Порівняння результатів детектування як методами неперервного та імпульсного спостереження

Abstract

Traditional continuous wave methods of observation of NMR and NQR is now almost completely superseded by pulse Fourier transform spectroscopy. Compared with the method of continuous frequency scanning, pulse Fourier transform spectroscopy has advantages, which consists in a high sensitivity, increased spectrum resolution, much less distortion of the lines shape. In addition, pulse spectroscopy provides a reduction in the time of observation compared with stationary methods. The aim of the paper is to determine the effectiveness of assessment of output materials for photoelectronics by NQR hardware methods. The comparison of the NQR spectra obtained by the method of continuous passage of the resonance lines and the pulse method with a fast Fourier transformation are performed in this paper. Research was done both on the nitrogen containing substance and the annealed GaSe and InSe crystals important for heterostructures production. Resonance of nitrogen 14N nuclei is in the low-frequency region (100 kHz – 5 MHz) and has a weak intensity, caused by small value of the quantum transitions energy. Obtained results indicate a higher resolution of NQR pulse spectroscopy in comparison with continuous spectroscopy. Based on these experimental results it can be concluded that the same signal / noise ratio, methods of continuous frequency scanning and pulsed excitation provide identical results, but the shapes of resonance lines obtained using these methods are different. In the pulse method there is a simultaneous response of all resonant transitions, i.e. it is recorded that response of nuclear induction over which the Fourier transform is made. In case of stationary technique – slow passage of resonance while maintaining a quasi-equilibrium nuclear spin excitation conditions is made at a single frequency. This leads to a decrease in the spectrometer sensitivity, so that the registration process is much longer. Application of NQR pulse method of fast Fourier transform for the study of layered semiconductors is more appropriate than the stationary method based on continuous frequency scanning in resonance area. Pulse method provides better spectra resolution, and also enables to determine a time of nuclear spin relaxation. It was found that in both cases the spectra with the same values of the signal / noise ratio can be obtained, while in the pulse method the time of spectra determination is for an order of magnitude smaller compared with the method of continuous passage. Порівняно спектри ЯКР, отримані методами неперервного проходження резонансних ліній та імпульсного зі швидким Фур’є-перетворенням. Встановлено, що в обох випадках можна отримати спектри з однаковими значеннями сигнал / шум, при цьому в імпульсному методі час реєстрації спектрів є на порядок меншим порівняно з методом неперервного проходження. Крім того, застосування імпульсного методу забезпечує кращу роздільну здатність в спектрі у разі неспотвореної форми резонансних ліній, що є важливим під час дослідження шаруватих напівпровідникових матеріалів, резонансні спектри яких є складними і займають широкий частотний діапазон.