https://oldena.lpnu.ua/handle/ntb/42088| Title: | Oleochemical synthesis of sulfanes, their structure and properties |
| Other Titles: | Олеохімічний синтез сульфанів, їх будова та властивості |
| Authors: | Bodachivskyi, Iurii Pop, Grigoriy Zheleznyi, Leonid Zubenko, Stepan Okhrimenko, Mykhailo |
| Affiliation: | Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine |
| Bibliographic description (Ukraine): | Oleochemical synthesis of sulfanes, their structure and properties / Iurii Bodachivskyi, Grigoriy Pop, Leonid Zheleznyi, Stepan Zubenko, Mykhailo Okhrimenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 3. — P. 365–371. |
| Bibliographic description (International): | Oleochemical synthesis of sulfanes, their structure and properties / Iurii Bodachivskyi, Grigoriy Pop, Leonid Zheleznyi, Stepan Zubenko, Mykhailo Okhrimenko // Chemistry & Chemical Technology. — Lviv : Lviv Politechnic Publishing House, 2017. — Vol 11. — No 3. — P. 365–371. |
| Is part of: | Chemistry & Chemical Technology, 3 (11), 2017 |
| Issue: | 3 |
| Volume: | 11 |
| Issue Date: | 20-Jan-2017 |
| Publisher: | Lviv Politechnic Publishing House |
| Place of the edition/event: | Lviv |
| Keywords: | ріпакова олія органічні сульфани синтез механізми реакцій додатки до мастильних матеріалів rapeseed oil organic sulfanes synthesis reaction mechanisms lubricant additives |
| Number of pages: | 7 |
| Page range: | 365-371 |
| Start page: | 365 |
| End page: | 371 |
| Abstract: | Вперше внаслідок послідовної вулканізації
алкілових естерів вищих жирних кислот ріпакової олії
пероксидом бензоїлу та елементним сульфуром синтезовано
олеохімічні сульфани. Методами інструментального аналізу
встановлено їх будову і властивості. Показано, що олеохімічні
сульфани – комлексні структури різного ступеню зшивання,
характеризуються відмінними антиокиснювальними й трибо-
логічними властивостями і не викликають корозії міді та
сталі зажорстких умов тестування. For the first time, oleochemical sulfanes were synthesized via sequential vulcanization of fatty acid alkyl esters from rapeseed oil by benzoyl peroxide and elemental sulfur. Their structure and properties were established by the methods of instrumental analysis and it was shown that oleochemical sulfanes are complex structures with different cross-linking degrees, which provide excellent antioxidant and tribological characteristics and do not cause steel or copper corrosion under harsh test conditions. |
| URI: | https://ena.lpnu.ua/handle/ntb/42088 |
| Copyright owner: | © Національний університет „Львівська політехніка“, 2017 © Bodachivskyi I., Pop G., Zheleznyi L., Zubenko S., Okhrimenko M., 2017 |
| URL for reference material: | https://doi.org/10.1021/cr010127m https://doi.org/10.1002/9781118799734 https://doi.org/10.1016/j.fuel.2013.06.020 https://doi.org/10.1016/j.tca.2012.05.029 https://doi.org/10.1016/j.jhazmat.2008.03.078 |
| References (Ukraine): | [1] Steudel R.: Chem. Rev., 2002, 102, 3905. https://doi.org/10.1021/cr010127m [2] Torbacke M., Rudolphi A., Kassfeldt E.: Lubricants: Introduction to Properties and Performance. Wiley, Chichester 2014. https://doi.org/10.1002/9781118799734 [3] Cristano A.: NLGI Spokesman, 2000, 64, 22. [4] Rudnick L.: Lubricant Additives: Chemistry and Application. CRC Press, New York 2010. [5] Popov Y., Uskach Y, Ledenyov S. et al.: Khim. i Technol. Topliv i Masel, 2014, 3, 17. [6] Ledenyov S, Popov Y., Kroman D., Pavlova V.: Khim. i Technol. Topliv i Masel, 2015, 5, 21. [7] Krueger M., Byers J., Turchin H.: Pat. EU 0656415A1, Publ. Jun. 07, 1995. [8] Bodachivskyi Y., Pop G.: Kataliz i Neftehimiya, 2014, 23, 27. [9] Bodachivskyi Y., Pop G., Rogalskyi S.: Kataliz i Neftehimiya, 2015, 24, 41. [10] Armarego W., Chai C.: Purification of Laboratory Chemicals. Elsevier Inc., Waltham 2013. [11] Patrylak L., Patrylak K., Okhrimenko M. et al.: Fuel, 2013, 113, 650. https://doi.org/10.1016/j.fuel.2013.06.020 [12] Zubenko S., Patrylak L.: Kataliz i Neftehimiya, 2014, 23, 46. [13] Frisch M., Trucks G., Schlegel H. et al.: Gaussian 09, Revision A.02. Gaussian, Wallingford 2009. [14] Ishchuk Yu.: Technologia Plastichnyh Smazok. Naukova dumka, Kiev 1986. [15] Antonovskyi V., Hursan S.: Fizicheskaya Khimia Organicheskih Peroksidov. Akademkniga, Moskva 2003. [16] Pretsch E., Buhlman P., Badertscher M.: Structure Determination of Organic Compounds. Springer, Berlin 2009. [17] Hofmann W.: Vulkanizatsiya i Vulkanizuyuschiye Agenty. Khimiya, Moskva 1968. [18] Zhaoa B., Wana P., Liua J. et al.: Thermochimica Acta, 2012, 543, 232. https://doi.org/10.1016/j.tca.2012.05.029 [19] Lua K., Chena T., Hu K.: J. Hazard. Mat., 2009, 161, 246. https://doi.org/10.1016/j.jhazmat.2008.03.078 [20] Lv J., Chen W., Chen L. et al.: Proceed. AiChe Annual Meeting, USA, San Francisco 2013, 318455. [21] Sun C., Yang S., Lin X. et al.: Chem. Res. Chinese Univ., 2003, 19, 355. [22] Wunderlich B.: Thermal Analysis of Polymeric Materials. Springer, Berlin 2005. |
| References (International): | [1] Steudel R., Chem. Rev., 2002, 102, 3905. https://doi.org/10.1021/cr010127m [2] Torbacke M., Rudolphi A., Kassfeldt E., Lubricants: Introduction to Properties and Performance. Wiley, Chichester 2014. https://doi.org/10.1002/9781118799734 [3] Cristano A., NLGI Spokesman, 2000, 64, 22. [4] Rudnick L., Lubricant Additives: Chemistry and Application. CRC Press, New York 2010. [5] Popov Y., Uskach Y, Ledenyov S. et al., Khim. i Technol. Topliv i Masel, 2014, 3, 17. [6] Ledenyov S, Popov Y., Kroman D., Pavlova V., Khim. i Technol. Topliv i Masel, 2015, 5, 21. [7] Krueger M., Byers J., Turchin H., Pat. EU 0656415A1, Publ. Jun. 07, 1995. [8] Bodachivskyi Y., Pop G., Kataliz i Neftehimiya, 2014, 23, 27. [9] Bodachivskyi Y., Pop G., Rogalskyi S., Kataliz i Neftehimiya, 2015, 24, 41. [10] Armarego W., Chai C., Purification of Laboratory Chemicals. Elsevier Inc., Waltham 2013. [11] Patrylak L., Patrylak K., Okhrimenko M. et al., Fuel, 2013, 113, 650. https://doi.org/10.1016/j.fuel.2013.06.020 [12] Zubenko S., Patrylak L., Kataliz i Neftehimiya, 2014, 23, 46. [13] Frisch M., Trucks G., Schlegel H. et al., Gaussian 09, Revision A.02. Gaussian, Wallingford 2009. [14] Ishchuk Yu., Technologia Plastichnyh Smazok. Naukova dumka, Kiev 1986. [15] Antonovskyi V., Hursan S., Fizicheskaya Khimia Organicheskih Peroksidov. Akademkniga, Moskva 2003. [16] Pretsch E., Buhlman P., Badertscher M., Structure Determination of Organic Compounds. Springer, Berlin 2009. [17] Hofmann W., Vulkanizatsiya i Vulkanizuyuschiye Agenty. Khimiya, Moskva 1968. [18] Zhaoa B., Wana P., Liua J. et al., Thermochimica Acta, 2012, 543, 232. https://doi.org/10.1016/j.tca.2012.05.029 [19] Lua K., Chena T., Hu K., J. Hazard. Mat., 2009, 161, 246. https://doi.org/10.1016/j.jhazmat.2008.03.078 [20] Lv J., Chen W., Chen L. et al., Proceed. AiChe Annual Meeting, USA, San Francisco 2013, 318455. [21] Sun C., Yang S., Lin X. et al., Chem. Res. Chinese Univ., 2003, 19, 355. [22] Wunderlich B., Thermal Analysis of Polymeric Materials. Springer, Berlin 2005. |
| Content type: | Article |
| Appears in Collections: | Chemistry & Chemical Technology. – 2017. – Vol. 11, No. 3 |
| File | Description | Size | Format | |
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| 2017v11n3_Bodachivskyi_I-Oleochemical_synthesis_365-371.pdf | 571.07 kB | Adobe PDF | View/Open | |
| 2017v11n3_Bodachivskyi_I-Oleochemical_synthesis_365-371__COVER.png | 501.84 kB | image/png | View/Open |
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