https://oldena.lpnu.ua/handle/ntb/43915| Title: | Synthesis of methanol from methane in cavitation field |
| Other Titles: | Синтез метанолу з метану в кавітаційному полі |
| Authors: | Tselishchev, Oleksii Ijagbuji, Ayodeji Loriia, Maryna Nosach, Vanadii |
| Affiliation: | Volodymyr Dahl East Ukrainian National University JSC «ORGCHIM» |
| Bibliographic description (Ukraine): | Synthesis of methanol from methane in cavitation field / Oleksii Tselishchev, Ayodeji Ijagbuji, Maryna Loriia, Vanadii Nosach // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 69–73. |
| Bibliographic description (International): | Synthesis of methanol from methane in cavitation field / Oleksii Tselishchev, Ayodeji Ijagbuji, Maryna Loriia, Vanadii Nosach // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2-18. — Vol 12. — No 1. — P. 69–73. |
| Is part of: | Chemistry & Chemical Technology, 1 (12), 2-18 |
| Issue: | 1 |
| Volume: | 12 |
| Issue Date: | 20-Jan-2018 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | активація метану гідроксильний радикал метильний радикал кавітація синтез метанолу methane activation hydroxyl radical methyl radical cavitation methanol synthesis |
| Number of pages: | 5 |
| Page range: | 69-73 |
| Start page: | 69 |
| End page: | 73 |
| Abstract: | Розроблений спосіб синтезу метанолу за
вільно-радикальним механізмом з використанням метану і
гідроксильних радикалів. Метан та пероксид гідрогену
подаються у кавітаційне поле. Головними продуктами реакції є
метанол і вода. Розраховано ступінь перетворення метану,
який дорівнює ~10 %. Methanol synthesis was achieved by a free-radical mechanism of the compounding reaction of methane and hydroxyl radical. Experiments were performed by feeding methane and hydrogen-peroxide into a cavitation field. The major reaction products were methanol and water molecules. The calculated degree of methane conversion equals to ~10 %. |
| URI: | https://ena.lpnu.ua/handle/ntb/43915 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2018 © Tselishchev O., Ijagbuji A., Loriia M., Nosach V., 2018 |
| URL for reference material: | https://doi.org/10.1038/30934 https://doi.org/10.1021/cr00036a005 https://doi.org/10.1070/RC2005v074n12ABEH001199 https://doi.org/10.4028/www.scientific.net/AMR.660.51 https://doi.org/10.1016/j.jece.2014.08.008 https://doi.org/10.1016/j.jhazmat.2009.03.122 https://doi.org/10.1007/978-1-4615-4787-7 https://doi.org/10.1023/A:1015207214720 |
| References (Ukraine): | [1] Imperial Chemical Industries (ICI). Methanol Synthesis Technology, London 1966. [2] Dlugokencky E., Masarie K., Lang P. et al.: Nature, 1998, 393,447. https://doi.org/10.1038/30934 [3] Crabtree R.: Chem. Rev., 1995, 95, 987.https://doi.org/10.1021/cr00036a005 [4] Rozovskyy A., Lin G.: Teoreticheskie Osnovy Processa Sinteza Metanola. Khimiya, Moskva 1990. [5] Shilov A., Shul'pin G.: Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence ofMetal Complexes [in:] Parkins A. (Ed.), Applied Organometallic Chemistry. Kluwer Academic Publishers, Dordrecht 2000. [6] Rudakov E.: Elektroliz v Neorganicheskoi Khimii. Naukova Dumka, Kiev 1985. [7] Arutyunov V., Krylov E.: Uspekhi Khimii, 2005, 74, 1216.https://doi.org/10.1070/RC2005v074n12ABEH001199 [8] Tselishchev A., Zakharov I., Loriya M. et al.: Voprosy Khim. i Khim. Technol., 2012, 2, 39. [9] Loriya M., Ijagbuji A., Tselischev A. et al.: Adv. Mat. Res., 2013,660, 51. https://doi.org/10.4028/www.scientific.net/AMR.660.51 [10] Tselishchev A., LòriyaM., Zakharov I.: Visnyk Kiev Polytech. Inst., 2011, 65, 111. [11] Zakharov I., Ijagbuji A., Tselischev A. et al.: J. Environ. Chem. Eng., 2015, 3, 405. https://doi.org/10.1016/j.jece.2014.08.008 [12] ZamilovM., Godin S.: Quant. Potent. Corp., 2012, 1. [13] Wang X., Wang J., GuoW. et al.: J. Hazard. Mater, 2009, 169,486 – 491. https://doi.org/10.1016/j.jhazmat.2009.03.122 [14] Shah Y., Pandit A., Moholkar V.: Cavitation Reaction Engineering. Kluwer Academic/Plenum Publ., New York 1999.https://doi.org/10.1007/978-1-4615-4787-7 [15] Tselischev A., Nosach V., KoshovetsM. et al.: Pat. UA104811 MEI G05D 19/00, Publ. Febr. 25, 2016. [16] Tselishchev A., Zakharov I., Loriya M. et al.: Khim. Promysh. Ukrainy, 2014, 121, 39. [17] Tselischev A., Nosach V., KoshovetsM. et. al.: Pat. UA105427 MEI S10G 2/100, Publ. March 25, 2016. [18] Jiang H., Gong H., Yang Z. et al.: React. Kinetic Catal. Lett.,2002, 75, 315. https://doi.org/10.1023/A:1015207214720 [19] Tselishchev A., LòriyaM., Eliseev P. et al.: East. Eur. J. Enterp. Technol., 2015, 6, 48. [20] Tselischev A., Elissev P., LòryiaM. et al.:Matematicheskoe Modelirovanie Technologicheskikh Protsessov. Vostochnoukr. Nats. Univ., Lugansk 2011. |
| References (International): | [1] Imperial Chemical Industries (ICI). Methanol Synthesis Technology, London 1966. [2] Dlugokencky E., Masarie K., Lang P. et al., Nature, 1998, 393,447. https://doi.org/10.1038/30934 [3] Crabtree R., Chem. Rev., 1995, 95, 987.https://doi.org/10.1021/cr00036a005 [4] Rozovskyy A., Lin G., Teoreticheskie Osnovy Processa Sinteza Metanola. Khimiya, Moskva 1990. [5] Shilov A., Shul'pin G., Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence ofMetal Complexes [in:] Parkins A. (Ed.), Applied Organometallic Chemistry. Kluwer Academic Publishers, Dordrecht 2000. [6] Rudakov E., Elektroliz v Neorganicheskoi Khimii. Naukova Dumka, Kiev 1985. [7] Arutyunov V., Krylov E., Uspekhi Khimii, 2005, 74, 1216.https://doi.org/10.1070/RC2005v074n12ABEH001199 [8] Tselishchev A., Zakharov I., Loriya M. et al., Voprosy Khim. i Khim. Technol., 2012, 2, 39. [9] Loriya M., Ijagbuji A., Tselischev A. et al., Adv. Mat. Res., 2013,660, 51. https://doi.org/10.4028/www.scientific.net/AMR.660.51 [10] Tselishchev A., LòriyaM., Zakharov I., Visnyk Kiev Polytech. Inst., 2011, 65, 111. [11] Zakharov I., Ijagbuji A., Tselischev A. et al., J. Environ. Chem. Eng., 2015, 3, 405. https://doi.org/10.1016/j.jece.2014.08.008 [12] ZamilovM., Godin S., Quant. Potent. Corp., 2012, 1. [13] Wang X., Wang J., GuoW. et al., J. Hazard. Mater, 2009, 169,486 – 491. https://doi.org/10.1016/j.jhazmat.2009.03.122 [14] Shah Y., Pandit A., Moholkar V., Cavitation Reaction Engineering. Kluwer Academic/Plenum Publ., New York 1999.https://doi.org/10.1007/978-1-4615-4787-7 [15] Tselischev A., Nosach V., KoshovetsM. et al., Pat. UA104811 MEI G05D 19/00, Publ. Febr. 25, 2016. [16] Tselishchev A., Zakharov I., Loriya M. et al., Khim. Promysh. Ukrainy, 2014, 121, 39. [17] Tselischev A., Nosach V., KoshovetsM. et. al., Pat. UA105427 MEI S10G 2/100, Publ. March 25, 2016. [18] Jiang H., Gong H., Yang Z. et al., React. Kinetic Catal. Lett.,2002, 75, 315. https://doi.org/10.1023/A:1015207214720 [19] Tselishchev A., LòriyaM., Eliseev P. et al., East. Eur. J. Enterp. Technol., 2015, 6, 48. [20] Tselischev A., Elissev P., LòryiaM. et al.:Matematicheskoe Modelirovanie Technologicheskikh Protsessov. Vostochnoukr. Nats. Univ., Lugansk 2011. |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2018. – Vol. 12, No. 1 |
| File | Description | Size | Format | |
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| 2-18v12n1_Tselishchev_O-Synthesis_of_methanol_69-73.pdf | 234.33 kB | Adobe PDF | View/Open | |
| 2-18v12n1_Tselishchev_O-Synthesis_of_methanol_69-73__COVER.png | 533 kB | image/png | View/Open |
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