https://oldena.lpnu.ua/handle/ntb/39896| Title: | Effect of the reactants molar ratio on the kinetics of cycloaddition of 2,3-dimethylbuta-1,3-diene to allylmethacrylate |
| Authors: | Kostiv, I. Marshalok, G. Marshalok, O. |
| Affiliation: | Lviv Polytechnic National University |
| Bibliographic description (Ukraine): | Kostiv I. Effect of the reactants molar ratio on the kinetics of cycloaddition of 2,3-dimethylbuta-1,3-diene to allylmethacrylate / I. Kostiv, G. Marshalok, O. Marshalok // Litteris et Artibus : proceedings of the 5th International youth science forum, November 26–28, 2015, Lviv, Ukraine / Lviv Polytechnic National University. – Lviv : Lviv Polytechnic Publishing House, 2015. – P. 354–357. – Bibliography: 13 titles. |
| Conference/Event: | Litteris et Artibus |
| Issue Date: | 2015 |
| Publisher: | Lviv Polytechnic Publishing House |
| Country (code): | UA |
| Place of the edition/event: | Lviv |
| Keywords: | 2,3-dimethylbuta-1,3-diene allylmethacrylate allyl-1,3,4-trimethylcyclohex-3-ene-1-carboxylate cycloaddition reaction Michaelis–Menten equation effective rate constants intermediate complex limiting stage |
| Number of pages: | 354-357 |
| Abstract: | The cycloaddition reaction between 2,3-dimethylbuta-1,3-diene and allylmethacrylate proceeds by the second order kinetics. The rate constants increase with the increase in the excess of one of the reactants. The change in the effective rate constants is described by the Michaelis–Menten equation indicating that the reaction proceeds through the initial equilibrium stage of formation of an intermediate complex which then transforms into the product. The effective rate constants, the equilibrium constants of formation of the intermediate complex, and the rate constant of its transformation into the reaction product were determined, as well as the thermodynamic parameters of the formation of the intermediate complex and the activation parameters of the transformation of the intermediate complex into the product. The limiting stage of the reaction is established and its mechanism is suggested. |
| URI: | https://ena.lpnu.ua/handle/ntb/39896 |
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| Content type: | Conference Abstract |
| Appears in Collections: | Litteris et Artibus. – 2015 р. |
| File | Description | Size | Format | |
|---|---|---|---|---|
| 130-354-357.pdf | 150.02 kB | Adobe PDF | View/Open |
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