |
| 2018v1n1_Reutskyy_V_V-Improvement_of_homogeneous_54-58__COVER.png | 423.24 kB | image/png | View/Open |
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